LEADER 05294nam 2200649 a 450 001 9910829856403321 005 20230617010016.0 010 $a1-280-27660-6 010 $a9786610276608 010 $a0-470-35818-1 010 $a0-471-71798-3 010 $a0-471-71797-5 035 $a(CKB)1000000000355617 035 $a(EBL)238762 035 $a(SSID)ssj0000230986 035 $a(PQKBManifestationID)11187383 035 $a(PQKBTitleCode)TC0000230986 035 $a(PQKBWorkID)10197302 035 $a(PQKB)11369755 035 $a(MiAaPQ)EBC238762 035 $a(OCoLC)85820596 035 $a(EXLCZ)991000000000355617 100 $a20040831d2005 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aQuadrupole ion trap mass spectrometry$b[electronic resource] /$fRaymond E. March, John F.J. Todd 205 $a2nd ed. 210 $aHoboken, N.J. $cJ. Wiley$dc2005 215 $a1 online resource (389 p.) 225 1 $aChemical analysis ;$vv. 165 300 $aRev. ed of: Quadrupole storage mass spectrometry. c1989. 311 $a0-471-48888-7 320 $aIncludes bibliographical references and index. 327 $aQUADRUPOLE ION TRAP MASS SPECTROMETRY; CONTENTS; Preface; Preface to First Edition; Nomenclature; 1 A Historical Review of the Early Development of the Quadrupole Ion Trap; 1.1. Introduction; 1.2. Principles of Operation; 1.3. Utilization of the Quadrupole Ion Trap; 1.3.1. Early Mass-Selective Modes of Operation; 1.3.1.1. Mass-Selective Detection; 1.3.1.2. Mass-Selective Storage; 1.3.2. Ion Loss Processes; 1.3.2.1. Unstable Trajectories; 1.3.2.2. Interactions; 1.3.2.3. Nonlinear Resonances; 1.3.2.4. Self-Emptying; 1.4. The Low-Pressure QUISTOR-Quadrupole Combination 327 $a1.5. Early Studies of the Theoretical Aspects of Low-Pressure Ion Trap Operation1.6. Research Activities with the Quadrupole Ion Trap; 1.7. Mass-Selective Axial Ejection; 1.8. Conclusion; References; 2 Theory of Quadrupole Instruments; 2.1. Prelude; 2.2. Introduction; 2.3. Theory of Quadrupolar Devices; 2.3.1. The Quadrupole Mass Filter (QMF); 2.3.1.1. QMF with Round Rods; 2.3.1.2. The Structure of the QMF; 2.3.1.3. Quadrupolar Potential; 2.3.1.4. The Mathieu Equation; 2.3.1.5. Regions of Stability of the QMF; 2.3.1.6. Mass Selectivity of the QMF; 2.3.2. The Quadrupole Ion Trap (QIT) 327 $a2.3.2.1. The Structure of the QIT2.3.2.2. Electrode Surfaces; 2.3.2.3. Quadrupolar Potential; 2.3.2.4. An Alternative Approach to QIT Theory; 2.3.2.5. Regions of Ion Trajectory Stability; 2.3.3. Secular Frequencies; 2.3.4. Calculations; 2.3.4.1. q(z) and LMCO; 2.3.4.2. b(z); 2.3.4.3. w(z); 2.3.4.4. Mass Range; 2.3.5. The Complete Solution to the Mathieu Equation; 2.3.6. Secular Frequencies; 2.4. Conclusions; Appendix; References; 3 Dynamics of Ion Trapping; 3.1. Introduction; 3.2. The Pseudopotential Well Model; 3.2.1. Specimen Calculation of the Pseudopotential Well Depth D(z) 327 $a3.2.2. Some Applications of the Pseudopotential Well Model3.2.2.1. Estimation of the Effects of Space Charge; 3.2.2.2. Ion Kinetic Energies; 3.3. Higher Order Field Components and Nonlinear Resonances; 3.3.1. Historical Background; 3.3.2. Fundamental Aspects of Nonlinear Resonances; 3.3.2.1. Multipole Fields; 3.3.2.2. Experimental Observations of Effects Arising from Nonlinear Resonances in the Quadrupole Ion Trap Mass Spectrometer; 3.3.2.3. Nonlinear Field Effects in Quadrupole Mass Spectrometers and Linear Ion Traps; 3.3.2.4. Mass Shifts; 3.4. Motion of Trapped Ions 327 $a3.4.1. Collision Processes: Collisional Cooling3.4.2. Collision Processes: Trapping Injected Ions; 3.4.3. Resonant Excitation; 3.4.3.1. Resonant Excitation: Ion Ejection; 3.4.3.2. Resonant Excitation: Collision-Activated Decomposition; 3.4.3.3. Collision Energies; 3.4.4. Boundary-Activated Dissociation (BAD); 3.4.5. Surface-Induced Dissociation; 3.5. Conclusion; References; 4 Simulation of Ion Trajectories in the Quadrupole Ion Trap; 4.1. Introduction; 4.2. Recent Applications of Simulations; 4.3. Theoretical Background; 4.3.1. Numerical Integration of the Mathieu Equation 327 $a4.3.2. Calculation of Electrostatic Fields 330 $aA definitive reference, completely updatedPublished in 1989, the First Edition of this book, originally entitled Quadrupole Storage Mass Spectrometry, quickly became the definitive reference in analytical laboratories worldwide. Revised to reflect scientific and technological advances and new applications in the field, the Second Edition includes new chapters covering:* New ion trap instruments of high sensitivity* Peptide analysis by liquid chromatography/ion trap tandem mass spectrometry* Analytical aspects of ion trap mass spectrometry combined with gas chromatography