LEADER 05362nam 2200697Ia 450 001 9910830722503321 005 20230317170651.0 010 $a1-283-20329-4 010 $a9786613203298 010 $a0-470-38075-6 010 $a0-470-38073-X 035 $a(CKB)1000000000553236 035 $a(EBL)380487 035 $a(OCoLC)299753386 035 $a(SSID)ssj0000136057 035 $a(PQKBManifestationID)11162422 035 $a(PQKBTitleCode)TC0000136057 035 $a(PQKBWorkID)10082400 035 $a(PQKB)10758114 035 $a(MiAaPQ)EBC380487 035 $a(PPN)152264256 035 $a(EXLCZ)991000000000553236 100 $a20080110d2008 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aDefects in solids$b[electronic resource] /$fRichard J.D. Tilley 210 $aHoboken, N.J. $cWiley$dc2008 215 $a1 online resource (549 p.) 225 1 $aSpecial Topics in Inorganic Chemistry ;$vv.4 300 $aDescription based upon print version of record. 311 08$a0-470-07794-8 320 $aIncludes bibliographical references and indexes. 327 $aDEFECTS IN SOLIDS; CONTENTS; Preface; 1. Point Defects; 1.1 Introduction; 1.2 Point and Electronic Defects in Crystalline Solids; 1.3 Electronic Properties: Doped Silicon and Germanium as Examples; 1.4 Optical Properties: F Centers and Ruby as Examples; 1.5 Bulk Properties; 1.5.1 Unit Cell Dimensions; 1.5.2 Density; 1.5.3 Volume; 1.5.4 Young's Modulus (the Elastic Modulus); 1.6 Thermoelectric Properties: The Seebeck Coefficient as an Example; 1.7 Point Defect Notation; 1.8 Charges on Defects; 1.8.1 Electrons and Electron Holes; 1.8.2 Atomic and Ionic Defects 327 $a1.9 Balanced Populations of Point Defects: Schottky and Frenkel Defects 1.9.1 Schottky Defects; 1.9.2 Frenkel Defects; 1.10 Antisite Defects; 1.11 Defect Formation and Reaction Equations; 1.11.1 Addition and Subtraction of Atoms; 1.11.2 Equation Formalism; 1.11.3 Formation of Antisite Defects; 1.11.4 Nickel Oxide; 1.11.5 Cadmium Oxide; 1.11.6 Calcia-stabilized Zirconia; 1.11.7 Ternary Oxides; 1.12 Combinations of Point Defects in Pure Materials; 1.13 Structural Consequences of Point Defect Populations; 1.14 Answers to Introductory Questions; Problems and Exercises; References; Further Reading 327 $a2. Intrinsic Point Defects in Stoichiometric Compounds 2.1 Equilibrium Population of Vacancies in a Monatomic Crystal; 2.2 Equilibrium Population of Self-Interstitials in a Monatomic Crystal; 2.3 Equilibrium Population of Schottky Defects in a Crystal; 2.4 Lithium Iodide Battery; 2.5 Equilibrium Population of Frenkel Defects in a Crystal; 2.6 Photographic Film; 2.7 Photochromic Glasses; 2.8 Equilibrium Population of Antisite Defects in a Crystal; 2.9 Intrinsic Defects: Trends and Further Considerations; 2.10 Computation of Defect Energies; 2.10.1 Defect Calculations 327 $a2.10.2 Point Defect Interactions 2.10.3 Atomistic Simulation; 2.10.4 The Shell Model; 2.10.5 Defect Formation Energy; 2.10.6 Quantum Mechanical Calculations; 2.11 Answers to Introductory Questions; Problems and Exercises; References; Further Reading; 3. Extended Defects; 3.1 Dislocations; 3.2 Edge Dislocations; 3.3 Screw Dislocations; 3.4 Mixed Dislocations; 3.5 Unit and Partial Dislocations; 3.6 Multiplication of Dislocations; 3.7 Interaction of Dislocations and Point Defects; 3.7.1 Dislocation Loops; 3.7.2 Dislocation Climb; 3.7.3 Decoration of Dislocations 327 $a3.8 Dislocations in Nonmetallic Crystals 3.9 Internal Boundaries; 3.10 Low-Angle Grain Boundaries; 3.11 Twin Boundaries; 3.12 Antiphase Boundaries; 3.13 Domains and Ferroic Materials; 3.13.1 Magnetic Structures; 3.13.2 Ferroelectric Structures; 3.13.3 Ferroic Structures; 3.14 External Surfaces and Grain Boundaries; 3.14.1 Optical Characteristics of Polycrystalline Solids; 3.14.2 Electronic Properties of Interfaces; 3.14.3 Varistors; 3.14.4 Positive Temperature Coefficient Thermistors; 3.15 Volume Defects and Precipitates; 3.16 Answers to Introductory Questions; Problems and Exercises 327 $aFurther Reading 330 $aProvides a thorough understanding of the chemistry and physics of defects, enabling the reader to manipulate them in the engineering of materials.Reinforces theoretical concepts by placing emphasis on real world processes and applications. Includes two kinds of end-of-chapter problems: multiple choice (to test knowledge of terms and principles) and more extensive exercises and calculations (to build skills and understanding).Supplementary material on crystallography and band structure are included in separate appendices. 410 0$aSpecial Topics in Inorganic Chemistry 606 $aSolids$xDefects 606 $aSolids$xElectric properties 606 $aSolids$xMagnetic properties 606 $aSolids$xOptical properties 615 0$aSolids$xDefects. 615 0$aSolids$xElectric properties. 615 0$aSolids$xMagnetic properties. 615 0$aSolids$xOptical properties. 676 $a620.1/1 676 $a620.11 700 $aTilley$b R. J. D$0856746 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910830722503321 996 $aDefects in solids$93932251 997 $aUNINA