LEADER 05254nam 2200661 450 001 9910830737303321 005 20230721033054.0 010 $a1-281-84131-5 010 $a9786611841317 010 $a0-470-99460-6 010 $a0-470-99459-2 035 $a(CKB)1000000000549550 035 $a(EBL)366775 035 $a(SSID)ssj0000201514 035 $a(PQKBManifestationID)11183736 035 $a(PQKBTitleCode)TC0000201514 035 $a(PQKBWorkID)10245499 035 $a(PQKB)11372096 035 $a(MiAaPQ)EBC366775 035 $a(OCoLC)264615480 035 $a(EXLCZ)991000000000549550 100 $a20160818h20082008 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aMesocrystals and nonclassical crystallization /$fHelmut Co?lfen, Markus Antonietti 210 1$aWest Sussex, England :$cJohn Wiley & Sons Ltd,$d2008. 210 4$dİ2008 215 $a1 online resource (296 p.) 300 $aDescription based upon print version of record. 311 $a0-470-02981-1 320 $aIncludes bibliographical references and index. 327 $aMesocrystals and Nonclassical Crystallization; Contents; Preface; 1 Mesocrystals and Nonclassical Crystallization; 1.1 Introduction; References; 2 Physico-Chemical Principles of Crystallization; 2.1 Classical Crystallization; 2.2 Definition of a Crystal and Crystal Growth; 2.3 Nucleation Theories; 2.3.1 Classical Nucleation Theory; 2.3.2 Experimental Tests of Nucleation Theories; 2.4 Some Points towards a More Realistic View of Supersaturation and Crystallization; 2.4.1 Concentration Fluctuations and Spinodal Crystallization 327 $a2.4.2 Reduction of Supersaturation by the Formation of Clusters and Amorphous Intermediates2.5 Thermodynamic and Kinetic Crystallization Pathways; 2.6 Polymorph Control; 2.7 Crystal Morphology and the Role of Additives and Selective Adsorption; 2.7.1 Crystal Morphology; 2.7.2 What Determines Adsorption of an Additive?; 2.8 Properties of Single Crystals and Polycrystals; 2.8.1 Electrical Polarization; 2.8.2 Light Refraction and Birefringence; 2.8.3 Mechanical Properties; References; 3 Examples of Crystals Challenging the Classical Textbook Mechanism; 3.1 Some Biomineral Examples 327 $a3.1.1 Elongated Magnetite Nanocrystals in Magnetotactic Bacteria3.1.2 Calcite with Complex Form and Single Crystal Behavior in Foraminifera; 3.1.3 Calcite with Complex Form and Single Crystal Behavior in Sea Urchin Spines; 3.1.4 Calcite Single Crystals with Complex Form in Coccoliths; 3.1.5 Morphological Complexity Develops with Time; 3.2 From Biology to Biomimetics:In VitroMineralization Examples; 3.3 Biomorphs; 3.4 Other Synthetic Examples; References; 4 Nonclassical Crystallization; 4.1 Amorphous Precursors; 4.2 Liquid Precursors; 4.3 Oriented Attachment; 4.4 Mesocrystals; References 327 $a5 Self-Assembly and Self-OrganizationReferences; 6 Colloidal Crystals with Spherical Units: Opals and Colloidal Nanocrystals; References; 7 Mesocrystal Systems; 7.1 Mesocrystals and Their Properties; 7.2 Early Reports on Mesocrystals; 7.3 One-Dimensional Mesocrystals; 7.4 Two-Dimensional Mesocrystals; 7.5 Mesocrystals in Biomineralization; 7.6 Mesocrystals in Gels; 7.7 Mesocrystals Formed without Additives; 7.8 Mesocrystals Formed with Simple Ion Additives; 7.9 Mesocrystals Formed with Polymer Additives; 7.10 Mesocrystals in Nonaqueous Systems 327 $a7.11 Mesocrystals Formed via Solid-State Reactions7.11.1 Solid Matrices for Mesocrystal Formation; 7.11.2 Topotactic Reactions; 7.12 Liquid Crystals, Tactoids, Somatoids, and Schiller Layers; References; 8 Mechanisms of Mesocrystal Formation; 8.1 Principal Mechanisms Leading to Mesocrystals; 8.2 Conditions for Mesocrystal Formation; 8.3 Alignment by Colloidal Forces, Capillarity and Other Short-Ranged Physical Fields; 8.3.1 Alignment by Capillary Forces; 8.3.2 Alignment by Hydrophobic Forces and Interface Energies; 8.3.3 Alignment by Minimization of the Interfacial Energy 327 $a8.3.4 Alignment by Additive Coding of Nanoparticles 330 $aThrough both explanation and discussion, this title presents a complete review into mesocrystals, and accurately describes this relatively new study of established materials. This book also provides an introduction to other areas of crystallisation including self-assembly, classical crystallisation and colloidal crystals. Key features:Description of crystals as well as their formation processes and ways to modify them.Examines new ways towards the design of new materials and aids comprehension of the building principles of biominerals.Helps to explain many unus 606 $aColloidal crystals 606 $aCrystal growth 606 $aNanostructured materials 615 0$aColloidal crystals. 615 0$aCrystal growth. 615 0$aNanostructured materials. 676 $a548 676 $a548.5 700 $aCo?lfen$b H$g(Helmut),$01593280 702 $aAntonietti$b M. 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910830737303321 996 $aMesocrystals and nonclassical crystallization$93913339 997 $aUNINA