LEADER 04761nam 2200601 450 001 9910830240103321 005 20170816142308.0 010 $a3-527-63266-2 010 $a3-527-63267-0 035 $a(CKB)2550000001123267 035 $a(EBL)700885 035 $a(OCoLC)774065416 035 $a(SSID)ssj0000506311 035 $a(PQKBManifestationID)11337703 035 $a(PQKBTitleCode)TC0000506311 035 $a(PQKBWorkID)10515625 035 $a(PQKB)10593918 035 $a(MiAaPQ)EBC700885 035 $a(PPN)185468713 035 $a(EXLCZ)992550000001123267 100 $a20110706h20102010 uy| 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aConjugated polymer synthesis $emethods and reactions /$fedited by Yoshiki Chujo 205 $a4th ed. 210 1$aWeinheim :$cWiley-VCH,$d[2010] 210 4$dİ2010 215 $a1 online resource (331 p.) 300 $aDescription based upon print version of record. 311 $a3-527-32267-1 311 $a1-299-90726-1 320 $aIncludes bibliographical references and index. 327 $aConjugated Polymer Synthesis: Methods and Reactions; Contents; Preface; List of Contributors; 1 Organometallic Polycondensation for Conjugated Polymers; 1.1 Basic Organometallic C-C Coupling; 1.2 Syntheses of ?-Conjugated Polymers; 1.3 Optical Properties; 1.3.1 UV-Vis Data; 1.3.2 Photoluminescence; 1.3.3 Other Optical Properties; 1.4 Redox Behavior and Electrical Conductivity; 1.5 Linear Structure and Alignment on the Surface of Substrates; 1.6 Stacking in the Solid and Colloid; 1.7 Chemical Reactivity and Catalysis; 1.7.1 Metal Complexes and Modification of Nitrogen 327 $a1.8 Electronic and Optical Devices (ECD, Battery, EL, Diode, Transistor, Nonlinear Optical Device, etc.)1.8.1 Redox Functions; 1.8.2 Electronic and Optical Devices; 1.9 Conclusions; References; 2 Catalyst-Transfer Condensation Polymerization for Precision Synthesis of ?-Conjugated Polymers; 2.1 Introduction; 2.2 Kumada-Tamao Coupling Polymerization with Ni Catalyst; 2.2.1 Polythiophene; 2.2.1.1 Discovery and Mechanism of Catalyst-Transfer Condensation Polymerization; 2.2.1.2 A Variety of Monomers; 2.2.1.3 Block Polythiophenes; 2.2.1.4 Block Copolymers of Polythiophene and Other Polymers 327 $a2.2.1.5 Graft Copolymers2.2.2 Polyphenylenes; 2.2.3 Polypyrroles; 2.2.4 Polyfluorenes and Polycarbazoles; 2.3 Suzuki-Miyaura Coupling Polymerization with Pd Catalyst; 2.3.1 Polyfluorenes; 2.3.2 Polyphenylenes; 2.4 Conclusion; References; 3 Regioregular and Regiosymmetric Polythiophenes; 3.1 Introduction; 3.2 Synthesis of Polythiophene and Regioirregular Polythiophenes; 3.3 Head-to-Tail Coupled Regioregular Poly(3-Alkylthiophene)s; 3.3.1 Design and Synthesis of rrP3ATs; 3.3.1.1 McCullough Method; 3.3.1.2 Rieke Method; 3.3.1.3 GRIM Method; 3.3.1.4 Palladium-Catalyzed Polymerization Methods 327 $a3.3.2 Mechanism of the Nickel-Catalyzed Polymerization3.4 Side Chain Functionalized HT Regioregular Polythiophenes; 3.4.1 Heteroatom-Containing Groups; 3.4.2 Aromatic-Containing Group; 3.4.3 Chiral Groups; 3.4.4 ?-Functionalized Groups; 3.5 End Group Functionalized HT Regioregular Polythiophenes; 3.5.1 Postpolymerization End Group Functionalization; 3.5.2 In Situ End Group Functionalization; 3.6 Block Copolymers Derived from HT Regioregular Polythiophenes; 3.6.1 All-Conjugated Block Copolymers; 3.6.2 Conjugated-Non-Conjugated Block Copolymers; 3.7 Universal Use of the GRIM Method 327 $a3.8 Regiosymmetric Polythiophenes3.9 Summary; References; 4 Functional Hyperbranched Polymers Constructed from Acetylenic An-Type Building Blocks; 4.1 Introduction; 4.2 Hyperbranched Polymers Constructed from Acetylenic An-Type Building Blocks; 4.2.1 Hyperbranched Poly(Alkylenephenylene)s (hb-PAPs); 4.2.1.1 Synthesis; 4.2.1.2 Structures; 4.2.1.3 Properties; 4.2.2 Hyperbranched Poly(Arylenephenylene)s (hb-PArPs); 4.2.2.1 Synthesis; 4.2.2.2 Structures; 4.2.2.3 Properties; 4.2.3 Hyperbranched Poly(Aroylphenylene)s (hb-PAkPs) and Poly(Aroxycarbonylphenylene)s (hb-PAePs); 4.2.3.1 Synthesis 327 $a4.2.3.2 Structures 330 8 $aEdited and authored by top international experts, this first book on conjugated polymers with a focus on synthesis provides a detailed overview of all modern synthetic methods for these highly interesting compounds. 606 $aConjugated polymers 615 0$aConjugated polymers. 676 $a547.70457 701 $aChujo$b Y$g(Yoshiki)$01711069 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910830240103321 996 $aConjugated polymer synthesis$94102144 997 $aUNINA