LEADER 05268nam 2200673 450 001 9910830276603321 005 20170816111721.0 010 $a1-281-94705-9 010 $a9786611947057 010 $a3-527-62285-3 010 $a3-527-62286-1 035 $a(CKB)1000000000552623 035 $a(EBL)482371 035 $a(OCoLC)283799094 035 $a(SSID)ssj0000202432 035 $a(PQKBManifestationID)11166376 035 $a(PQKBTitleCode)TC0000202432 035 $a(PQKBWorkID)10255068 035 $a(PQKB)11252723 035 $a(MiAaPQ)EBC482371 035 $a(PPN)18240630X 035 $a(EXLCZ)991000000000552623 100 $a20160819h20082008 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aMicroreactors in organic synthesis and catalysis /$fedited by Thomas Wirth 210 1$aWeinheim, [Germany] :$cWiley-VCH Verlag GmbH & Co. KGaA,$d2008. 210 4$dİ2008 215 $a1 online resource (299 p.) 300 $aDescription based upon print version of record. 311 $a3-527-31869-0 320 $aIncludes bibliographical references at the end of each chapters and index. 327 $aMicroreactors in Organic Synthesis and Catalysis; Contents; Preface; List of Contributors; 1 Fabrication of Microreactors Made from Metals and Ceramics; 1.1 Manufacturing Techniques for Metals; 1.1.1 Etching; 1.1.2 Machining; 1.1.3 Generative Method: Selective Laser Melting (SLM); 1.1.4 Metal-Forming Techniques; 1.1.5 Assembling and Bonding of Metal Microstructures; 1.2 Ceramic Devices; 1.2.1 Joining and Sealing; References; 2 Fabrication and Assembling of Microreactors Made from Glass and Silicon; 2.1 How Microreactors are Constructed; 2.2 Glass as Material; 2.3 Silicon as Material 327 $a2.4 The Structuring of Glass and Silicon2.5 Structuring by Means of Masked Etching in Microsystems Technology; 2.6 Etching Technologies; 2.6.1 Anisotropic (Crystallographic) Wet Chemical Etching of Silicon (KOH); 2.6.2 Isotropic Wet Chemical Etching of Silicon; 2.6.3 Anisotropic Dry Etching of Silicon; 2.6.4 Isotropic Wet Chemical Etching of Silicon Glass; 2.6.5 Photostructuring of Special Glass; 2.7 Chip Removing Processing; 2.7.1 Drilling, Diamond Lapping, Ultrasonic Lapping; 2.7.2 Micropowder Blasting; 2.7.3 Summary; 2.8 Bonding Methods; 2.8.1 Anodic Bonding of Glass and Silicon 327 $a2.8.2 Silicon Direct Bonding (Silicon Fusion Bonding)2.8.3 Glass Fusion Bonding; 2.9 Establishing Fluid Contact; 2.10 Other Materials; References; 3 Properties and Use of Microreactors; 3.1 Introduction; 3.2 Physical Characteristics of Microreactors; 3.2.1 Geometries; 3.2.2 Constructional Materials and Their Properties; 3.3 Fluid Flow and Delivery Regimes; 3.3.1 Fluid Flow; 3.3.2 Fluid Delivery; 3.3.3 Mixing Mechanisms; 3.4 Multifunctional Integration; 3.5 Uses of Microreactors; 3.5.1 Overview; 3.5.2 Unstable Intermediates Fast and Exothermic Reactions; 3.5.3 Precision Particle Manufacture 327 $a3.5.4 Wider Industrial Context3.5.4.1 Sustainability Agenda; 3.5.4.2 Point-of-Demand Synthesis; References; 4 Organic Chemistry in Microreactors; 4.1 Homogeneous Reactions; 4.1.1 Acid-Promoted Reactions; 4.1.2 Base-Promoted Reactions; 4.1.3 Condensation Reactions; 4.1.4 Metal-Catalyzed Reactions; 4.1.5 Photochemical Reactions; 4.1.6 Electrochemical Reactions; 4.1.7 Miscellaneous; 4.1.7.1 Swern Oxidation; 4.1.7.2 Grignard Exchange Reaction; 4.1.7.3 Lithium-Halogen Exchange Reaction; 4.1.7.4 Phenyl Boronic Acid Synthesis; References; 4.2 Heterogeneous Reactions; 4.2.1 Introduction 327 $a4.2.2 Concepts in Flow Mode Synthesis4.2.3 Methods of Conducting Flow Chemistry; 4.2.3.1 On-Bead Synthesis; 4.2.3.2 Solution-Phase Synthesis; 4.2.3.3 Library Synthesis in Flow; 4.2.3.4 Heterocycle Synthesis; 4.2.4 Introduction to Monoliths; 4.2.5 Transition Metal Chemistry Under Flow Conditions; 4.2.5.1 Reduction; 4.2.5.2 Oxidation; 4.2.5.3 Cross-Coupling Reactions; 4.2.5.4 Olefin Metathesis; 4.2.6 Enantioselective Reactions; 4.2.6.1 Hydrolytic Kinetic Resolution; 4.2.6.2 Organometallic Additions; 4.2.6.3 Enantioselective Diels-Alder Reactions; 4.2.6.4 Ene Reactions; 4.2.6.5 Cyclopropanation 327 $a4.2.6.6 Asymmetric Conjugate Addition 330 $aThis one-stop reference is the first book on this emerging and rapid developing field with a focus on synthesis and catalysis. As such, it covers all aspects from academia and industry in a clearly structured way. Leading experts provide the background information as an initial aid for newcomers to the field, while chapters on different reaction types and industrial applications make this an equally vital resource for specialists. 606 $aMicroreactors 606 $aOrganic compounds$xSynthesis 606 $aCatalysis 615 0$aMicroreactors. 615 0$aOrganic compounds$xSynthesis. 615 0$aCatalysis. 676 $a547.2 676 $a660.2832 686 $a35.52$2bcl 702 $aWirth$b Thomas$f1964- 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910830276603321 996 $aMicroreactors in organic synthesis and catalysis$94003008 997 $aUNINA