LEADER 04737nam 2200625 450 001 9910830498103321 005 20230109082824.0 010 $a1-280-52033-7 010 $a3-527-60524-X 010 $a9786610520336 010 $a3-527-60162-7 035 $a(CKB)1000000000019281 035 $a(EBL)481655 035 $a(OCoLC)68904728 035 $a(SSID)ssj0000145161 035 $a(PQKBManifestationID)11158535 035 $a(PQKBTitleCode)TC0000145161 035 $a(PQKBWorkID)10156492 035 $a(PQKB)11392096 035 $a(MiAaPQ)EBC481655 035 $a(MiAaPQ)EBC7076253 035 $a(Au-PeEL)EBL7076253 035 $a(EXLCZ)991000000000019281 100 $a20230109d2003 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aElectron spin resonance spectroscopy of organic radicals /$fFabian Gerson, Walter Huber 210 1$aWeinheim, Germany :$cWiley-VCH GmbH,$d[2003] 210 4$dİ2003 215 $a1 online resource (482 p.) 300 $aDescription based upon print version of record. 311 $a3-527-60604-1 311 $a3-527-30275-1 320 $aIncludes bibliographical references and index. 327 $aElectron Spin Resonance Spectroscopy of Organic Radicals; Contents; Preface; Abbreviations and Symbols; A General Part; 1 Physical Fundamentals of Electron Spin Resonance; 1.1 Spin and Magnetic Moment of Electron; 1.2 Zeeman Splitting and Resonance Condition; 1.3 Spin-lattice Relaxation; 1.4 Line-width and Line-form; 2 Paramagnetic Organic Species and Their Generation; 2.1 Spin Multiplicity; 2.2 Neutral Radicals; 2.3 Radical Ions; 2.4 Triplets: Electron-Electron Magnetic Interaction; 3 Electron-Nuclear Magnetic Interaction; 3.1 Nuclear Magnetism; 3.2 Hyperfine Splitting of ESR Signal 327 $a4 Spin Density, Spin Population, Spin Polarization, and Spin Delocalization4.1 Concepts; 4.2 ? Radicals; 4.3 ? Radicals; 4.4 Triplet States; 4.5 Calculations of Spin Populations; 5 Multiresonance; 5.1 Historical Note; 5.2 ENDOR; 5.3 TRIPLE Resonance; 5.4 ELDOR; 6 Taking and Analyzing ESR Spectra; 6.1 Instrumentation; 6.2 g(e) Factor; 6.3 Optimal Conditions; 6.4 Unravelling Hyperfine Pattern; 6.5 Assignment and Sign of Coupling Constants; 6.6 Ion Pairing; 6.7 Intramolecular Dynamic Processes; B Special Part; 7 Organic Radicals Centered on One, Two, or Three Atoms 327 $a7.1 C-, N-, and O-centered Radicals7.2 Si-, P-, and S-centered Radicals; 7.3 CC-, NN-, and OO-centered Radicals; 7.4 NO- and NO(2)-centered Radicals; 7.5 PO-, PP-, SO-, SS-, and SO(2)-centered Radicals; 8 Conjugated Hydrocarbon Radicals; 8.1 Theoretical Introduction; 8.2 Odd Alternant Radicals; 8.3 Odd Nonalternant Radicals and Radical Dianions; 8.4 Even Alternant Radical Ions; 8.5 Even Nonalternant Radical Ions; 8.6 Radicals and Radical Ions with a Perturbed ? Perimeter; 8.7 Radical Ions of Phanes; 8.8 Radical Ions of Radialenes; 9 Conjugated Radicals with Heteroatoms; 9.1 Neutral Radicals 327 $a9.2 Radical Anions of Electron Acceptors9.3 Radical Cations of Electron Donors; 9.4 Radical Cations with Special Structures; 9.5 Radical Ions of Multi-redox Systems; 10 Saturated Hydrocarbon Radicals; 10.1 Radical Cations of Alkanes; 10.2 Structurally Modified Radical Cations; 11 Biradicals and Triplet-state Molecules; 11.1 Biradicals; 11.2 Molecules in Photoexcited Triplet State; 11.3 Molecules in Ground or Thermally Accessible Triplet State; Appendices; A.1 Nitroxyls as Spin Labels and Spin Adducts; A.2 Hyperfine Splitting by Alkali-Metal Nuclei in Counterions of Radical Anions; References 327 $aIndex 330 $aElectron spin resonance spectroscopy is the method used to determine the structure and life expectancy of a number of radicals. Written by Fabian Gerson and Walter Huber, top experts in the field of electron spin resonance spectroscopy, this book offers a compact yet readily comprehensible introduction to the modern world of ESR. Thanks to its comprehensive coverage, ranging from fundamental theory right up to the treatment of all important classes of organic radicals and triplet-state molecules that can be analyzed using ESR spectroscopy, this unique book is suitable for users in both researc 606 $aElectron paramagnetic resonance spectroscopy 615 0$aElectron paramagnetic resonance spectroscopy. 676 $a543.67 700 $aGerson$b Fabian$01622662 702 $aHuber$b Walter$f1949- 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910830498103321 996 $aElectron spin resonance spectroscopy of organic radicals$93956655 997 $aUNINA