LEADER 09013nam 2200481 450 001 9910830548703321 005 20231004190039.0 010 $a9786610276110 010 $a0-470-01431-8 035 $a(OCoLC)85820671 035 $a(CKB)1000000000376258 035 $a(NjHacI)991000000000376258 035 $a(EXLCZ)991000000000376258 100 $a20231004d2005 uy 0 101 0 $aeng 135 $aur||||||||||| 181 $ctxt$2rdacontent 182 $cc$2rdamedia 183 $acr$2rdacarrier 200 10$aMass Spectrometry of Inorganic and Organometallic Compounds - Tools - Techniques - Tips /$fWilliam Henderson 210 1$aHoboken, New Jersey :$cJohn Wiley & Sons, Inc.,$d2005. 215 $a1 online resource (271 pages) 225 1 $aInorganic chemistry (John Wiley & Sons) 311 $a0-470-85015-9 327 $aPreface -- List of commonly-used abbreviations -- 1 Fundamentals -- 1.1 Introduction -- 1.2 Inlets -- 1.3 Collision-Induced Dissociation -- 1.3.1 Bond dissociation energies from CID studies -- 1.3.2 Presentation of CID data -- 1.4 Detectors -- 1.5 Mass Resolution -- 1.5.1 Mass accuracy -- 1.6 Data Processing -- 1.7 Isotopes -- 1.7.1 Isotopic abundances of the elements -- 1.7.2 Isotope pattern matching -- References -- 2 Mass analysers -- 2.1 Introduction -- 2.2 Sectors -- 2.2.1 MS/MS -- 2.2.2 Summary -- 2.3 Quadrupoles -- 2.3.1 MS/MS -- 2.3.2 Summary -- 2.4 Quadrupole Ion Trap -- 2.4.1 MS/MS and MSn -- 2.4.2 Summary -- 2.5 Time-of-Flight -- 2.5.1 Reflectron instruments -- 2.5.2 Orthogonal TOF (oa-TOF) -- 2.5.3 MS/MS -- 2.5.4 Summary -- 2.6 Fourier Transform Ion Cyclotron Resonance -- 2.6.1 MS/MS -- 2.6.2 Summary -- References -- 3 Ionisation techniques -- 3.1 Introduction -- 3.2 Electron Ionisation -- 3.2.1 Fragmentation of metal-containing compounds -- 3.2.2 Applications -- 3.2.3 Summary -- 3.3 Chemical Ionisation -- 3.3.1 Applications -- 3.3.2 Summary -- 3.4 Field Ionisation/Field Desorption -- 3.4.1 Summary -- 3.5 Plasma Desorption -- 3.5.1 Applications -- 3.5.2 Summary -- 3.6 Fast Atom Bombardment/Liquid Secondary Ion Mass Spectrometry -- 3.6.1 Matrices -- 3.6.2 Ions observed in FAB/LSIMS -- 3.6.3 Applications -- 3.6.4 Summary -- 3.7 Matrix Assisted Laser Desorption Ionisation -- 3.7.1 Matrices -- 3.7.2 MALDI of air-sensitive samples -- 3.7.3 Applications -- 3.7.4 Summary -- 3.8 Inductively Coupled Plasma Mass Spectrometry -- 3.8.1 Applications -- 3.8.2 Summary -- 3.9 Electrospray Ionisation -- 3.9.1 Electrochemistry in the ESI process -- 3.9.2 Multiply-charged species -- 3.9.3 Nanospray -- 3.9.4 ESI MS: Practical considerations -- 3.9.5 Applications -- 3.9.6 Summary -- References -- 4 The ESI MS behaviour of simple inorganic compounds -- 4.1 Introduction -- 4.2 Simple Metal Salts -- 4.2.1 Salts of singly-charged ions, M+X- -- 4.2.2 Salts of multiply-charged ions, e.g. M +(X-)2, M +(X-)3 etc. -- 4.2.3 Negative-ion ESI mass spectra of metal salts -- 4.2.4 ESI MS behaviour of easily-reduced metal ions: copper(II), iron(III) and mercury(II) -- 4.3 Polyanions Formed by Main Group Elements -- 4.4 Oxoanions Formed by Main Group Elements -- 4.5 Borane Anions -- 4.6 Fullerenes -- 4.7 Inorganic Phosphorus Compounds: Phosphoranes and Cyclophosphazenes -- 4.8 Summary -- References -- 5 The ESI MS behaviour of coordination complexes -- 5.1 Introduction -- 5.2 Charged, 'Simple' Coordination Complexes -- 5.2.1 Cationic coordination complexes -- 5.2.2 Anionic metal halide complexes -- 5.2.3 Highly-charged, anionic transition metal complexes - cyanometallate anions -- 5.3 (Neutral) Metal Halide Coordination Complexes -- 5.4 Metal Complexes of Polydentate Oxygen Donor Ligands: Polyethers, Crown Ethers, Cryptands and Calixarenes -- 5.5 Porphyrins and Metalloporphyrins -- 5.6 Metal Alkoxides - Highly Moisture-Sensitive Coordination Compounds -- 5.7 &beta'-Diketonate Complexes -- 5.8 Metal Complexes of Carbohydrates -- 5.9 Metal Complexes of Amino Acids, Peptides and Proteins -- 5.9.1 Amino acids -- 5.9.2 Proteins and peptides -- 5.10 Oxoanions, Polyoxoanions and Related Species -- 5.10.1 Simple transition metal oxoanions -- 5.10.2 Reactivity studies involving molybdate and tungstate ions -- 5.10.3 Polyoxoanions -- 5.10.4 Miscellaneous oxo complexes -- 5.11 Metal Clusters -- 5.12 Compounds with Anionic Sulfur and Selenium Donor Ligands -- 5.12.1 Metal sulfide, selenide and related complexes -- 5.12.2 Metal dithiocarbamate and dithiophosphate complexes -- 5.12.3 Metal thiolate complexes -- 5.13 Characterisation of Metal-Based Anticancer Drugs, their Reaction Products and Metabolites -- 5.13.1 Characterisation of anticancer-active platinum complexes -- 5.13.2 Reactions of platinum anticancer drugs with biomolecules and detection of metabolites -- 5.13.3 Other non-platinum anticancer agents -- 5.14 In situ Formation of Coordination Complexes as an Ionisation Technique -- 5.15 Summary -- References -- 6 The ESI MS behaviour of main group organometallic compounds -- 6.1 Introduction -- 6.2 Organometallic Derivatives of Group 14 Elements -- 6.2.1 Organosilicon compounds -- 6.2.2 Organogermanium compounds -- 6.2.3 Organotin compounds -- 6.2.4 Organolead compounds -- 6.3 Organometallic Derivatives of Group 15 Elements -- 6.3.1 Organophosphorus compounds -- 6.3.2 Organoarsenic compounds -- 6.3.3 Organoantimony and -bismuth compounds -- 6.4 Organometallic Derivatives of Group 16 Elements; Organosulfur, -Selenium and -Tellurium Compounds -- 6.5 Organomercury Compounds -- 6.6 Other Organometallic Derivatives -- 6.7 Summary -- References -- 7 The ESI MS behaviour of transition metal and lanthanide organometallic compounds -- 7.1 Introduction -- 7.2 Metal Carbonyl Complexes -- 7.2.1 Ionic mononuclear metal carbonyl compounds -- 7.2.2 Ionic metal carbonyl clusters -- 7.2.3 Neutral metal carbonyl compounds -- 7.2.4 Oxidation and reduction processes involving metal carbonyls -- 7.2.5 Characterisation of reaction mixtures involving metal carbonyl clusters -- 7.2.6 Fragmentation of transition metal carbonyl clusters; electrospray as a source of bare metal clusters -- 7.2.7 The use of 'Electrospray-friendly' ligands in organometallic chemistry -- 7.3 Metal Isocyanide Complexes -- 7.4 Metal Cyclopentadicnyl and Related Complexes -- 7.4.1 Fenocene-based compounds -- 7.4.2 Use of ferrocene derivatives as elcctroactive derivatisation agents for electrospray ionisation -- 7.4.3 Other metallocene systems -- 7.4.4 Monocyclopentadienyl complexes -- 7.5 Metal ? -allyl Complexes -- 7.6 Metal Arene Complexes -- 7.7 Formation of ?-Hydrocarbon Complexes and their Use as an Ionisation Aid -- 7.8 Metal-Acetylene/acetylide Complexes and Complexes of Metal-Acetylides -- 7.9 Transition Metal ?-Alkyl and Aryl Complexes -- 7.10 Mass Spectrometry of Lanthanide Organometallic Complexes -- 7.11 Summary -- References -- 8 A selection of special topics -- 8.1 Introduction -- 8.2 Characterisation of Dendrimers Using ES1 and MALDI-TOF MS Techniques -- 8.3 Investigating the Formation of Supramolecular Coordination Assemblies Using ESI MS -- 8.4 Using ESI MS as a Tool for Directing Chemical Synthesis: A Case Study Involving the Platinum Metalloligands [Pt2(?-Epsilon)2(PPh3)4] -- 8.4.1 Background -- 8.4.2 Analysis of the metalloligands; formation of protonated species -- 8.4.3 Reactivity of [Pt2(?-Epsilon)2(PPh3)4] towards metal-halide complexes -- 8.5 Applications of ESI MS in the Detection of Reactive Intermediates and Catalyst Screening -- 8.5.1 Detection of intermediates in reactions of organic compounds -- 8.5.2 Detection and chemistry of reaction intermediates in the gas phase -- 8.5.3 Screening of new catalysts using mass spectrometry -- References -- Appendix 1 Naturally occurring isotopes -- Appendix 2 Periodic table of the elements -- Appendix 3 Alphabetical list of elements -- Appendix 4 Glossary of terms -- Appendix 5 Useful sources of information -- Index. 330 $a"Mass spectrometry is one of the many powerful instrumental techniques that are available to the inorganic, coordination or organometallic chemist. This textbook focuses on bringing the subject up to date for those synthetic chemists who use mass spectrometry as an afterthought or as a very minor component of their toolkit of characterisation techniques."--Jacket. 410 0$aInorganic chemistry (John Wiley & Sons) 517 $aMass Spectrometry of Inorganic and Organometallic Compounds 531 $aMASS SPECTROMETRY OF INORGANIC, COORDINATION AND ORGANOMETALLIC COMPOUNDS 606 $aChemistry, Inorganic 606 $aMass spectrometry 606 $aOrganometallic compounds 615 0$aChemistry, Inorganic. 615 0$aMass spectrometry. 615 0$aOrganometallic compounds. 676 $a546 700 $aHenderson$b William$017447 801 0$bNjHacI 801 1$bNjHacl 906 $aBOOK 912 $a9910830548703321 996 $aMass Spectrometry of Inorganic and Organometallic Compounds - Tools - Techniques - Tips$93993686 997 $aUNINA