LEADER 05540nam 22007214a 450 001 9910830519703321 005 20170816123635.0 010 $a1-280-52014-0 010 $a9786610520145 010 $a3-527-60382-4 010 $a3-527-60499-5 035 $a(CKB)1000000000377491 035 $a(EBL)481291 035 $a(SSID)ssj0000224279 035 $a(PQKBManifestationID)11175140 035 $a(PQKBTitleCode)TC0000224279 035 $a(PQKBWorkID)10206956 035 $a(PQKB)11788016 035 $a(MiAaPQ)EBC481291 035 $a(OCoLC)85820509 035 $a(PPN)242594328 035 $a(EXLCZ)991000000000377491 100 $a20060807d2004 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aPolymer brushes$b[electronic resource] $esynthesis, characterization, applications /$fedited by Rigoberto C. Advincula ... [et al.] 210 $aWeinheim $cWiley-VCH$dc2004 215 $a1 online resource (509 p.) 300 $aDescription based upon print version of record. 311 $a3-527-31033-9 320 $aIncludes bibliographical references and index. 327 $aPolymer Brushes; Contents; Preface; List of Contributors; Polymer Brushes: On the Way to Tailor-Made Surfaces; 1 Growth of Polymer Molecules at Surfaces: Introductory Remarks; 2 Coatings: From First Principles to High-Tech Applications; 3 Surface-Coating Techniques; 4 Surface-Attached Polymers; 5 Polymer Brushes: General Features; 6 Theory of Polymer Brushes; 7 Synthesis of Polymer Brushes; 8 Polymer Brushes as Functional Materials; 9 Microstructured Polymer Brushes; 10 Surface-Initiated Polymerization: The Overall Picture; Part I Synthesis; 1 Recent Advances in Polymer Brush Synthesis 327 $a1.1 Introduction1.2 "Grafting To" Synthesis Technique; 1.3 "Grafting From" Synthesis Technique; 2 Polymer Brushes by Atom Transfer Radical Polymerization; 2.1 Introduction; 2.2 Polymer Brushes on Flat Surfaces; 2.2.1 Controlled ATRP from Flat Surfaces; 2.2.2 Block Copolymer Brushes on Flat Surfaces; 2.2.3 Stimuli-Responsive Ultrathin Films from "Grafting To" Approach; 2.3 Polymer Brushes from Particles; 2.3.1 Spherical Brushes from Inorganic Colloids; 2.3.2 Multilayered Core-Shell Colloids; 2.3.3 Imaging of Individual Spherical Brushes; 2.3.4 Modification of Carbon Black Fillers 327 $a2.4 Molecular Brushes2.4.1 Synthesis of Molecular Brushes from Linear Polymeric Macroinitiators; 2.4.2 Molecular Brushes from Dendritic Macroinitiators; 3 Polymer Brushes by Atom Transfer Radical Polymerization Initiated from Macroinitiator Synthesized on the Surface; 3.1 Introduction; 3.2 Experimental; 3.3 Results and Discussion; 3.3.1 Synthesis of Macroinitiator for ATRP; 3.3.2 ATRP from Macroinitiator; 4 Synthesis of Polypeptide Brushes; 4.1 Introduction; 4.2 Preparation of Peptide Brushes by "Grafting To"; 4.3 Preparation of Peptide Brushes by Grafting From Polymerization 327 $a4.3.1 Mechanisms of NCA Polymerization4.3.2 Amine-Initiated Grafting From Polymerizations in Solution; 4.3.3 Other Techniques for Amine-Initiated Grafting From Polymerizations; 4.4 Preparation of Peptide Brushes by Living Grafting From Polymerization; 4.4.1 Copolymerization Approach; 4.4.2 Alloc-Amide Approach; 5 Bottle Brush Brushes: Ring-Opening Polymerization of Lactide from Poly(hydroxyethyl methacrylate) Surfaces; 5.1 Introduction; 5.2 Synthesis of PHEMA-g-PLA; 5.3 Conclusions and Implications for Future Studies; 5.4 Experimental Section; 5.4.1 Materials 327 $a5.4.2 Preparation of Monomer Solution and Substrates5.4.3 Ring-Opening Polymerization from PHEMA Surface; 5.4.4 Analytical Methods; 6 Preparation of Well-Defined Organic-Inorganic Hybrid Nanostructures using Living Cationic Surface-Initiated Polymerization from Silica Nanoparticles; 6.1 Introduction; 6.2 Experimental Section; 6.2.1 Materials; 6.2.2 Characterization; 6.2.3 Synthesis of Immobilized Macroinitiators; 6.3 Results and Discussion; 6.3.1 Living Cationic Surface-Initiated Polymerization of IB from Silica Nanoparticles in the Presence of Sacrificial Free Initiator 327 $a6.3.2 Living Cationic Surface-Initiated Polymerization of IB from Silica Macroinitiators 330 $aMaterials scientists, polymer chemists, surface physicists and materials engineers will find this book a complete and detailed treatise on the field of polymer brushes, their synthesis, characterization and manifold applications. In a first section, the various synthetic pathways and different surface materials are introduced and explained, followed by a second section covering important aspects of characterization and analysis in both flat surfaces and particles. These specific surface initiated polymerization (SIP) systems such as linear polymers, homopolymers, block copolymers, and hyperbra 606 $aPolymerization 606 $aPolymers$xSurfaces 606 $aThin films 606 $aPolyme?res$xSurfaces 606 $aPolyme?risation 606 $aCouches minces 615 0$aPolymerization. 615 0$aPolymers$xSurfaces. 615 0$aThin films. 615 6$aPolyme?res$xSurfaces. 615 6$aPolyme?risation. 615 6$aCouches minces. 676 $a620.192 676 $a668.9 701 $aAdvincula$b Rigoberto C$01609889 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910830519703321 996 $aPolymer brushes$93937365 997 $aUNINA