LEADER 00721nam0-22002771i-450- 001 990001641390403321 005 20050407151050.0 035 $a000164139 035 $aFED01000164139 035 $a(Aleph)000164139FED01 035 $a000164139 100 $a20030910d1916----km-y0itay50------ba 101 0 $aita 200 1 $aSoccorsi d' urgenza$fCarlo Calliano 210 $aMilano$cHoepli$d1916 215 $a430 p.$d15 cm 610 0 $aSoccorso d'urgenza 676 $a614.88 700 1$aCalliano,$bCarlo$070430 801 0$aIT$bUNINA$gRICA$2UNIMARC 901 $aBK 912 $a990001641390403321 952 $a60 616 C 1$b24051$fFAGBC 959 $aFAGBC 996 $aSoccorsi d' urgenza$9367968 997 $aUNINA LEADER 05374nam 2200613 450 001 9910830228103321 005 20230807221718.0 010 $a1-119-17853-3 010 $a1-119-17851-7 010 $a1-119-17852-5 035 $a(CKB)3710000000468773 035 $a(EBL)2063995 035 $a(MiAaPQ)EBC4911573 035 $a(MiAaPQ)EBC2063995 035 $a(EXLCZ)993710000000468773 100 $a20171017h20152015 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $2rdacontent 182 $2rdamedia 183 $2rdacarrier 200 10$aThermodynamic modeling of solid phases /$fMichel Soustelle 210 1$aLondon, England ;$aHoboken, New Jersey :$ciSTE :$cWiley,$d2015. 210 4$dİ2015 215 $a1 online resource (266 p.) 225 1 $aChemical Engineering Series. Chemical Thermodynamics set ;$vVolume 3 300 $aDescription based upon print version of record. 311 $a1-84821-866-4 320 $aIncludes bibliographical references and index. 327 $aCover; Title Page; Copyright; Contents; Preface; Notations and Symbols; 1: Pure Crystalline Solids; 1.1. Characteristic values of a solid; 1.2. Effect of stress and Young's modulus; 1.3. Microscopic description of crystalline solids; 1.4. Partition function of vibration of a solid; 1.4.1. Einstein's single-frequency model; 1.4.2. Debye's frequency distribution model; 1.4.3. Models with more complex frequency distributions; 1.5. Description of atomic solids; 1.5.1. Canonical partition function of an atomic solid; 1.5.2. Helmholtz energy and internal energy of an atomic solid 327 $a1.6. Description of molecular solids1.6.1. Partition function of molecular crystals; 1.6.2. Thermodynamic functions of molecular solids; 1.7. Description of an ionic solid; 1.7.1. Crosslink energy of an ionic solid; 1.7.1.1. Attraction energy; 1.7.1.2. Repulsion energy; 1.7.1.3. Crosslink energy; 1.7.2. Born/Haber cycle; 1.7.3. Vibrational partition function and internal energy of an ionic solid; 1.8. Description of a metallic solid; 1.8.1. Sommerfeld's electron perfect gas model; 1.8.1.1. Determination of the coefficient ?; 1.8.1.2. Kinetic energy of electrons in the metal 327 $a1.8.1.3. Electrochemical potential of the electrons in the metal and the Fermi energy1.8.1.4. Energy distribution of the free electrons; 1.8.1.5. Contribution of the free electrons to the internal energy of a metal; 1.8.2. The metallic bond and band theory; 1.8.2.1. Origin of energy bands; 1.8.2.2. Conductors, insulators and semiconductors; 1.8.2.3. Determination of the number N of free electrons; 1.8.2.4. Distribution of energy states and of free electrons at absolute zero; 1.9. Molar specific heat capacities of crystalline solids 327 $a1.9.1. Contribution of the vibrational energy to the specific heat capacity at constant volume1.9.1.1. Case of a unique vibration in Einstein's model; 1.9.1.2. Case of Debye's acoustic vibration distribution; 1.9.2. Specific heat capacity of an atomic solid at constant volume; 1.9.2.1. Case of conductors; 1.9.2.2. Case of insulating materials; 1.9.3. Specific heat capacity of a molecular or ionic solid at constant volume; 1.9.4. Conclusion as to the specific heat capacity of a crystalline solid; 1.10. Thermal expansion of solids; 1.10.1. Expansion coefficients 327 $a1.10.1.1. Linear expansion coefficient1.10.1.2. Thermal expansion tensor; 1.10.1.3. Cubic expansion coefficient (or coefficient of relative volume increase); 1.10.1.4. Relation between the thermomechanical coefficients; 1.10.2. Origin of thermal expansion in solids; 1.10.3. Quantum treatment of thermal expansion. Gru?neisen parameter; 1.10.4. Expansion coefficient of metals; 2: Solid Solutions; 2.1. Families of solid solutions; 2.1.1. Substitutional solid solutions; 2.1.2. Insertion solid solution; 2.1.2.1. Octahedral sites of the cubic centered faces lattice 327 $a2.1.2.2. Tetrahedral sites of the cubic centered faces lattice 330 $a The book offers advanced students, in 7 volumes, successively characterization tools phases, the study of all types of phase, liquid, gas and solid, pure or multi-component, process engineering, chemical and electrochemical equilibria, the properties of surfaces and phases of small sizes. Macroscopic and microscopic models are in turn covered with a constant correlation between the two scales. Particular attention was given to the rigor of mathematical developments. Besides some very specialized books, the vast majority of existing works are intended for beginners and therefore limited in s 410 0$aChemical engineering series (ISTE Ltd).$pChemical thermodynamics set ;$vVolume 3. 606 $aPhase rule and equilibrium$xMathematical models 606 $aSolids$xThermal properties 606 $aThermodynamics$xMathematical models 606 $aChemical reactions 615 0$aPhase rule and equilibrium$xMathematical models. 615 0$aSolids$xThermal properties. 615 0$aThermodynamics$xMathematical models. 615 0$aChemical reactions. 676 $a536.7 700 $aSoustelle$b Michel$01628148 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910830228103321 996 $aThermodynamic modeling of solid phases$94021244 997 $aUNINA