LEADER 01657nam 2200421 450 001 9910830203803321 005 20231008135521.0 010 $a3-527-62077-X 024 7 $a10.1002/9783527620777 035 $a(CKB)4540000000000282 035 $a(NjHacI)994540000000000282 035 $a(EXLCZ)994540000000000282 100 $a20231008d2005 uy 0 101 0 $aeng 135 $aur||||||||||| 181 $ctxt$2rdacontent 182 $cc$2rdamedia 183 $acr$2rdacarrier 200 10$aOrganosilicon Chemistry Set $eFrom Molecules to Materials /$fNorbert Auner, Johann Weis 210 1$aWeinheim, Germany :$cWiley-VCH,$d2005. 210 4$dİ2005 215 $a1 online resource 311 $a3-527-32347-3 330 $aAryl ligands carrying oxygen, phosphorus or sulfur donor atoms in the side chain are introduced at silicon. Here we report on the synthesis of silyl chlorides and silyl triflates. The interaction between the silicon centre and the donor atom are discussed on the basis of NMR and X-ray crystallographic data. In the reaction of bis[2-(methoxymethyl)phenyl]methylsilyl triflate 8 with nucleophiles, reactivity of oxonium as well as of siliconium ions is observed. 517 $aOrganosilicon Chemistry Set 606 $aOrganosilicon compounds 606 $aSilicon compounds 615 0$aOrganosilicon compounds. 615 0$aSilicon compounds. 676 $a547.08 700 $aAuner$b Norbert$0906518 702 $aWeis$b Johann 801 0$bNjHacI 801 1$bNjHacl 906 $aBOOK 912 $a9910830203803321 996 $aOrganosilicon Chemistry Set$94082566 997 $aUNINA