LEADER 05141nam 2200589 a 450 001 9910830503503321 005 20230721032855.0 010 $a1-281-75190-1 010 $a9786611751906 010 $a0-470-37794-1 010 $a0-470-37793-3 035 $a(CKB)1000000000539652 035 $a(EBL)353340 035 $a(OCoLC)437219518 035 $a(SSID)ssj0000227201 035 $a(PQKBManifestationID)11202662 035 $a(PQKBTitleCode)TC0000227201 035 $a(PQKBWorkID)10264297 035 $a(PQKB)10214676 035 $a(MiAaPQ)EBC353340 035 $a(EXLCZ)991000000000539652 100 $a20080124d2008 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aPrinciples and applications of emulsion polymerization$b[electronic resource] /$fChorng-Shyan Chern 210 $aHoboken, N.J. $cWiley$dc2008 215 $a1 online resource (268 p.) 300 $aDescription based upon print version of record. 311 $a0-470-12431-8 320 $aIncludes bibliographical references and index. 327 $aPRINCIPLES AND APPLICATIONS OF EMULSION POLYMERIZATION; CONTENTS; Preface; 1 Introduction; 1.1 Free Radical Polymerization; 1.1.1 Free Radical Polymerization Mechanisms; 1.1.2 Free Radical Polymerization Kinetics; 1.2 Emulsion Polymerization; 1.2.1 Conventional Emulsion Polymerization; 1.2.2 Emulsion Polymerization Processes; 1.2.3 Miniemulsion Polymerization; 1.2.4 Microemulsion Polymerization; 1.2.5 Inverse Emulsion Polymerization; 1.3 Colloidal Stability; 1.3.1 A Critical but Often Ignored Issue; 1.3.2 Electrostatic Interactions; 1.3.3 Steric Interactions; 1.3.4 Mechanical Stability 327 $a1.4 Some Performance Properties for Industrial Applications1.4.1 Rheology; 1.4.2 Film Formation; References; 2 Interfacial Phenomena; 2.1 Thermodynamic Consideration; 2.1.1 Emulsification of Oil in Water; 2.1.2 Interfaces; 2.1.3 Surfactant Molecules Adsorbed at an Interface; 2.2 Surfactants; 2.2.1 Critical Micelle Concentration (CMC); 2.2.2 Hydrophile-Lipophile Balance (HLB); 2.2.3 Solubility Parameter; 2.3 Colloidal Stability; 2.3.1 Van der Waals Forces; 2.3.2 Electrostatic Interactions; 2.3.3 Steric Interactions; 2.3.4 Kinetics of Flocculation; References; 3 Particle Nucleation Mechanisms 327 $a3.1 Micellar Nucleation3.1.1 Harkins-Smith-Ewart Theory; 3.1.2 Competitive Absorption of Free Radicals by Micelles and Particle Nuclei; 3.2 Homogeneous Nucleation; 3.2.1 Formation of Particle Nuclei in the Continuous Aqueous Phase; 3.2.2 Hansen-Ugelstad-Fitch-Tsai (HUFT) Model; 3.3 Coagulative Nucleation; 3.3.1 General Features of Coagulative Nucleation; 3.3.2 Coagulative Nucleation Model Development; 3.4 Mixed Mode of Particle Nucleation Mechanisms; 3.5 Surfactant-Free Emulsion Polymerization; 3.6 Experimental Work on Particle Nucleation; 3.6.1 A Dilemma about Particle Nucleation Mechanisms 327 $a3.6.2 Some Representative Experimental Data of Particle Nucleation3.6.3 Some Potential Techniques for Studying Particle Nucleation; 3.6.4 Effects of Surfactant Concentration on Particle Nucleation; 3.7 Nonionic and Mixed Surfactant Systems; 3.7.1 Nonionic Surfactant Systems; 3.7.2 Mixed Anionic and Nonionic Surfactant Systems; References; 4 Emulsion Polymerization Kinetics; 4.1 Emulsion Polymerization Kinetics; 4.1.1 Smith-Ewart Theory; 4.1.2 Pioneering Kinetic Models for Predicting Average Number of Free Radicals per Particle; 4.2 Absorption of Free Radicals by Latex Particles 327 $a4.2.1 Collision- and Diffusion-Controlled Models4.2.2 Propagation-Controlled Model; 4.2.3 Some Controversial Issues; 4.3 Desorption of Free Radicals Out of Latex Particles; 4.3.1 Desorption of Free Radicals in Emulsion Homopolymerization Systems; 4.3.2 Desorption of Free Radicals in Emulsion Copolymerization Systems; 4.3.3 Effect of Interfacial Properties on Desorption of Free Radicals; 4.4 Growth of Latex Particles; 4.4.1 Thermodynamic Consideration; 4.4.2 Concentrations of Comonomers in Emulsion Copolymerization Systems; 4.4.3 Competitive Growth of Latex Particles 327 $a4.5 Polymer Molecular Weight 330 $aUp-to-date coverage of methods of emulsion polymerization This book provides a comprehensive reference on emulsion polymerization methods,focusing on the fundamental mechanisms and kinetics of each process, as well as howthey can be applied to the manufacture of environmentally friendly polymeric materials.Topics covered include: Conventional emulsion polymerization Miniemulsion polymerization Microemulsion polymerization Industrial emulsion polymerization processes (primarily the semibatch and continuous reactions systems) The role of various colloidal 606 $aEmulsion polymerization 615 0$aEmulsion polymerization. 676 $a668.9 676 $a668.92 700 $aChern$b Chorng-Shyan$01720606 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910830503503321 996 $aPrinciples and applications of emulsion polymerization$94119425 997 $aUNINA LEADER 01137cam0-22003851i-450 001 990001446970403321 005 20250616131137.0 010 $a88-339-5099-9 035 $a000144697 035 $aFED01000144697 035 $a(Aleph)000144697FED01 100 $a20001205d1984----km-y0itay50------ba 101 0 $aita 102 $aIT 105 $aa 001yy 200 1 $aCristallografia mineralogica$fStefano Bonatti, Marco Franzini 205 $a2. ed. 210 $aTorino$cBoringhieri$d1984 215 $a361 p.$cill.$d24 cm 225 1 $aTesti e manuali della scienza contemporanea$iSerie di geologia 610 0 $aCristallografia 676 $a549.18$v20$zita 700 1$aBonatti,$bStefano$f<1902-1968>$062750 701 1$aFranzini,$bMarco$062751 801 0$aIT$bUNINA$gREICAT$2UNIMARC 901 $aBK 912 $a990001446970403321 952 $aEDISU-548-1$b20368$fSC1 952 $aEDISU-548-1A$b20369$fSC1 952 $aEDISU-548-1B$b20370$fSC1 952 $a549.18 BONS 1984$b00/0244/25$fFAGBC 959 $aSC1 959 $aFAGBC 996 $aCristallografia mineralogica$9366709 997 $aUNINA