LEADER 05031nam 2200601Ia 450 001 9910830632103321 005 20230422044902.0 010 $a1-281-76409-4 010 $a9786611764098 010 $a3-527-61318-8 010 $a3-527-61319-6 035 $a(CKB)1000000000376608 035 $a(EBL)482249 035 $a(OCoLC)261223818 035 $a(SSID)ssj0000204207 035 $a(PQKBManifestationID)11172937 035 $a(PQKBTitleCode)TC0000204207 035 $a(PQKBWorkID)10196081 035 $a(PQKB)10477916 035 $a(MiAaPQ)EBC482249 035 $a(EXLCZ)991000000000376608 100 $a20000502d2000 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aModern amination methods$b[electronic resource] /$fedited by Alfredo Ricci 210 $aWeinheim ;$aCambridge $cWiley-VCH$dc2000 215 $a1 online resource (288 p.) 300 $aDescription based upon print version of record. 311 $a3-527-29976-9 327 $aModern Amination Methods; Preface; Contents; List of Authors; Chapter 1 Modem Allylic Amination Methods; 1.1 Introduction; 1.2 Nucleophilic Amination of Functionalized Alkenes; 1.2.1 Amination of Allyl Alcohols; 1.2.2 Amination of Allyl halides; 1.2.2.1 Amination of Allyl Halides and Acetates Catalyzed by metal Complexes; 1.2.3 Electrophilic Amination of Non-Functionalized Alkenes; 1.2.4 Amination with Nitrene Complexes; 1.2.5 Amination Based on Ene-Reaction-Like Processes; 1.2.5.1 Type 1 Reactions: Ene Reaction Followed by [2,3]-Sigmatropic Rearrangement; 1.2.5.2 Type 2 Ene Reactions 327 $a1.2.6 Allylic Amination with Ar-NX and a Metal Catalyst1.3 Summary; Acknowledgments; References; Chapter 2 Eletrophilic Amination Routes from Alkenes; 2.1 Introduction; 2.2 Indirect Stoichiometric Amination; 2.2.1 Amination via Organoboron Compounds; 2.2.1.1 Applications to the Synthesis of Primary Amines; 2.2.1.2 Applications to the Synthesis of Secondary Amines; 2.2.1.3 Applications to the Synthesis of Tertiary Amines; 2.2.2 Amination via Organozirconium Compounds; 2.3 Indirect Catalytic Amination; 2.4 Direct Alkene Amination; References 327 $aChapter 3 Stereoselective Electrophilic Amination with Sulfonyloxycarbamates and Azodicarboxylates3.1 Introduction; 3.2 Sulfonyloxycarbamates; 3.2.1 Preparation of N-[(arylsulfonyl)oxy]carbamates; 3.2.2 Stereoselective Synthesis of a-Amino Carboxylic and Phosphonic Acids via Electrophilic Amination with Lithium rerr-Butyl N-(tosyloxy) Carbamate; 3.2.2.1 ?-Amino Carboxylic Acids; 3.2.2.2 ?-Amino Phosphonic Acids; 3.2.3 Reactions of Ethyl N-((p-nitrobenzenesulfonyl)oxy(carbamate with Chiral Enamines and Enol Ethers; 3.3 Dialkylazodicarboxylates 327 $a3.3.1 Electrophilic Amination of Silyl Ketene Acetals3.3.2 Electrophilic Amination of Chiral Amide Enolates; 3.3.3 Electrophilic Amination of Chiral Ester Enolates; 3.3.3.1 ?-Hydroxy Esters; 3.3.3.2 ?-Amino Esters; 3.3.4 Electrophilic Amination of Ketone Enolates; 3.3.5 Electrophilic Amination of Phosphorous-Stabilized Anions; 3.3.5.1 Oxazaphospholanes; 3.3.5.2 Diazaphospholidines; 3.4 Chiral Electrophilic Aminating Reagents; 3.4.1 Azodicarboxylates and Azodicarboxamides; 3.4.2 Chiral Catalytic Approach; 3.5 Conclusion; References 327 $aChapter 4 Glycosylamines as Auxiliaries in Stereoselective Syntheses of Chiral Amino Compounds4.1 Introduction; 4.1.1 Exo Anomeric Effect; 4.1.2 Influence of Coordinating Centers; 4.1.3 Pseudo-Enantiomeric Carbohydrates in Stereoselective Syntheses; 4.2 Syntheses of Amino Acids; 4.2.1 Syntheses of Enantiomerically Pure a-Amino Acids; 4.2.2 Syntheses of Enantiomerically Pure ?-Amino Acids; 4.2.3 Rearrangement Reactions; 4.2.4 Stereoselective Multicomponent Reactions; 4.3 Stereoselective Syntheses of Chiral Heterocycles; 4.3.1 Heterocycles Through Cycloaddition Reactions 327 $a4.3.2 Stereoselective Syntheses of Chiral Piperidines via Addition Reactions to 4-Pyridones 330 $aOrganic compounds containing amino groups are at the center of modern organic chemistry, and are widely used in the pharmaceutical industry, crop protection, natural product chemistry, and in advanced materials. Modern methods for the introduction of the amino group are therefore of major importance to synthetic chemists and product developers.Over the last decade, many methods have been developed to generate new C-N bonds. At the same time, the pharmaceutical and chemical industry was rapidly moving away from the development of racemic compounds to the direct synthesis of enantiomeric 606 $aAmination$xMethodology 606 $aAmines 615 0$aAmination$xMethodology. 615 0$aAmines. 676 $a547.25 676 $a660 701 $aRicci$b Alfredo$f1939-$0249833 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910830632103321 996 $aModern amination methods$93941411 997 $aUNINA