LEADER 05210nam 2200601 a 450 001 9910830452603321 005 20230721005119.0 010 $a1-282-11300-3 010 $a9786612113000 010 $a0-470-42160-6 010 $a0-470-42154-1 035 $a(CKB)1000000000719446 035 $a(EBL)427573 035 $a(SSID)ssj0000253711 035 $a(PQKBManifestationID)11195521 035 $a(PQKBTitleCode)TC0000253711 035 $a(PQKBWorkID)10205097 035 $a(PQKB)11414385 035 $a(MiAaPQ)EBC427573 035 $a(OCoLC)352829607 035 $a(EXLCZ)991000000000719446 100 $a20080613d2009 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt$2rdacontent 182 $cc$2rdamedia 183 $acr$2rdacarrier 200 00$aSuperacid chemistry$b[electronic resource] /$fGeorge A. Olah ... [et al.] 205 $a2nd ed. 210 $aHoboken, N.J. $cWiley$dc2009 215 $a1 online resource (872 p.) 300 $aRev. ed. of: Superacids / George A. Olah, G.K. Surya Prakash, Jean Sommer. c1985 311 $a0-471-59668-X 320 $aIncludes bibliographical references and index 327 $aSUPERACID CHEMISTRY; CONTENTS; Preface to the Second Edition; Preface to the First Edition; 1. General Aspects; 1.1. Defining Acidity; 1.1.1. Acids and Bases; 1.1.2. The pH Scale; 1.1.3. Acidity Functions; 1.2. Definition of Superacids; 1.2.1. Range of Acidities; 1.3. Types of Superacids; 1.3.1. Primary Superacids; 1.3.2. Binary Superacids; 1.3.3. Ternary Superacids; 1.3.4. Solid Superacids; 1.4. Experimental Techniques for Acidity Measurements (Protic Acids); 1.4.1. Spectrophotometric Method; 1.4.2. Nuclear Magnetic Resonance Methods; 1.4.2.1. Chemical Shift Measurements 327 $a1.4.2.2. Exchange Rate Measurements Based on Line-Shape Analysis (DNMR: Dynamic Nuclear Magnetic Resonance)1.4.3. Electrochemical Methods; 1.4.4. Chemical Kinetics; 1.4.5. Heats of Protonation of Weak Bases; 1.4.6. Theoretical Calculations and Superacidity in the Gas Phase; 1.4.7. Estimating the Strength of Lewis Acids; 1.4.8. Experimental Techniques Applied to Solid Acids; References; 2. Superacid Systems; 2.1. Primary Superacids; 2.1.1. Brønsted Superacids; 2.1.1.1 Perchloric Acid; 2.1.1.2. Chlorosulfuric Acid; 2.1.1.3. Fluorosulfuric Acid; 2.1.1.4. Perfluoroalkanesulfonic Acids 327 $a2.1.1.5. Hydrogen Fluoride2.1.1.6. Carborane Superacids H(CB(11)HR(5)X(6)); 2.1.2. Lewis Superacids; 2.1.2.1. Antimony Pentafluoride; 2.1.2.2. Arsenic Pentafluoride; 2.1.2.3. Phosphorus Pentafluoride; 2.1.2.4. Tantalum and Niobium Pentafluoride; 2.1.2.5. Boron Trifluoride; 2.1.2.6. Tris(pentafluorophenyl) Borane; 2.1.2.7. Boron Tris(trifluoromethanesulfonate); 2.1.2.8. Aprotic Organic Superacids (Vol'pin's Systems); 2.2. Binary Superacids; 2.2.1. Binary Brønsted Superacids; 2.2.1.1. Hydrogen Fluoride-Fluorosulfuric Acid; 2.2.1.2. Hydrogen Fluoride-Trifluoromethanesulfonic Acid 327 $a2.2.1.3. Tetra(Hydrogen Sulfato)Boric Acid-Sulfuric Acid2.2.2. Conjugate Brønsted-Lewis Superacids; 2.2.2.1. Oleums-Polysulfuric Acids; 2.2.2.2. Fluorosulfuric Acid-Antimony Pentafluoride (""Magic Acid""); 2.2.2.3. Fluorosulfuric Acid-Sulfur Trioxide; 2.2.2.4. HSO(3)F-MF(n)(SO(3)F)(5-n); n = 3, 4, M = Nb, Ta; 2.2.2.5. Fluorosulfuric Acid-Arsenic Pentafluoride; 2.2.2.6. Perfluoroalkanesulfonic Acid-Based Systems; 2.2.2.7. Hydrogen Fluoride-Antimony Pentafluoride (Fluoroantimonic Acid); 2.2.2.8. Hydrogen Fluoride- Phosphorus Pentafluoride; 2.2.2.9. Hydrogen Fluoride-Tantalum Pentafluoride 327 $a2.2.2.10. Hydrogen Fluoride-Boron Trifluoride (Tetrafluoroboric Acid)2.2.2.11. Conjugate Friedel-Crafts Acids (HX-AlX(3), etc.); 2.3. Ternary Superacids; 2.3.1. HSO(3)F-HF-SbF(5); 2.3.2. HSO(3)F-HF-CF(3)SO(3)H; 2.3.3. CF(3)SO(3)H-HF-Lewis Acid; 2.3.4. HSO(3)F-SbF(5)-SO(3); 2.4. Solid Superacids; 2.4.1. Zeolitic Acids; 2.4.2. Polymeric Resin Sulfonic Acids; 2.4.2.1. Lewis Acid-Complexed Sulfonic Acid Resins; 2.4.2.2. Perfluorinated Polymer Resin Acids; 2.4.3. Enhanced Acidity Solids; 2.4.3.1. Brønsted Acid-Modified Metal Oxides: TiO(2)-H(2)SO(4); ZrO(2)-H(2)SO(4) 327 $a2.4.3.2. Lewis Acid-Modified Metal Oxides and Mixed Oxides 330 $aThe chemistry of superacids has developed in the last two decades into a field of growing interest and importance. Now available in a new expanded second edition, this definitive work on superacids offers a comprehensive review of superacids and discusses the development of new superacid systems and applications of superacids in the promotion of unusual reactions. Covering Bronsted and Leurs superacids, solid superacids, carbocations, heterocations, and catalyzed reactions, this timely volume is invaluable to professionals, faculty, and graduate students in organic, inorganic, and physical che 606 $aSuperacids 615 0$aSuperacids. 676 $a546.24 676 $a546/.24 701 $aOlah$b George A$g(George Andrew),$f1927-2017$016147 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910830452603321 996 $aSuperacid chemistry$93954598 997 $aUNINA