LEADER 05130nam 2200601Ia 450 001 9910830795503321 005 20230829003135.0 010 $a1-280-85431-6 010 $a9786610854318 010 $a3-527-60799-4 010 $a3-527-60724-2 035 $a(CKB)1000000000376404 035 $a(EBL)481836 035 $a(OCoLC)70160889 035 $a(SSID)ssj0000117772 035 $a(PQKBManifestationID)11128959 035 $a(PQKBTitleCode)TC0000117772 035 $a(PQKBWorkID)10049251 035 $a(PQKB)10005480 035 $a(MiAaPQ)EBC481836 035 $a(EXLCZ)991000000000376404 100 $a20050704d2006 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aCarbon-rich compounds$b[electronic resource] $efrom molecules to materials /$fedited by Michael M. Haley and Rik R. Tykwinski 210 $aWeinheim $cWiley-VCH ;$a[Chichester $cJohn Wiley [distributor]]$d2006 215 $a1 online resource (665 p.) 300 $aDescription based upon print version of record. 311 $a3-527-31224-2 327 $aCarbon-Rich Compounds; Foreword; Contents; Preface; List of Contributors; 1 Pioneers of Carbon-rich Compounds; 1.1 Introduction; 1.2 19th Century Achievements; 1.3 1900-1928: Dawn of the Twentieth Century; 1.4 1929-1949: Rise of the Polycyclic Aromatic Hydrocarbon; 1.5 1950-1969; 1.5.1 The Annulenes, Dehydrobenzoannulenes, and Phenylacetylene Scaffolding; 1.5.2 Fused Polycyclic and peri-Condensed Benzenoid Systems; 1.5.3 The Helicenes, Radialenes, Fulvalenes, and Circulenes; 1.6 1970-Present: The Way Ahead; References; 2 Electronic Conduction in Photoactive Metallo-wires; 2.1 Introduction 327 $a2.2 Attenuation along Molecular Bridges2.3 Information Transfer; 2.3.1 Intramolecular Triplet Energy Transfer; 2.3.2 Short Covalent Bridges; 2.3.3 Supramolecular Systems; 2.3.4 Prolonging the Excited State Lifetime; 2.3.5 Long-range Triplet Energy Transfer; 2.4 Molecular-scale Switches; 2.5 Perspectives; 2.6 Experimental: Selected Procedures; 2.6.1 General Procedure for the Preparation of the Mononuclear [RuL(n)]; 2.6.2 General Procedure for the Preparation of the Hetero-Dinuclear Complexes 81(1) and 81(5); 2.6.3 Synthesis at the Complex; Acknowledgements; Abbreviations; References 327 $a3 All-benzenoid Polycyclic Aromatic Hydrocarbons: Synthesis, Self-assembly and Applications in Organic Electronics3.1 A Brief Introduction to Polycyclic Aromatic Hydrocarbons; 3.2 All-benzenoid PAHs - Synthesis, Structural Characterizations and Electronic Properties; 3.2.1 Hexa-peri-hexabenzocoronene - An Old Story with New Discoveries; 3.2.2 All-benzenoid Graphitic PAHs Larger than HBCs; 3.2.3 PAHs with Varying Peripheries; 3.2.4 ''Superbenzene'' Chemistry and Others; 3.3 Self-assembly and Application of Columnar Liquid Crystals based on PBAHs 327 $a3.3.1 Columnar Superstructures in the Bulk State3.3.2 Alignment on Substrates and Device Applications of Columnar Liquid Crystals; 3.3.3 Controlled Self-assembly in Solution; 3.3.4 Two-dimensional Crystals at the Solid/Liquid Interface; 3.4 Conclusion; 3.5 Experimental: Selected Procedures; 3.5.1 Synthesis of hexa-peri-hexabenzocoronene 10 by Cu(II)-mediated oxidative cyclodehydrogenation - a general procedure to prepare unsubstituted graphitic molecules [35] 327 $a3.5.2 Synthesis of hexakis(4-dodecylphenyl)-peri-hexabenzocoronene (HBC-PhC12) - a general synthetic method towards six-fold alkyl- and alkylphenyl-substituted HBCs [38]3.5.3 Functionalization of insoluble HBC building blocks 30-32 by Sonogashira coupling reactions [48]. Synthesis of hexakis(1-dodecynylphenyl)-peri-hexabenzocoronene (34a) as a representative example; 3.5.4 Synthesis of C96-C12 precursor 1,3,5-tris[3 ?,4 ?-di(4 ? ?-dodecylphenyl)-2 ?,5 ?-diphenylphenyl]benzene (44a) by Diels-Alder cycloaddition reaction - a representative procedure for the synthesis of branched oligophenylenes [50] 327 $a3.5.5 Hydrogenation of hexakis-dodecyl-peri-hexabenzocoronenes 74 [66] 330 $aThis is the only up-to-date book on the market to focus on the synthesis of these compounds in this particularly suitable way. A team of excellent international authors guarantees high-quality content, covering such topics as monodisperse carbon-rich oligomers, molecular electronic wires, polyaromatic hydrocarbons, nonconjugated small molecules, nanotubes, fullerenes, polyynes, macrocycles, dendrimers, phenylenes and diamondoid structures.The result is a must-have for everyone working in this expanding and interdisciplinary field, including organic and polymer chemists, materials scientist 606 $aCarbon compounds 606 $aChemistry, Organic 615 0$aCarbon compounds. 615 0$aChemistry, Organic. 676 $a547 701 $aHaley$b Michael$0201171 701 $aTykwinski$b R. R$g(Rik R.)$01603712 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910830795503321 996 $aCarbon-rich compounds$94086996 997 $aUNINA