LEADER 05206nam 2200637Ia 450 001 9910830829503321 005 20170815112524.0 010 $a1-5231-4395-9 010 $a1-280-54175-X 010 $a9786610541751 010 $a0-471-46076-1 010 $a0-471-22451-0 035 $a(CKB)111087027123414 035 $a(EBL)210518 035 $a(OCoLC)475918921 035 $a(SSID)ssj0000224302 035 $a(PQKBManifestationID)11202088 035 $a(PQKBTitleCode)TC0000224302 035 $a(PQKBWorkID)10209574 035 $a(PQKB)11186792 035 $a(MiAaPQ)EBC210518 035 $a(PPN)25058395X 035 $a(EXLCZ)99111087027123414 100 $a20010801d2002 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aPolymer solutions$b[electronic resource] $ean introduction to physical properties /$fIwao Teraoka 210 $aNew York $cWiley-Interscience$dc2002 215 $a1 online resource (355 p.) 300 $aDescription based upon print version of record. 311 $a0-471-38929-3 320 $aIncludes bibliographical references and index. 327 $aContents; Preface; 1 Models of Polymer Chains; 1.1 Introduction; 1.1.1 Chain Architecture; 1.1.2 Models of a Linear Polymer Chain; 1.1.3 Real Chains and Ideal Chains; 1.2 Ideal Chains; 1.2.1 Random Walk in One Dimension; 1.2.2 Random Walks in Two and Three Dimensions; 1.2.3 Dimensions of Random-Walk Chains; 1.2.4 Problems; 1.3 Gaussian Chain; 1.3.1 What is a Gaussian Chain?; 1.3.2 Dimension of a Gaussian Chain; 1.3.3 Entropy Elasticity; 1.3.4 Problems; 1.4 Real Chains; 1.4.1 Excluded Volume; 1.4.2 Dimension of a Real Chain; 1.4.3 Self-Avoiding Walk; 1.4.4 Problems; 1.5 Semirigid Chains 327 $a1.5.1 Examples of Semirigid Chains1.5.2 Wormlike Chain; 1.5.3 Problems; 1.6 Branched Chains; 1.6.1 Architecture of Branched Chains; 1.6.2 Dimension of Branched Chains; 1.6.3 Problems; 1.7 Molecular Weight Distribution; 1.7.1 Average Molecular Weights; 1.7.2 Typical Distributions; 1.7.3 Problems; 1.8 Concentration Regimes; 1.8.1 Concentration Regimes for Linear Flexible Polymers; 1.8.2 Concentration Regimes for Rodlike Molecules; 1.8.3 Problems; 2 Thermodynamics of Dilute Polymer Solutions; 2.1 Polymer Solutions and Thermodynamics; 2.2 Flory-Huggins Mean-Field Theory; 2.2.1 Model 327 $a2.2.2 Free Energy, Chemical Potentials, and Osmotic Pressure2.2.3 Dilute Solutions; 2.2.4 Coexistence Curve and Stability; 2.2.5 Polydisperse Polymer; 2.2.6 Problems; 2.3 Phase Diagram and Theta Solutions; 2.3.1 Phase Diagram; 2.3.2 Theta Solutions; 2.3.3 Coil-Globule Transition; 2.3.4 Solubility Parameter; 2.3.5 Problems; 2.4 Static Light Scattering; 2.4.1 Sample Geometry in Light-Scattering Measurements; 2.4.2 Scattering by a Small Particle; 2.4.3 Scattering by a Polymer Chain; 2.4.4 Scattering by Many Polymer Chains; 2.4.5 Correlation Function and Structure Factor 327 $a2.4.6 Structure Factor of a Polymer Chain2.4.7 Light Scattering of a Polymer Solution; 2.4.8 Other Scattering Techniques; 2.4.9 Problems; 2.5 Size Exclusion Chromatography and Confinement; 2.5.1 Separation System; 2.5.2 Plate Theory; 2.5.3 Partitioning of Polymer with a Pore; 2.5.4 Calibration of SEC; 2.5.5 SEC With an On-Line Light-Scattering Detector; 2.5.6 Problems; APPENDICES; 2.A: Review of Thermodynamics for Colligative Properties in Nonideal Solutions; 2.B: Another Approach to Thermodynamics of Polymer Solutions; 2.C: Correlation Function of a Gaussian Chain 327 $a3 Dynamics of Dilute Polymer Solutions3.1 Dynamics of Polymer Solutions; 3.2 Dynamic Light Scattering and Diffusion of Polymers; 3.2.1 Measurement System and Autocorrelation Function; 3.2.2 Autocorrelation Function; 3.2.3 Dynamic Structure Factor of Suspended Particles; 3.2.4 Diffusion of Particles; 3.2.5 Diffusion and DLS; 3.2.6 Dynamic Structure Factor of a Polymer Solution; 3.2.7 Hydrodynamic Radius; 3.2.8 Particle Sizing; 3.2.9 Diffusion From Equation of Motion; 3.2.10 Diffusion as Kinetics; 3.2.11 Concentration Effect on Diffusion; 3.2.12 Diffusion in a Nonuniform System; 3.2.13 Problems 327 $a3.3 Viscosity 330 $aPolymer Solutions: An Introduction to Physical Properties offers a fresh, inclusive approach to teaching the fundamentals of physical polymer science. Students, instructors, and professionals in polymer chemistry, analytical chemistry, organic chemistry, engineering, materials, and textiles will find Iwao Teraoka's text at once accessible and highly detailed in its treatment of the properties of polymers in the solution phase. Teraoka's purpose in writing Polymer Solutions is twofold: to familiarize the advanced undergraduate and beginning graduate student with basic concepts, theories, mode 606 $aPolymer solutions 606 $aPolymers 615 0$aPolymer solutions. 615 0$aPolymers. 676 $a547.7 676 $a547/.70454 700 $aTeraoka$b Iwao$01627883 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910830829503321 996 $aPolymer solutions$93964691 997 $aUNINA