LEADER 05253nam 2200637Ia 450 001 9910830668303321 005 20230721003751.0 010 $a1-281-94717-2 010 $a9786611947170 010 $a3-527-62323-X 010 $a3-527-62324-8 035 $a(CKB)1000000000556195 035 $a(EBL)481568 035 $a(OCoLC)283799101 035 $a(SSID)ssj0000216329 035 $a(PQKBManifestationID)11197412 035 $a(PQKBTitleCode)TC0000216329 035 $a(PQKBWorkID)10197084 035 $a(PQKB)10014171 035 $a(MiAaPQ)EBC481568 035 $a(EXLCZ)991000000000556195 100 $a20080215d2008 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aOrganosulfur chemistry in asymmetric synthesis$b[electronic resource] /$fedited by Takeshi Toru and Carsten Bolm 210 $aWeinheim $cWiley-VCH$dc2008 215 $a1 online resource (450 p.) 300 $aDescription based upon print version of record. 311 $a3-527-31854-2 320 $aIncludes bibliographical references and index. 327 $aOrganosulfur Chemistry in Asymmetric Synthesis; Contents; Preface; List of Contributors; 1 Asymmetric Synthesis of Chiral Sulfoxides; 1.1 Chiral Sulfoxides; 1.1.1 Introduction; 1.1.2 The Main Routes to Chiral Sulfoxides; 1.2 Use of Chiral Sulfur Precursors; 1.2.1 Sulfinates (Andersen Method); 1.2.2 Diastereoselective Formation of Sulfinates; 1.2.3 Sulfinates from Sulfites; 1.2.4 Sulfinamides; 1.3 Catalytic Enantioselective Sulfide Oxidation; 1.3.1 Titanium Complexes; 1.3.1.1 Diesters of Tartaric Acid; 1.3.1.2 C(2)-Symmetric 1,2-Diols as Ligands; 1.3.1.3 Binaphthol and Derivatives 327 $a1.3.1.4 C(3)-Symmetric Triethanolamine Ligands1.3.1.5 Ti (Salen) Catalysts; 1.3.2 Manganese Complexes; 1.3.3 Vanadium Complexes; 1.3.4 Molybdenum Complexes; 1.3.5 Iron Complexes; 1.3.6 Miscellaneous; 1.4 Catalytic Arylation of Sulfenate Anions; 1.5 Enantioselective Oxidation of Sulfides; 1.6 Summary; References; 2 Asymmetric Synthesis of Optically Active Sulfinic Acid Esters; 2.1 Introduction; 2.2 Enantiomeric Sulfinic Acid Esters; 2.3 Diastereomeric Sulfinic Acid Esters; References; 3 Asymmetric Transformations Mediated by Sulfinyl Groups; 3.1 Introduction 327 $a3.2 Nucleophilic Additions to C=O and C=N Bonds Mediated by ?-Sulfinyl Groups3.2.1 ?-Ketosulfoxides; 3.2.1.1 Reduction Reactions; 3.2.1.2 Alkylation Reactions; 3.2.1.3 Aldol Reaction with ?-Ketosulfoxides Acting as Electrophiles; 3.2.1.4 Hydrocyanation Reactions; 3.2.2 ?-Imino(enamino)sulfoxides; 3.3 Conjugate Additions to ?,?-Unsaturated Sulfoxides; 3.3.1 Nucleophilic Additions; 3.3.1.1 (E) and (Z)-2-Substituted Vinyl Sulfoxides; 3.3.1.2 1-Substituted Vinyl Sulfoxides; 3.3.2 Tandem Reactions; 3.3.3 Radical Conjugate Additions and Other Reactions; 3.4 Cycloadditions 327 $a3.4.1 Asymmetric Diels-Alder Reactions3.4.1.1 Sulfinyl Dienophiles; 3.4.1.2 Sulfinyl Dienes; 3.4.2 Asymmetric Hetero Diels-Alder Reactions; 3.4.3 Asymmetric 1,3-Dipolar Cycloadditions; 3.4.3.1 Reactions with Nitrones; 3.4.3.2 Reactions with Azomethine Ylides; 3.4.3.3 Reactions with Nitrile Oxides; 3.4.3.4 Reactions with Diazoalkanes; 3.4.3.5 Reactions with Other Dipoles; 3.4.4 Other Asymmetric Cycloadditions; 3.5 Asymmetric Processes Stereocontrolled by Remote Sulfoxides; 3.5.1 Nucleophilic Processes; 3.5.1.1 Reactions with Sulfinylated Electrophiles 327 $a3.5.1.2 Reactions with Sulfinylated Nucleophiles3.6 Asymmetric Pummerer Reaction; References; 4 Synthesis and Applications of Chiral Dithioacetal Derivatives; 4.1 Introduction; 4.2 Lithiated Dithianes; 4.3 Alternative Methods; 4.4 Oxidation Methods for the Construction of Chiral Dithioacetal Derivatives and Applications in Synthesis; 4.5 Applications of Chiral Dithioacetal Derivatives in Natural Product and Biologically Active Compound Synthesis; 4.6 Summary; References; 5 Synthesis and Use of Chiral Sulfur Ylides; 5.1 Introduction; 5.1.1 Reactions of Sulfonium Ylides 327 $a5.1.2 Methods of Preparation 330 $aIn this first book to gather the information on this hot topic otherwise widely spread throughout the literature, experienced editors and top international authors cover everything the reader needs -- from the synthesis of chiral organosulfur compounds to applications and catalysis: * Asymmetric synthesis of chiral sulfinates and sulfoxides* Synthesis and use of chiral dithioacetal derivatives, ylids, chiral sulfoximines and sulfinamides* Use of chiral sulfoxides as ligands in catalysis* Asymmetric reactions of alpha-sulfenyl, alpha-sulfinyl and alpha-sulfonyl carbanions.As 606 $aOrganosulfur compounds 606 $aAsymmetric synthesis 606 $aEnantioselective catalysis 615 0$aOrganosulfur compounds. 615 0$aAsymmetric synthesis. 615 0$aEnantioselective catalysis. 676 $a547.06045 701 $aToru$b Takeshi$01639465 701 $aBolm$b Carsten$0542970 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910830668303321 996 $aOrganosulfur chemistry in asymmetric synthesis$93982473 997 $aUNINA