LEADER 05370nam 2200685 450 001 9910830296403321 005 20230926184813.0 010 $a1-282-78420-X 010 $a9786612784200 010 $a3-527-62119-9 010 $a3-527-62120-2 035 $a(CKB)1000000000376635 035 $a(EBL)481862 035 $a(OCoLC)609855471 035 $a(SSID)ssj0000354384 035 $a(PQKBManifestationID)11259055 035 $a(PQKBTitleCode)TC0000354384 035 $a(PQKBWorkID)10302319 035 $a(PQKB)10474413 035 $a(MiAaPQ)EBC481862 035 $a(PPN)250393840 035 $a(EXLCZ)991000000000376635 100 $a20160818h20082008 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aIonic liquids in synthesis /$fedited by Peter Wasserscheid and Tom Welton 205 $a2nd ed. 210 1$aWeinheim, [Germany] :$cWiley-VCH Verlag GmbH & Co. KGaA,$d2008. 210 4$dİ2008 215 $a1 online resource (749 p.) 300 $aDescription based upon print version of record. 311 $a3-527-31239-0 320 $aIncludes bibliographical references at the end of each chapters and index. 327 $av. 1 -- v. 2 327 $aIonic Liquids in Synthesis; Contents; Preface to the Second Edition; A Note from the Editors; Acknowledgements; List of Contributors; 1 Introduction; 2 Synthesis and Purification; 2.1 Synthesis of Ionic Liquids; 2.1.1 Introduction; 2.1.2 Quaternization Reactions; 2.1.3 Anion-exchange Reactions; 2.1.3.1 Lewis Acid-based Ionic Liquids; 2.1.3.2 Anion Metathesis; 2.1.4 Purification of Ionic Liquids; 2.1.5 Improving the Sustainability of Ionic Liquids; 2.1.6 Conclusions; 2.2 Quality Aspects and Other Questions Related to Commercial Ionic Liquid Production; 2.2.1 Introduction 327 $a2.2.2 Quality Aspects of Commercial Ionic Liquid Production2.2.2.1 Color; 2.2.2.2 Organic Starting Material and Other Volatiles; 2.2.2.3 Halide Impurities; 2.2.2.4 Protic Impurities; 2.2.2.5 Other Ionic Impurities from Incomplete Metathesis Reactions; 2.2.2.6 Water; 2.2.3 Upgrading the Quality of Commercial Ionic Liquids; 2.2.4 Novel, Halide-Free Ionic Liquids; 2.2.5 Scale-up of Ionic Liquid Synthesis; 2.2.6 Health, Safety and Environment; 2.2.7 Corrosion Behavior of Ionic Liquids; 2.2.8 Recycling of Ionic Liquids; 2.2.9 Future Price of Ionic Liquids 327 $a2.3 Synthesis of Task-specific Ionic Liquids2.3.1 Introduction; 2.3.2 General Synthetic Strategies; 2.3.3 Functionalized Cations; 2.3.4 Functionalized Anions; 2.3.5 Conclusion; 3 Physicochemical Properties; 3.1 Physicochemical Properties of Ionic Liquids: Melting Points and Phase Diagrams; 3.1.1 Introduction; 3.1.2 Measurement of Liquid Range; 3.1.2.1 Melting Points; 3.1.2.2 Upper Limit - Decomposition Temperature; 3.1.3 Effect of Ion Sizes on Salt Melting Points; 3.1.3.1 Anion Size; 3.1.3.2 Mixtures of Anions; 3.1.3.3 Cation Size; 3.1.3.4 Cation Symmetry; 3.1.3.5 Imidazolium Salts 327 $a3.1.3.6 Imidazolium Substituent Alkyl Chain Length3.1.3.7 Branching; 3.1.4 Summary; 3.2 Viscosity and Density of Ionic Liquids; 3.2.1 Viscosity of Ionic Liquids; 3.2.1.1 Viscosity Measurement Methods; 3.2.1.2 Ionic Liquid Viscosities; 3.2.2 Density of Ionic Liquids; 3.2.2.1 Density Measurement; 3.2.2.2 Ionic Liquid Densities; 3.3 Solubility and Solvation in Ionic Liquids; 3.3.1 Introduction; 3.3.2 Metal Salt Solubility; 3.3.2.1 Halometallate Salts; 3.3.2.2 Metal Complexes; 3.3.3 Extraction and Separations; 3.3.4 Organic Compounds; 3.3.5 Conclusions; 3.4 Gas Solubilities in Ionic Liquids 327 $a3.4.1 Introduction3.4.2 Experimental Techniques; 3.4.2.1 Gas Solubilities and Related Thermodynamic Properties; 3.4.2.2 The Stoichiometric Technique; 3.4.2.3 The Gravimetric Technique; 3.4.2.4 Spectroscopic Techniques; 3.4.2.5 Gas Chromatography; 3.4.3 Gas Solubilities; 3.4.3.1 CO(2); 3.4.3.2 Reaction Gases (O(2), H(2), CO); 3.4.3.3 Other Gases (N(2), Ar, CH(4), C(2)H(6), C(2)H(4), H(2)O, SO(2), CHF(3), etc.); 3.4.3.4 Mixed Gases; 3.4.3.5 Enthalpies and Entropies; 3.4.4 Applications; 3.4.4.1 Reactions Involving Gases; 3.4.4.2 Gas Storage; 3.4.4.3 Gas Separations 327 $a3.4.4.4 Extraction of Solutes from Ionic Liquids with Compressed Gases or Supercritical Fluids 330 $aThe second, completely revised and enlarged edition of what has become the standard reference work in this fascinating field brings together the latest developments, supplemented by numerous practical tips, providing those working in both research and industry with an indispensable source of information. New contributions have been added, to reflect the fact that industrial processes are already established, and ionic liquids are now commercially available.A must for everyone working in the field. 606 $aIonic solutions 606 $aOrganic compounds$xSynthesis 606 $aInorganic compounds$xSynthesis 615 0$aIonic solutions. 615 0$aOrganic compounds$xSynthesis. 615 0$aInorganic compounds$xSynthesis. 676 $a541.39 702 $aWasserscheid$b Peter 702 $aWelton$b Tom 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910830296403321 996 $aIonic liquids in synthesis$9668620 997 $aUNINA