LEADER 05245nam 2200625 a 450 001 9910830671503321 005 20170816123654.0 010 $a1-280-56077-0 010 $a9786610560776 010 $a3-527-60644-0 010 $a3-527-60209-7 035 $a(CKB)1000000000019280 035 $a(EBL)481800 035 $a(OCoLC)77640507 035 $a(SSID)ssj0000183822 035 $a(PQKBManifestationID)11939047 035 $a(PQKBTitleCode)TC0000183822 035 $a(PQKBWorkID)10199238 035 $a(PQKB)10745499 035 $a(MiAaPQ)EBC481800 035 $a(PPN)242642381 035 $a(EXLCZ)991000000000019280 100 $a20031022d2003 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 14$aThe iron oxides$b[electronic resource] $estructure, properties, reactions, occurrences, and uses /$fR.M. Cornell, U. Schwertmann 205 $a2nd ed. 210 $aWeinheim $cWiley-VCH$d2003 215 $a1 online resource (706 p.) 300 $aDescription based upon print version of record. 311 $a3-527-30274-3 320 $aIncludes bibliographical references (p. 553-646) and index. 327 $aThe Iron Oxides; Contents; Preface to the Second Edition; Preface to the First Edition; Abbreviations; Colour Plates; 1 Introduction to the iron oxides; 2 Crystal structure; 2.1 General; 2.2 Iron oxide structures; 2.2.1 Close packing of anion layers; 2.2.2 Linkages of octahedra or tetrahedra; 2.3 Structures of the individual iron oxides; 2.3.1 The oxide hydroxides; 2.3.1.1 Goethite ?-FeOOH; 2.3.1.2 Lepidocrocite ?-FeO(OH); 2.3.1.3 Akagane?ite ?-FeO(OH) and schwertmannite Fe(16)O(16) (OH)(y)(SO(4))(z) ·n H(2)O; 2.3.1.4 ?-FeOOH and ? ?-FeOOH (feroxyhyte); 2.3.1.5 High pressure FeOOH 327 $a2.3.1.6 Ferrihydrite2.3.2 The Hydroxides; 2.3.2.1 Bernalite Fe(OH)(3) · nH(2)O; 2.3.2.2 Fe(OH)(2); 2.3.2.3 Green rusts; 2.3.3 The Oxides; 2.3.3.1 Hematite ?-Fe(2)O(3); 2.3.3.2 ?-Fe(2)O(3); 2.3.3.3 Magnetite Fe(3)O(4); 2.3.3.4 Maghemite ?-Fe(2)O(3); 2.3.3.5 Wu?stite Fe(1-x)O; 2.4 The Fe-Ti oxide system; Appendix; 3 Cation substitution; 3.1 General; 3.2 Goethite and lepidocrocite; 3.2.1 Al substitution; 3.2.2 Other substituting cations; 3.3 Hematite; 3.3.1 Al substitution; 3.3.2 Other cations; 3.4 Magnetite and maghemite; 3.5 Other Iron oxides; 4 Crystal morphology and size; 4.1 General 327 $a4.1.1 Crystal growth4.1.2 Crystal morphology; 4.1.3 Crystal size; 4.2 The iron oxides; 4.2.1 Goethite; 4.2.1.1 General; 4.2.1.2 Domainic character; 4.2.1.3 Twinning; 4.2.1.4 Effect of additives; 4.2.2 Lepidocrocite; 4.2.3 Akagane?ite and schwertmannite; 4.2.4 Ferrihydrite; 4.2.5 Hematite; 4.2.6 Magnetite; 4.2.7 Maghemite; 4.2.8 Other Iron Oxides; 5 Surface area and porosity; 5.1 Surface Area; 5.2 Porosity; 5.3 Surface Roughness and Fractal Dimensions; 5.4 The iron oxides; 5.4.1 Goethite; 5.4.2 Lepidocrocite; 5.4.3 Akagane?ite and schwertmannite; 5.4.4 ?-FeOOH and feroxyhyte; 5.4.5 Ferrihydrite 327 $a5.4.6 Hematite5.4.7 Magnetite; 5.4.8 Maghemite; 6 Electronic, electrical and magnetic properties and colour; 6.1 Electronic properties; 6.1.1 Free Fe(3+) and Fe(2+) ions; 6.1.2 Bound Fe ions; 6.1.3 Molecular orbital description of bonding in iron oxides; 6.2 Electrical properties; 6.2.1 Semiconductor properties of iron oxides; 6.3 Magnetic properties; 6.3.1 Basic definitions; 6.3.2 Types of magnetism (Fig. 6.5); 6.3.3 Magnetic behaviour of iron oxides; 6.3.4 The different iron oxides; 6.3.4.1 Goethite; 6.3.4.2 Lepidocrocite; 6.3.4.3 Akagane?ite 327 $a6.3.4.4 ?-FeOOH, feroxyhyte and high pressure FeOOH6.3.4.5 Ferrihydrite; 6.3.4.6 Hematite; 6.3.4.7 Magnetite and Maghemite; 6.3.4.8 Other Fe oxides; 6.4 Colour; 6.4.1 General; 6.4.2 Colours; 6.4.3 Pigment properties; 7 Characterization; 7.1 Introduction; 7.2 Infrared spectroscopy; 7.2.1 Goethite; 7.2.2 Lepidocrocite; 7.2.3 Ferrihydrite; 7.2.4 Hematite; 7.2.5 Other iron oxides; 7.3 Raman spectroscopy; 7.4 Ultraviolet-visible spectroscopy; 7.4.1 General; 7.4.2 Spectra of the different Fe oxides; 7.5 Mo?ssbauer spectroscopy; 7.5.1 General; 7.5.2 Spectra of the various Fe oxides 327 $a7.5.2.1 Goethite and Lepidocrocite 330 $aThis book brings together in one, compact volume all aspects of the available information about the iron oxides. It presents a coherent, up to date account of the properties, reactions and mechanisms of formation of these compounds. In addition, there are chapters dealing with iron oxides in rocks and soils, as biominerals and as corrosion products together with methods of synthesis and the numerous application of these compounds. Their role in the environment is also discussed. The authors are experts in the field of iron oxides and have worked on all the topics covered. Much recent data from 606 $aIron oxides 615 0$aIron oxides. 676 $a542.6212 676 $a546/.6212 700 $aCornell$b R. M$01663191 701 $aSchwertmann$b Udo$0439418 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910830671503321 996 $aThe iron oxides$94020316 997 $aUNINA