LEADER 05076nam 2200661Ia 450 001 9910830730203321 005 20230829003219.0 010 $a1-280-72283-5 010 $a9786610722839 010 $a3-527-60933-4 010 $a3-527-60949-0 035 $a(CKB)1000000000376450 035 $a(EBL)481970 035 $a(OCoLC)77602792 035 $a(SSID)ssj0000122439 035 $a(PQKBManifestationID)11140006 035 $a(PQKBTitleCode)TC0000122439 035 $a(PQKBWorkID)10123893 035 $a(PQKB)11571771 035 $a(MiAaPQ)EBC481970 035 $a(EXLCZ)991000000000376450 100 $a20060825d2006 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aCis-trans isomerization in biochemistry$b[electronic resource] /$fedited by Christophe Dugave 210 $aWeinheim $cWiley-VCH$dc2006 215 $a1 online resource (372 p.) 300 $aDescription based upon print version of record. 311 $a3-527-31304-4 320 $aIncludes bibliographical references and index. 327 $acis-trans Isomerization in Biochemistry; Contents; Preface; List of Contributors; 1 Nomenclature; 2 General Mechanisms of Cis-Trans Isomerization: A Rapid Survey; 2.1 Introduction; 2.2 Homolytic Cis-Trans Isomerization; 2.3 Heterolytic Cis-Trans Isomerization; 3 Mechanisms of Cis-Trans Isomerization around the Carbon-Carbon Double Bonds via the Triplet State; 3.1 A Concept of a Triplet-Excited Region; 3.2 Triplet-State Isomerization in Retinal; 3.2.1 Cis-Trans Isomerization Examined by Electronic Absorption and Raman Spectroscopies and by High-Performance Liquid Chromatography Analysis 327 $a3.2.2 Triplet-Excited Region in All-trans-Retinal Shown in Terms of Stretching Force Constants Determined by Raman Spectroscopy and Normal Coordinate Analysis [9]3.2.3 Dynamic Triplet-Excited Region in Retinal As Revealed by Deuteration Effects on the Quantum Yields of Isomerization via the T(1) State (Okumura, Koyama, unpublished results); 3.2.4 Summary and Future Trends; 3.3 Triplet-State Isomerization in ?-Carotene and Spheroidene; 3.3.1 Cis-Trans Isomerization in ?-Carotene Studied by Electronic Absorption and Raman Spectroscopies and by HPLC Analysis 327 $a3.3.2 Cis-Trans Isomerization in Spheroidene Studied by Time-Resolved Absorption Spectroscopy and by HPLC Analysis [17]3.3.3 The Triplet-Excited Region of All-trans-Spheroidene in Solution and the Triplet-State Structure of 15-cis-Spheroidene Bound to the Bacterial Reaction Center Determined by Raman Spectroscopy and Normal Coordinate Analysis [18]; 3.3.3.1 All-trans-Spheroidene in Solution; 3.3.3.2 15-cis-Spheroidene Bound to the Reaction Center 327 $a3.3.4 Conformational Changes and the Inversion of Spin-Polarization Identified by Low-Temperature Electron Paramagnetic Resonance Spectroscopy of the Reaction Center-Bound 15-cis-Spheroidene: A Hypothetical Mechanism of Triplet-Energy Dissipation [19]3.3.5 Summary and Future Trends; 3.4 Spectroscopic and Analytical Techniques for Studying Cis-Trans Isomerization in the T(1) State; 3.4.1 Spectroscopic Techniques: Electronic Absorption, Raman, and Magnetic Resonance Spectroscopies; 3.4.2 A Useful Analytical Technique: Singular-Value Decomposition Followed by Global Fitting [23-25] 327 $a4 Retinal Binding Proteins4.1 Retinal Chromophore in Rhodopsins; 4.1.1 Specific Color Regulation of the Retinal Chromophore in Protein; 4.1.2 Unique Photochemistry of the Retinal Chromophore in Protein; 4.2 Photoisomerization in Visual Rhodopsins; 4.2.1 Structure and Function of Visual Rhodopsins; 4.2.2 Primary Process in Vision Studied by Ultrafast Spectroscopy; 4.2.3 Structural Changes of the Chromophore and Protein upon Retinal Photoisomerization; 4.3 Photoisomerization in Archaeal Rhodopsins; 4.3.1 Structure and Function of Archaeal Rhodopsin 327 $a4.3.2 Primary Process in Bacterial Photosynthesis and Light Sensor Studied by Ultrafast Spectroscopy 330 $aCollating the knowledge from over 20,000 publications in chemistry, biology and nanotechnology, this handbook is the first to comprehensively present the state of the art in one ready reference. A team of international authors connects the various disciplines involved, covering cis-trans isomerization of double bonds and pseudo-double bonds, as well as other cis-trans isomerizations.For biochemists, organic chemists, physicochemists, photochemists, polymer and medicinal chemists. 606 $aBiomolecules 606 $aStereochemistry 606 $aIsomerism 606 $aBiochemistry 615 0$aBiomolecules. 615 0$aStereochemistry. 615 0$aIsomerism. 615 0$aBiochemistry. 676 $a547.12252 676 $a547.7804452 701 $aDugave$b Christophe$01593251 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910830730203321 996 $aCis-trans isomerization in biochemistry$93913292 997 $aUNINA