LEADER 05213nam 2200625Ia 450 001 9910830407203321 005 20230422044813.0 010 $a1-281-76420-5 010 $a9786611764203 010 $a3-527-61360-9 010 $a3-527-61361-7 035 $a(CKB)1000000000377521 035 $a(EBL)481622 035 $a(OCoLC)261345490 035 $a(SSID)ssj0000253932 035 $a(PQKBManifestationID)11216071 035 $a(PQKBTitleCode)TC0000253932 035 $a(PQKBWorkID)10188087 035 $a(PQKB)11440994 035 $a(MiAaPQ)EBC481622 035 $a(EXLCZ)991000000000377521 100 $a19991122d1999 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aSupramolecular electrochemistry$b[electronic resource] /$fAngel Kaifer, Marielle Go?mez-Kaifer 210 $aWeinheim ;$aNew York $cWiley-VCH$dc1999 215 $a1 online resource (257 p.) 300 $aDescription based upon print version of record. 311 $a3-527-29597-6 320 $aIncludes bibliographical references and index. 327 $aSupramolecular Electrochemistry; Contents; 1 Fundamentals of Electrochemical Theory; 1.1 Cell potentials and Electrochemical Reactions; 1.2 Mass Transport; 1.3 Kinetics of Electrode Reactions; 1.4 References; 2 An Overview of Electrochemical Techniques; 2.1 Faradaic and Nonfaradaic Currents; 2.2 Classification of Electrochemical Techniques; 2.3 Two-Electrode and Three-Electrode Cells; 2.4 An Overview of Voltammetric Techniques; 2.5 The Nernst Equation in Potential Controlled Experiments; 2.6 Common Reversible Redox Couples; 2.7 References; 3 Potential Step Experiments 327 $a3.1 The Cottrell Experiment3.2 Chronoamperometry; 3.3 Chronocoulometry; 3.4 Bulk Electrolysis; 3.5 References; 4 Potential Sweep Methods; 4.1 Linear Sweep Voltammetry; 4.2 Cyclic Voltammetry; 4.3 Pulsed Voltammetric Techniques; 4.4 References; 5 Ultramicroelectrodes and Their Applications; 5.1 Characteristics of Ultramicroelectrodes; 5.2 Scanning Electrochemical Microscopy; 5.3 Electrochemistry of Single Molecules; 5.4 Conclusions and Outlook; 5.5 References; 6 Practical Experimental Methods; 6.1 Electrodes and Working Electrode Surfaces; 6.2 Solvents and Supporting Electrolytes 327 $a6.3 Basic Cell Design6.4 Vacuum Methods; 6.5 References; 7 Digital Simulation; 7.1 Principles of Digital Simulation; 7.2 Simulations of the CV Behavior of a Simple Redox Couple; 7.3 Simulation of Electron Transfer Reactions Coupled to Homogeneous Chemical Processes; 7.4 References; 8 Electrochemical Considerations for Supramolecular Systems; 8.1 Intramolecular Forces under Electrochemical Conditions; 8.2 Self-Assembly and Fixed Association in Supramolecular Structures: Implications for Reversible Redox-Switching; 8.3 Systems Involving Multiple Identical or Non-Identical Redox- Active Moieties 327 $a8.4 References9 Electrochemical Switching; 9.1 The Concept of Electrochemical Switching; 9.2 Switchable Binding in a Redox-Active Cation Host; 9.3 Electrochemical Switching as a Means of Controlling Molecular Devices and Other Structures; 9.4 References; 10 Electrochemically Switchable Cation and Anion Binding; 10.1 Electrochemically-Switched Cation-Binding Systems; 10.2 Electrochemically-Switched Anion Binding; 10.3 References; 11 Redox-Switchable Cyclophanes and Other Molecular Receptors; 11.1 Early Cyclophane Studies and Metallocyclophanes 327 $a11.2 Redox-Active Cyclophanes as Molecular Receptors11.3 Viologen Based Cyclophanes- the Ideal ?-Acceptor Host; 11.4 Electroinactive Cyclophane Hosts and Their Binding of Redox- Switchable Guests; 11.5 Other Molecular Receptors; 11.6 Conclusions; 11.7 References; 12 Electroactive Intertwined Structures; 12.1 Electroactive Cyclodextrin-Based Rotaxanes and Pseudorotaxanes; 12.2 Templated Metallocatenates and Metallorotaxanes; 12.3 Catenanes Based on ?-Donor and ?-Acceptor Interactions; 12.4 Rotaxanes and Shuttles Based on ?-Donor/ Acceptor Chemistry 327 $a12.5 Perspectives on the Future of Molecular Devices 330 $aThis book describes the electrochemical behavior of supramolecular systems. Special emphasis will be given to the electrochemistry of host-guest complexes, monolayer and multilayer assemblies, dendrimers, and other supramolecular assemblies. A fundamental theme throughout the book is to explore the effects that supramolecular structure exerts on the thermodynamics and kinetics of electrochemical reactions. Conversely, attention will be placed to the various ways in which electrochemical or redox conversions can be utilized to control or affect the structure or properties of supramolecular syst 606 $aMacromolecules 606 $aElectrochemistry 615 0$aMacromolecules. 615 0$aElectrochemistry. 676 $a541.3/7 676 $a541.37 700 $aKaifer$b Angel E.$f1955-$0532459 701 $aGo?mez-Kaifer$b Marielle$0736222 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910830407203321 996 $aSupramolecular electrochemistry$91454755 997 $aUNINA