LEADER 05243nam 2200637Ia 450 001 9910830127403321 005 20170816122657.0 010 $a1-280-72346-7 010 $a9786610723461 010 $a3-527-60856-7 010 $a3-527-60851-6 035 $a(CKB)1000000000326916 035 $a(EBL)482260 035 $a(OCoLC)609855570 035 $a(SSID)ssj0000308925 035 $a(PQKBManifestationID)11227236 035 $a(PQKBTitleCode)TC0000308925 035 $a(PQKBWorkID)10276855 035 $a(PQKB)10370673 035 $a(MiAaPQ)EBC482260 035 $a(PPN)24196010X 035 $a(EXLCZ)991000000000326916 100 $a20060712d2006 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aScanning probe microscopies beyond imaging$b[electronic resource] $emanipulation of molecules and nanostructures /$fedited by Paolo Samori 210 $aWeinheim $cWiley-VCH$d2006 215 $a1 online resource (570 p.) 300 $aDescription based upon print version of record. 311 $a3-527-31269-2 320 $aIncludes bibliographical references and index. 327 $aScanning Probe Microscopies Beyond Imaging; Foreword; Contents; Preface; List of Authors; Part I Scanning Tunneling Microscopy-Based Approaches; Nanoscale Structural, Mechanical and Electrical Properties; 1 Chirality in 2D; 1.1 Introduction; 1.2 Chirality and STM: From 0D to 2D; 1.2.1 Determination of Absolute Chirality; 1.2.2 Expression of 2D Chirality by Enantiopure Molecules; 1.2.3 Racemic Mixture of Chiral Molecules; 1.2.4 Achiral Molecules; 1.2.5 Systems with Increased Complexity; 1.2.6 Multicomponent Systems; 1.2.6.1 Mixed Systems; 1.2.6.2 Cocrystals 327 $a1.2.7 Chemisorption versus Physisorption1.2.8 The Effect of Molecular Adsorption on Substrates: Toward Chiral Substrates; 1.2.9 Chirality and AFM; 1.3 Conclusion; Acknowledgements; References; 2 Scanning Tunneling Spectroscopy of Complex Molecular Architectures at Solid/Liquid Interfaces: Toward Single-Molecule Electronic Devices; 2.1 Introduction; 2.2 STM/STS of Molecular Adsorbates; 2.3 An Early Example of STS at the Solid/Liquid Interface; 2.4 Ultrahigh Vacuum versus Solid/Liquid Interface; 2.5 Probing ?-Coupling at the Single-Molecule Level by STS 327 $a2.6 Molecular Diodes and Prototypical Transistors2.7 Conclusions; Acknowledgements; References; 3 Molecular Repositioning to Study Mechanical and Electronic Properties of Large Molecules; 3.1 Introduction; 3.2 Specially Designed Molecules; 3.3 STM-Induced Manipulation; 3.3.1 Manipulation of Single Atoms; 3.3.2 Repositioning of Molecules at Room Temperature; 3.3.3 Manipulation in Constant Height Mode; 3.4 Mechanical Properties: Controlled Manipulation of Complex Molecules; 3.5 Inducing Conformational Changes: A Route to Molecular Switching; 3.6 The Role of the Substrate 327 $a3.7 Electronic Properties: Investigation of the Molecule-Metal Contact3.8 Perspectives; Acknowledgements; References; 4 Inelastic Electron Tunneling Microscopy and Spectroscopy of Single Molecules by STM; 4.1 Introduction; 4.1.1 Working Principle; 4.2 Experimental Results; 4.2.1 C(60) on Ag(110); 4.2.2 C(6)H(6) on Ag(110); 4.3 Theory; 4.3.1 Extension of Tersoff-Hamman Theory to IETS-STM; 4.3.2 Some Model Systems; 4.3.3 Acetylene Molecules on Cu(100); 4.3.4 Oxygen Molecules on Ag(110); 4.3.5 Ammonia Molecules on Cu(100); 4.4 Conclusion; References 327 $aPart II Scanning Force Microscopy-Based ApproachesPatterning; 5 Patterning Organic Nanostructures by Scanning Probe Nanolithography; 5.1 Importance of Patterning Organic Nanostructures; 5.2 Direct Patterning of Organic Thin Films; 5.2.1 Fabrication of Nanostructures by a Local Modification; 5.2.1.1 Nanorecording for Memory Storage; 5.2.1.2 Local Probe Photolithography; 5.2.1.3 Nanorubbing; 5.2.2 Self-Organization of Molecular Nanostructures Triggered by SPM; 5.3 Assembly of Organic Structures on Nanofabricated Patterns; 5.3.1 Replacement Nanolithography on Self-Assembly Monolayers (SAMs) 327 $a5.3.2 Template Growth of Molecular Nanostructures 330 $aThis first book to focus on the use of SPMs to actively manipulate molecules and nanostructures on surfaces goes way beyond conventional treatments of scanning microscopy merely for imaging purposes. It reviews recent progress in the use of SPMs on such soft materials as polymers, with a particular emphasis on chemical discrimination, mechanical properties, tip-induced reactions and manipulations, as well as their nanoscale electrical properties. Detailing the practical application potential of this hot topic, this book is of great interest to specialists of wide-ranging disciplines, including 606 $aScanning probe microscopy 606 $aMicroscopy 615 0$aScanning probe microscopy. 615 0$aMicroscopy. 676 $a502.82 686 $a33.03$2bcl 686 $a51.30$2bcl 701 $aSamori?$b Paolo$01637527 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910830127403321 996 $aScanning probe microscopies beyond imaging$93979398 997 $aUNINA