LEADER 05180nam 2200601 450 001 9910830162003321 005 20230721004111.0 010 $a1-282-78441-2 010 $a9786612784415 010 $a3-527-62174-1 010 $a3-527-62175-X 035 $a(CKB)1000000000687147 035 $a(EBL)481446 035 $a(SSID)ssj0000354540 035 $a(PQKBManifestationID)11249041 035 $a(PQKBTitleCode)TC0000354540 035 $a(PQKBWorkID)10322578 035 $a(PQKB)10293774 035 $a(MiAaPQ)EBC481446 035 $a(OCoLC)214281867 035 $a(EXLCZ)991000000000687147 100 $a20160819h20082008 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aNitroxides $eapplications in chemistry, biomedicine, and materials science /$fGertz I. Likhtenshtein [and four others] 210 1$aWeinheim, Germany :$cWILEY-VCH Verlag GmbH & Co. KGaA,$d2008. 210 4$dİ2008 215 $a1 online resource (441 p.) 300 $aDescription based upon print version of record. 311 $a3-527-31889-5 320 $aIncludes bibliographical references at the end of each chapters and index. 327 $aNitroxides; Contents; Preface; Symbols and Abbreviations; 1 Fundamentals of Magnetism; 1.1 Magnetism of Materials; 1.1.1 Historical Background; 1.1.2 Magnetic Moment and its Energy in a Magnetic Field; 1.1.3 Definitions of Magnetization and Magnetic Susceptibility; 1.1.4 Diamagnetism and Paramagnetism; 1.1.5 Classification of Magnetic Materials; 1.1.6 Important Variables, Units, and Relations; 1.2 Origins of Magnetism; 1.2.1 Origins of Diamagnetism; 1.2.2 Origins of Paramagnetism; 1.2.3 Magnetic Moments; 1.2.4 Specific Rules for Many Electrons; 1.2.5 Magnetic Moments in General Cases 327 $a1.2.6 Zeeman Effect1.2.7 Orbital Quenching; 1.3 Temperature Dependence of Magnetic Susceptibility; 1.3.1 The Langevin Function of Magnetization and the Curie Law; 1.3.2 The Brillouin Function of Magnetization and the Curie Law; 1.3.3 The Curie-Weiss Law; 1.3.4 Magnetic Ordered State; 1.3.5 Magnetic Interactions; 1.3.5.1 Exchange Interaction; 1.3.5.2 Dipolar Interaction; 1.3.6 Spin Hamiltonian; 1.3.7 Van Vleck Formula for Susceptibility; 1.3.8 Some Examples of the van Vleck Formula; 1.3.8.1 The Curie Law; 1.3.8.2 Zero-Filed Splitting Case; 1.3.8.3 Spin Cluster Case-The Dimer Model 327 $a1.3.8.4 Multiple-spin Cluster Case - The Triangle or Others1.3.8.5 Temperature-Independent Paramagnetism; 1.3.9 Low-Dimensional Interaction Network; 1.4 Experimental Magnetic Data Acquisition; 1.4.1 Methods; 1.4.2 Evaluations of Magnetic Susceptibility and Magnetic Moment; References; 2 Molecular Magnetism; 2.1 Magnetic Origins from Atoms and Molecules; 2.1.1 Historical Background; 2.1.2 Spin States Derived from Chemical Bonds; 2.1.3 Organic Free Radicals; 2.1.4 Coordinate Compounds; 2.2 Characteristics of Molecular Magnetism; 2.2.1 Molecular Paramagnetism 327 $a2.2.2 Magnetic Properties of Organic Free Radicals2.3 Nitroxide as a Building Block; 2.3.1 Stability of the N-O Bond; 2.3.2 Structural Resonance of the N-O Bond; 2.3.3 Molecular and Magnetic Interactions between Nitroxides; 2.3.4 Nitroxides as Building Block; 2.4 Low-Dimensional Properties of Nitroxides; 2.4.1 One-Dimensional Magnetism; 2.4.1.1 TANOL (TEMPOL); 2.4.1.2 F(5)PNN; 2.4.2 Interchain Interaction and Spin Long-Range Ordering; 2.4.3 Two-Dimensional Magnetism; 2.4.3.1 DANO; 2.4.3.2 p-NPNN; 2.4.4 Coordination of Nitroxide with Metal Ions; 2.4.4.1 Cu(2+), Mn(2+)-TANOL (TEMPOL) 327 $a2.4.4.2 Mn(2+)-IPNNReferences; 3 Fundamentals of Electron Spin Resonance (ESR); 3.1 Magnetic Resonance of Electron and Nuclear Spins; 3.1.1 Historical Background; 3.1.2 Classification of Magnetic Resonance; 3.2 Principle of Electron Spin Resonance (ESR); 3.2.1 Principle of ESR from Spectroscopic Interpretation; 3.2.2 Principle of ESR from Resonance Interpretation; 3.2.3 Bloch Equation; 3.2.3.1 Solutions of the Bloch Equation; 3.2.3.2 Absorption Line Shape; 3.2.3.3 Relaxation Times; 3.2.4 Modified Bloch Equation; 3.2.5 Hyperfine Interaction 327 $a3.2.5.1 Interaction of the Electron Spin with Nuclear Spins 330 $aCovering all aspects of this field, this volume also critically discusses recent results obtained with the use of nitroxides, while providing an analysis of future developments.Written by a group of scientists with long-term experience in investigating the chemistry, physicochemistry, biochemistry and biophysics of nitroxides, the book is not intended as an exhaustive survey of each topic, but rather a discussion of their theoretical and experimental background, as well as recent advances. The first four chapters expound the general theoretical and experimental background and the advan 606 $aNitroxides 615 0$aNitroxides. 676 $a547.041 676 $a661.65 702 $aLikhtenshtei?n$b G. I$g(Gert?s Il?ich), 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910830162003321 996 $aNitroxides$92273864 997 $aUNINA