LEADER 05077nam 2200625 a 450 001 9910830323603321 005 20230725053003.0 010 $a3-527-63654-4 010 $a1-283-28329-8 010 $a9786613283290 010 $a3-527-63655-2 010 $a3-527-63653-6 035 $a(CKB)3460000000000040 035 $a(EBL)693858 035 $a(SSID)ssj0000506320 035 $a(PQKBManifestationID)11332875 035 $a(PQKBTitleCode)TC0000506320 035 $a(PQKBWorkID)10513824 035 $a(PQKB)10177294 035 $a(MiAaPQ)EBC693858 035 $a(OCoLC)711782190 035 $a(EXLCZ)993460000000000040 100 $a20111111d2011 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aGlasses and the glass transition$b[electronic resource] /$fJu?rn W.P. Schmelzer and Ivan S. Gutzow ; with the collaboration of Oleg V. Mazurin ... [et al.] 210 $aWeinheim Germany $cWiley-VCH$d2011 215 $a1 online resource (430 p.) 300 $aDescription based upon print version of record. 311 $a3-527-40968-8 320 $aIncludes bibliographical references and index. 327 $aGlasses and the Glass Transition; Foreword; Contents; Preface; Contributors; 1 Introduction; 2 Basic Properties and the Nature of Glasses: an Overview; 2.1 Glasses: First Attempts at a Classification; 2.2 Basic Thermodynamics; 2.2.1 The Fundamental Laws of Classical Thermodynamics and Consequences; 2.2.2 Thermodynamic Evolution Criteria, Stability Conditionsand the Thermodynamic Description of Nonequilibrium States; 2.2.3 Phases and Phase Transitions:Gibbs's Phase Rule, Ehrenfest's Classification, and the Landau Theory 327 $a2.3 Crystallization, Glass Transition and Devitrification of Glass-Forming Melts: an Overview of Experimental Results2.4 The Viscosity of Glass-Forming Melts; 2.4.1 Temperature Dependence of the Viscosity; 2.4.2 Significance of Viscosity in the Glass Transition; 2.4.3 Molecular Properties Connected with the Viscosity; 2.5 Thermodynamic Properties of Glass-Forming Melts and Glasses: Overview on Experimental Results; 2.5.1 Heat Capacity; 2.5.2 Temperature Dependence of the Thermodynamic Functions: Simon's Approximation 327 $a2.5.3 Further Methods of Determination of Caloric Properties of Glass-Forming Melts and Glasses2.5.4 Change of Mechanical, Optical and Electrical Properties in the Glass Transition Range; 2.6 Thermodynamic Nature of the Glassy State; 2.7 Concluding Remarks; 3 Generic Theory of Vitrification of Glass-Forming Melts; 3.1 Introduction; 3.2 Basic Ideas and Equations of the Thermodynamics of Irreversible Processes and Application to Vitrification and Devitrification Processes; 3.2.1 Basic Assumptions; 3.2.2 General Thermodynamic Dependencies 327 $a3.2.3 Application to Vitrification and Devitrification Processes3.3 Properties of Glass-Forming Melts: Basic Model Assumptions; 3.3.1 Kinetics of Relaxation; 3.3.2 Thermodynamic Properties: Generalized Equation of State; 3.4 Kinetics of Nonisothermal Relaxation as a Model of the Glass Transition: Change of the Thermodynamic Functions in Cyclic Cooling-Heating Processes; 3.4.1 Description of the Cyclic Processes under Consideration; 3.4.2 Temperature Dependence of the Structural Order Parameter in Cyclic Cooling and Heating Processes 327 $a3.4.3 Definition of the Glass Transition Temperature via the Structural Order Parameter: the Bartenev--Ritland Equation3.4.4 Structural Order Parameter and Entropy Production; 3.4.5 Temperature Dependence of Thermodynamic Potentials at Vitrification; 3.4.6 Cyclic Heating-Cooling Processes: General Results; 3.5 The Prigogine-Defay Ratio; 3.5.1 Introduction; 3.5.2 Derivation; 3.5.3 Comparison with Experimental Data; 3.5.4 Discussion; 3.6 Fictive (Internal) Pressure and Fictive Temperature as Structural Order Parameters; 3.6.1 Brief Overview 327 $a3.6.2 Model-Independent Definition of Fictive (Internal) Pressure and Fictive Temperature 330 $a Written by renowned researchers in this field, this up-to date advanced treatise fills a gap in the literature on glasses. It gives an overview of basic experimental data, of its collection, prediction and theoretical interpretation, thereby paving the way to a deeper understanding of these topics. The present monograph covers the whole spectrum of problems involved in the interpretation of glasses and their properties such as glass transition, relaxation, viscosity, existing and possible unexpected future applications of glasses. The book is recommended for students, to both n 606 $aGlass 615 0$aGlass. 676 $a620.144 676 $a666.1 700 $aSchmelzer$b Ju?rn W. P$01696392 701 $aGutzow$b Ivan S$0871950 701 $aMazurin$b Oleg V$01696393 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910830323603321 996 $aGlasses and the glass transition$94076346 997 $aUNINA