LEADER 05282nam 2200601 a 450 001 9910830359003321 005 20230421041507.0 010 $a1-282-81728-0 010 $a9786612817281 010 $a0-470-93801-3 010 $a1-59124-597-4 010 $a0-470-93800-5 035 $a(CKB)111086367652174 035 $a(EBL)588856 035 $a(OCoLC)56935336 035 $a(SSID)ssj0000072127 035 $a(PQKBManifestationID)11123534 035 $a(PQKBTitleCode)TC0000072127 035 $a(PQKBWorkID)10091635 035 $a(PQKB)11102217 035 $a(MiAaPQ)EBC588856 035 $a(EXLCZ)99111086367652174 100 $a19950906d1995 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aGuidelines for safe storage and handling of reactive materials$b[electronic resource] 210 $aNew York $cAmerican Institute of Chemical Engineers$d1995 215 $a1 online resource (386 p.) 300 $aDescription based upon print version of record. 311 $a0-8169-0629-7 320 $aIncludes bibliographical references and index. 327 $aGuidelines for Safe Storage and Handling of Reactive Materials; Contents; Preface; Acknowledgments; Acronyms; Introduction; 1. Chemical Reactivity Hazards; 1.1. Framework for Understanding Reactivity Hazards; 1.1.1. Grouping of Reactivity Hazards into General Categories; 1.1.2. Key Parameters That Drive Reactions; 1.1.3. Types of Runaway Reactions; 1.1.4. How Reactive Chemical Storage and Handling Accidents are Initiated; 1.2. Self-Reactive Polymerizing Chemicals; 1.2.1. Thermal Instability; 1.2.2. Induction Time; 1.2.3. Example; 1.3. Self-Reactive Decomposing Chemicals; 1.3.1. Peroxides 327 $a1.3.2. Self-Accelerating Decomposition Temperature1.3.3. Predicting Instability Potential; 1.3.4. Deflagration and Detonation of Pure Material; 1.3.5. Slow Gas-Forming Reactions; 1.3.6. Heat of Compression; 1.3.7. Minimum Pressures for Vapor Decomposition; 1.3.8. Shock Sensitivity; 1.3.9. Examples of Shock Sensitivity; 1.4. Self-Reactive Rearranging Chemicals; 1.4.1. Isomerization; 1.4.2. Disproportionation; 1.5. Reactivity with Oxygen; 1.5.1. Spontaneous Ignition and Pyrophoricity; 1.5.2. Pyrophoricity versus Hypergolic Properties; 1.5.3. Accumulation and Explosion of Pyrophoric Materials 327 $a1.5.4. Competition between Air and Atmospheric Moisture1.5.5. Peroxide Formation; 1.6. Reactivity with Water; 1.6.1. Water Reactivity: Fast and Slow Reactions; 1.6.2. Water-Reactive Structures; 1.7. Reactivity with Other Common Substances; 1.7.1. Reactions with Metals; 1.7.2. Surface Area Effects; 1.7.3. Catalyst Deactivation and Surface Passivation; 1.8. Reactive with Other Chemicals: Incompatibility; 1.8.1. Oxidizing and Reducing Properties; 1.8.2. Acidic and Basic Properties; 1.8.3. Formation of Unstable Materials; 1.8.4. Thermite-Type Reactions 327 $a1.8.5. Incompatibility with Heat Transfer Fluids and Refrigerants1.8.6. Adsorbents; References; 2. Chemical Reactivity Classifications; 2.1. NFPA Reactivity Hazard Signal; 2.1.1. NFPA 704 Rating System for Overall Reactivity; 2.1.2. Definitions for Reactivity Signal Ratings; 2.1.3. Reactivity Hazards Not Identified by NFPA 704; 2.1.4. NFPA Reactivity Ratings for Specific Chemicals; 2.2. NPCA Hazardous Materials Identification System; 2.3. Classifications of Organic Peroxides; 2.3.1. SPI 19A Classification of Organic Peroxides; 2.3.2. NFPA 43B Classification of Organic Peroxides 327 $a2.4. Classification of Materials That Form Peroxides2.5. Classification of Water-Reactive Materials; 2.5.1. Materials That React Violently with Water; 2.5.2. Materials That React Slowly with Water; References; 3. Materials Assessment; 3.1. Prior Experience Review; 3.1.1. Common Knowledge; 3.1.2. Analogy; 3.1.3. Safety Data and Literature; 3.2. Theoretical Evaluations; 3.2.1. Unstable Atomic Groups; 3.2.2. Oxygen Balance; 3.2.3 Thermodynamics: Heat of Formation; 3.2.4. Thermodynamics: Heats of Reaction and Self-Reaction; 3.2.5. Thermodynamics: Equilibrium Considerations; 3.2.6. CHETAH 327 $a3.2.7. Example Evaluation 330 $aWith new and growing interest in dealing with the hazards of reactive chemicals, this book offers guidelines that can significantly reduce the risk or mitigate the severity of accidents associated with storing and handling reactive materials. Necessary elements of a reliable system to prevent equipment or human failures that might lead to a reactive chemical incident are sound and responsible management policies, together with a combination of superior siting, design, fabrication, erection, inspection, monitoring, maintenance, operations and maintenance of facilities. These Guidelines deal wit 606 $aChemicals$xStorage$xSafety measures 615 0$aChemicals$xStorage$xSafety measures. 676 $a660.2804 676 $a660/.2804 712 02$aAmerican Institute of Chemical Engineers.$bCenter for Chemical process Safety. 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910830359003321 996 $aGuidelines for safe storage and handling of reactive materials$92139175 997 $aUNINA LEADER 01299nam 2200337 n 450 001 9910437209003321 005 20230414064808.0 010 $a1-7281-1560-4 035 $a(CKB)5410000000003169 035 $a(NjHacI)995410000000003169 035 $a(EXLCZ)995410000000003169 100 $a20230414d2019 uu 0 101 0 $aeng 135 $aur||||||||||| 181 $ctxt$2rdacontent 182 $cc$2rdamedia 183 $acr$2rdacarrier 200 10$a2019 19th International Symposium on Electromagnetic Fields in Mechatronics, Electrical and Electronic Engineering (ISEF) /$fInstitute of Electrical and Electronics Engineers 210 1$aPiscataway, New Jersey :$cInstitute of Electrical and Electronics Engineers,$d2019. 215 $a1 online resource 311 $a1-7281-1561-2 517 $a2019 19th International Symposium on Electromagnetic Fields in Mechatronics, Electrical and Electronic Engineering 606 $aElectromagnetic fields$vCongresses 615 0$aElectromagnetic fields 676 $a530 801 0$bNjHacI 801 1$bNjHacl 906 $aPROCEEDING 912 $a9910437209003321 996 $a2019 19th International Symposium on Electromagnetic Fields in Mechatronics, Electrical and Electronic Engineering (ISEF)$92506714 997 $aUNINA