LEADER 05470nam 2200649 a 450 001 9910828803003321 005 20240313193400.0 010 $a3-527-64666-3 010 $a3-527-64669-8 010 $a3-527-64668-X 035 $a(CKB)3360000000455828 035 $a(EBL)1166317 035 $a(OCoLC)842841158 035 $a(SSID)ssj0000904911 035 $a(PQKBManifestationID)11545436 035 $a(PQKBTitleCode)TC0000904911 035 $a(PQKBWorkID)10925255 035 $a(PQKB)10945353 035 $a(MiAaPQ)EBC1166317 035 $a(Au-PeEL)EBL1166317 035 $a(CaPaEBR)ebr10691471 035 $a(CaONFJC)MIL484615 035 $a(EXLCZ)993360000000455828 100 $a20130504d2013 uy 0 101 0 $aeng 135 $aurcn||||||||| 181 $ctxt 182 $cc 183 $acr 200 00$aSupercapacitors $ematerials, systems, and applications /$fedited by Fran{cedil}cois B{acute}eguin and El{dot}zbieta Fr©?ackowiak 205 $a1st ed. 210 $aWeinheim $cWiley-VCH$d2013 215 $a1 online resource (569 p.) 225 0 $aMaterials for sustainable energy and development 300 $aDescription based upon print version of record. 311 $a3-527-32883-1 320 $aIncludes bibliographical references and index. 327 $aSupercapacitors; 11 Supercapacitor Module Sizing and Heat Management under Electric, Thermal, and Aging Constraints; 11.1 Introduction; Contents; Series Editor Preface; Preface; About the Series Editor; About the Volume Editors; List of Contributors; 1 General Principles of Electrochemistry; 1.1 Equilibrium Electrochemistry; 1.1.1 Spontaneous Chemical Reactions; 1.1.2 The Gibbs Energy Minimum; 1.1.3 Bridging the Gap between Chemical Equilibrium and Electrochemical Potential; 1.1.4 The Relation between E and DGr; 1.1.5 The Nernst Equation; 1.1.6 Cells at Equilibrium; 1.1.7 Standard Potentials 327 $a1.1.8 Using the Nernst Equation - Eh-pH Diagrams 1.2 Ionics; 1.2.1 Ions in Solution; 1.2.1.1 Ion-Solvent Interactions; 1.2.1.2 Thermodynamics; 1.2.2 The Born or Simple Continuum Model; 1.2.2.1 Testing the Born Equation; 1.2.3 The Structure of Water; 1.2.3.1 Water Structure near an Ion; 1.2.3.2 The Ion-Dipole Model; 1.2.3.3 Cavity Formation; 1.2.3.4 Breaking up the Cluster; 1.2.3.5 Ion-Dipole Interaction; 1.2.3.6 The Born Energy; 1.2.3.7 Orienting the Solvated Ion in the Cavity; 1.2.3.8 The Leftover Water Molecules; 1.2.3.9 Comparison with Experiment; 1.2.3.10 The Ion-Quadrupole Model 327 $a1.2.3.11 The Induced Dipole Interaction 1.2.3.12 The Results; 1.2.3.13 Enthalpy of Hydration of the Proton; 1.2.4 The Solvation Number; 1.2.4.1 Coordination Number; 1.2.4.2 The Primary Solvation Number; 1.2.5 Activity and Activity Coefficients; 1.2.5.1 Fugacity (f'); 1.2.5.2 Dilute Solutions of Nonelectrolytes; 1.2.5.3 Activity (a); 1.2.5.4 Standard States; 1.2.5.5 Infinite Dilution; 1.2.5.6 Measurement of Solvent Activity; 1.2.5.7 Measurement of Solute Activity; 1.2.5.8 Electrolyte Activity; 1.2.5.9 Mean Ion Quantities; 1.2.5.10 Relation between f, y, andy; 1.2.6 Ion-Ion Interactions 327 $a1.2.6.1 Introduction 1.2.6.2 Debye-Huckel Model for Calculating o2; 1.2.6.3 Poisson-Boltzmann Equation; 1.2.6.4 Charge Density; 1.2.6.5 Solving the Poisson-Boltzmann Equation; 1.2.6.6 Calculation of D ui-I; 1.2.6.7 Debye Length, K-1 or LD; 1.2.6.8 The Activity Coefficient; 1.2.6.9 Comparison with Experiment; 1.2.6.10 Approximations of the Debye-Huckel Limiting Law; 1.2.6.11 The Distance of Closest Approach; 1.2.6.12 Physical Interpretation of the Activity Coefficient; 1.2.7 Concentrated Electrolyte Solutions; 1.2.7.1 The Stokes-Robinson Treatment; 1.2.7.2 The Ion-Hydration Correction 327 $a1.2.7.3 The Concentration Correction 1.2.7.4 The Stokes-Robinson Equation; 1.2.7.5 Evaluation of the Stokes-Robinson Equation; 1.2.8 Ion Pair Formation; 1.2.8.1 Ion Pairs; 1.2.8.2 The Fuoss Treatment; 1.2.9 Ion Dynamics; 1.2.9.1 Ionic Mobility and Transport Numbers; 1.2.9.2 Diffusion; 1.2.9.3 Fick's Second Law; 1.2.9.4 Diffusion Statistics; 1.3 Dynamic Electrochemistry; 1.3.1 Review of Fundamentals; 1.3.1.1 Potential; 1.3.1.2 Potential inside a Good Conductor; 1.3.1.3 Charge on a Good Conductor; 1.3.1.4 Force between Charges; 1.3.1.5 Potential due to an Assembly of Charges 327 $a1.3.1.6 Potential Difference between Two Phases in Contact (Do) 330 $aWritten by an international group of leading experts from both academia and industry, this is the first comprehensive book on the topic for 10 years. Taking into account the commercial interest in these systems and the scientific and technological developments over the past decade, all important materials and systems are covered, with several chapters devoted to topics of direct industrial relevance.The book starts by providing an introduction to the general principles of electrochemistry, the properties of electrochemical capacitors, and electrochemical characterization techniques. There 410 0$aNew Materials for Sustainable Energy and Development 606 $aSupercapacitors 615 0$aSupercapacitors. 676 $a621.315 701 $aB{acute}eguin$b Fran{cedil}cois$01632943 701 $aFr©?ackowiak$b El{dot}zbieta$01632944 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910828803003321 996 $aSupercapacitors$93972425 997 $aUNINA