LEADER 05029nam 2200625 a 450 001 9910830727603321 005 20230828213315.0 010 $a1-280-28821-3 010 $a9786610288212 010 $a0-470-36177-8 010 $a0-471-76767-0 010 $a0-471-76766-2 035 $a(CKB)1000000000355350 035 $a(EBL)243684 035 $a(OCoLC)171257434 035 $a(SSID)ssj0000187115 035 $a(PQKBManifestationID)11939159 035 $a(PQKBTitleCode)TC0000187115 035 $a(PQKBWorkID)10253626 035 $a(PQKB)10376049 035 $a(MiAaPQ)EBC243684 035 $a(EXLCZ)991000000000355350 100 $a20050512d2006 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aKetenes II$b[electronic resource] /$fThomas T. Tidwell 205 $a2nd ed. 210 $aHoboken, N.J. $cWiley-Interscience$dc2006 215 $a1 online resource (672 p.) 300 $aDescription based upon print version of record. 311 $a0-471-69282-4 320 $aIncludes bibliographical references and index. 327 $aKETENES II; Contents; Preface; Introduction; References; 1 Structure, Bonding, and Thermochemistry of Ketenes; 1.1 Theoretical and Computational Studies of Ketenes; 1.1.1 Molecular and Electronic Structure and Energy; References; 1.1.2 Theoretical and Computational Studies of Ketene Reactions; References; 1.1.3 Substituent Effects on Ketenes; References; 1.2 Molecular Structure Determinations; References; 1.3 Thermochemistry of Ketenes; References; 2 Spectroscopy and Physical Properties of Ketenes; 2.1 Nuclear Magnetic Resonance Spectroscopy; References 327 $a2.2 Ultraviolet Spectra, Photoelectron Spectra, and Chiroptical PropertiesReferences; 2.3 Infrared Spectra and Raman Spectra; References; 2.4 Dipole Moments; References; 2.5 Mass Spectrometry and Gas Phase Ion Chemistry; References; 3 Preparation of Ketenes; 3.1 Ketenes from Ketene Dimers; References; 3.2 Ketenes from Carboxylic Acids and their Derivatives; 3.2.1 Ketenes from Carboxylic Acids and Anhydrides; 3.2.1.1 Ketenes from Carboxylic Acids; References; 3.2.1.2 Ketenes from Acid Anhydrides; References; 3.2.2 Ketenes from Acyl Halides and Activated Acids; References 327 $a3.2.3 Ketenes from Esters3.2.3.1 Ketenes from Ester Enolates; 3.2.3.2 Ketenes by Ester Pyrolysis; References; 3.2.4 Ketenes by Dehalogenation of a-Halo Carboxylic Acid Derivatives; References; 3.3 Ketenes from Diazo Ketones (Wolff Rearrangements); 3.3.1 Thermal Wolff Rearrangement; 3.3.2 Catalyzed Wolff Rearrangement; 3.3.3 Photochemical Wolff Rearrangement; 3.3.4 Other Routes to Ketocarbene Rearrangements; References; 3.4 Ketenes by Photochemical and Thermolytic Methods; 3.4.1 Ketenes from Cyclobutanones and Cyclobutenones; References 327 $a3.4.2 Ketenes from Photolysis of Cycloalkanones and EnonesReferences; 3.4.3 Ketenes from Cyclohexadienones and other Cycloalkenones; References; 3.4.4 Ketenes from Dioxinones; References; 3.4.5 Ketenes by Thermolysis of Alkynyl Ethers; References; 3.4.6 Ketenes from other Thermolytic and Photochemical Routes; References; 3.5 Ketenes from Metal Carbene Complexes; References; 3.6 Ketene Formation from Cations and Free Radicals; References; 3.7 Ketenes from Oxidation of Alkynes; References; 3.8 Other Routes to Ketenes; References; 4 Types of Ketenes; 4.1 Carbon-Substituted Ketenes 327 $a4.1.1 AlkylketenesReferences; 4.1.2 Alkenylketenes; References; 4.1.3 Alkynyl- and Cyanoketenes; References; 4.1.4 Aryl- and Heteroarylketenes; References; 4.1.5 Cyclopropyl-, Cyclopropenyl-, and Oxiranylketenes; References; 4.1.6 Acylketenes; References; 4.1.7 Imidoylketenes; References; 4.1.8 Cumulene-Substituted Ketenes; References; 4.1.9 Ketenes with Charged, Radical, or Carbenic Side Chains; References; 4.1.10 Fulvenones and Cumulenones; 4.1.10.1 Triafulvenones; 4.1.10.2 Pentafulvenones; References; 4.1.11 Oxoquinone Methides, Oxoxylylenes, and Related Species; References 327 $a4.2 Nitrogen-Substituted Ketenes 330 $aThe most up-to-date single reference on ketene chemistry for the practicing researcherKetenes are valued by both practicing organic synthetic chemists and pharmaceutical researchers for their ease of preparation, high reactivity, and versatility of use.Ketenes, Second Edition is an updated version of the premier resource on this important class of compounds, and features a comprehensive, self-contained guide to all aspects of ketene chemistry, including:* Types of ketenes* Theoretical studies* Thermochemistry* Ketene preparation* Reactions, including mechani 606 $aKetenes 615 0$aKetenes. 676 $a547.036 676 $a547.436 676 $a547/.436 700 $aTidwell$b Thomas T.$f1939-$01606478 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910830727603321 996 $aKetenes II$93932283 997 $aUNINA