LEADER 04890nam 2200673Ia 450 001 9910830645203321 005 20230331005428.0 010 $a1-282-30723-1 010 $a9786612307232 010 $a0-470-18735-2 010 $a0-470-18887-1 035 $a(CKB)1000000000376591 035 $a(EBL)469121 035 $a(OCoLC)746577067 035 $a(SSID)ssj0000339386 035 $a(PQKBManifestationID)11256682 035 $a(PQKBTitleCode)TC0000339386 035 $a(PQKBWorkID)10323840 035 $a(PQKB)10146950 035 $a(MiAaPQ)EBC469121 035 $a(EXLCZ)991000000000376591 100 $a19890728d1991 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aIsoxazoles$hPart one$b[electronic resource] /$fPaolo Gru?nanger, Paola Vita-Finzi 210 $aNew York $cJohn Wiley & Sons$d1991 215 $a1 online resource (904 p.) 225 1 $aChemistry of heterocyclic compounds,$x0069-3154 ;$vv. 49 300 $aDescription based upon print version of record. 311 $a0-471-02233-0 320 $aIncludes bibliographical references and indexes. 327 $aISOXAZOLES; The Chemistry of Heterocyclic Compounds Introduction to the Series; Preface; Contents; CHAPTER 1; 1. Isoxazoles; 1.1 Introduction; 1.2 Physicochemical Properties; 1.2.1 Infrared Spectra; 1.2.2 Ultraviolet Spectra; 1.2.3 Nuclear Magnetic Resonance Spectra; 1.2.3.1 PMR Spectra; 1.2.3.2 I3C-NMR Spectra; 1.2.3.3 I4N- and ""N-NMR Spectra; 1.2.3.4 Other Nuclei NMR Spectra; 1.2.4 Mass Spectra; 1.2.5 Other Spectra; 1.2.5.1 Microwave Spectra; 1.2.5.2 Photoelectron Spectra; 1.2.5.3 Electron Paramagnetic Resonance Spectra; 1.2.5.4 Electron Spin Resonance Spectra 327 $a1.2.5.5 Nuclear Quadrupole Resonance Spectra1.2.5.6 Other Spectra; 1.2.6 Crystal and Molecular Structure; 1.2.7 Dipole Moments; 1.2.8 Theoretical Calculations; 1.2.8.1 Reactivity, Aromaticity, and Electron Density; 1.2.8.2 Molecular Geometry; 1.2.8.3 Basicity and Dipole Moments; 1.2.8.4 Ionization Potentials; 1.2.8.5 Molecular Core Binding Energy; 1.2.8.6 Spectroscopic Data and Conformational Analysis; 1.2.9 Basicity; 1.2.10 Miscellaneous Data; 1.2.11 Analytical Methods; 1.3 Methods of Preparation; 1.3.1 [CCC + NO] Processes; 1.3.1.1 Oximation of 1, 3-Dicarbonyl (and Related) Compounds 327 $a1.3.1.2 Oximation of a-Acetylenic Carbonyl (and Related) Compounds1.3.1.3 Oximation of a-Dihalocarbonyl (and Related) Compounds; 1.3.1.4 Oximation of z, 8-Ethylenic Carbonyl (and Related) Compounds 8-Substituted with Electron-Withdrawing Groups; 1.3.1.5 Oximation of a, b-Ethylenic Carbonyl (and Related) Compounds; 1.3.1.6 Other Oximation Reactions; 1.3.1.7 Synthesis from Unsaturated Compounds and Nitric (Nitrous) Acid; 1.3.1.8 Nitrosation of Ketodicarboxylic Esters; 1.3.2 [CNO + CC] Processes; 1.3.2.1 Cycloaddition of Nitrile Oxides (or Their Precursors) to Acetylenic Compounds 327 $a1.3.2.2 Cycloaddition of Nitrile Oxides (or Their Precursors) to Ethylenic Compounds1.3.2.3 Cycloaddition of Nitrile Oxides (or Their Precursors) with Active Methylene Compounds; 1.3.2.4 Cycloaddition of Nitrile Oxides (or Their Precursors) with Sodium Acetylides or Acetylenic Grignard Reagents; 1.3.2.5 Other [CNO + CC] Processes; 1.3.3 [CNO + 2C] Processes: Syntheses from Nitro Derivatives; 1.3.4 [CCNO + C] Processes; 1.3.4.1 Synthesis from Oxime Dilithium Salts and Carboxylic Acid Derivatives; 1.3.4.2 Reaction of a-Chloroketoximes with Ylides; 1.3.5 [CCCN + O] Process 327 $a1.3.6 Cyclization Processes1.3.6.1 [OCCCN] Processes; 1.3.6.2 [CCCON] Processes; 1.3.6.3 [CCNOC] Processes; 1.3.6.4 [CCCNO] Processes; 1.3.7 From Heterocyclic Compounds; 1.3.7.1 From Other 1, 2-Oxazole Derivatives; 1.3.7.2 From Other Heterocycles; 1.4 Chemical Properties; 1.4.1 Protonation and Quaternization; 1.4.2 Complexation; 1.4.2.1 Metallic Complexes; 1.4.2.2 Molecular Complexes; 1.4.3 Reduction Reactions; 1.4.3.1 Hydrogenolytic Ring Cleavage; 1.4.3.2 Reductions without Ring Cleavage; 1.4.4 Oxidation Reactions; 1.4.5 Thermolysis and Photolysis; 1.4.6 Reactions with Nucleophiles 327 $a1.4.6.1 Reactions with Ring Cleavage 330 $aIsoxazoles. Isoxazolines (Dihydroisoxazoles). Isoxazolidines (Tetrahydroisoxazoles). References. Index. 410 0$aChemistry of heterocyclic compounds ;$vv. 49. 606 $aOxazoles 606 $aChemistry 615 0$aOxazoles. 615 0$aChemistry. 676 $a547.592 676 $a547/.59/05 676 $a547/.592 700 $aGru?nanger$b Paolo$0347683 701 $aVita-Finzi$b Paola$051885 701 $aDowling$b James Edward$f1966-$01647680 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910830645203321 996 $aIsoxazoles$93995402 997 $aUNINA