LEADER 05553nam 2200673 450 001 9910828347603321 005 20200520144314.0 010 $a1-118-77820-0 010 $a1-118-77817-0 010 $a1-118-77818-9 035 $a(CKB)2550000001171807 035 $a(EBL)1582380 035 $a(SSID)ssj0001082031 035 $a(PQKBManifestationID)11591791 035 $a(PQKBTitleCode)TC0001082031 035 $a(PQKBWorkID)11091741 035 $a(PQKB)11043443 035 $a(OCoLC)853618742 035 $a(MiAaPQ)EBC1582380 035 $a(DLC) 2013029045 035 $a(Au-PeEL)EBL1582380 035 $a(CaPaEBR)ebr10822347 035 $a(CaONFJC)MIL553207 035 $a(OCoLC)866449058 035 $a(PPN)219882622 035 $a(EXLCZ)992550000001171807 100 $a20130709d2014 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aMethods and applications of cycloaddition reactions in organic syntheses /$fedited by Nagatoshi Nishiwaki 210 1$aHoboken, New Jersey :$cWiley,$d2014. 215 $a1 online resource (673 p.) 300 $aDescription based upon print version of record. 311 $a1-118-29988-4 311 $a1-306-21956-6 320 $aIncludes bibliographical references and index. 327 $aMethods and Applications of Cycloaddition Reactions in Organic Syntheses; Contents; Preface; Contributors; Part I: [2+1] Cycloaddition; 1 [2+1]-Type Cyclopropanation Reactions; 1.1 INTRODUCTION; 1.2 CYCLOPROPANATION REACTION VIA MICHAEL-INDUCED RING CLOSURE REACTION; 1.2.1 Introduction; 1.2.2 Halo-Substituted Nucleophiles in MIRC Reaction; 1.2.3 Ylides for Cyclopropanation; 1.3 SIMMONS-SMITH CYCLOPROPANATION AND RELATED REACTIONS; 1.3.1 Introduction; 1.3.2 The Simmons-Smith Reaction with Zinc Reagents; 1.4 DIAZOALKANES WITH TRANSITION METAL CATALYSTS; 1.4.1 Introduction 327 $a1.4.2 Rhodium-Catalyzed Reactions1.4.4 Ruthenium-Catalyzed Reactions; 1.4.5 Cobalt- and Iron-Catalyzed Reactions; 1.4.6 Other Transition Metal-Catalyzed Reactions; 1.4.7 Cyclopropanation Without Transition Metal Catalysts; 1.4.8 Cyclopropanation of Dihalocarbenes; 1.5 CYCLOISOMERIZATION WITH TRANSITION METAL CATALYSTS; 1.5.1 Introduction; 1.5.2 Gold Complex-Catalyzed Reactions; 1.5.3 Palladium Complex-Catalyzed Reactions; 1.5.4 Platinum Complex-Catalyzed Reactions; 1.5.5 Ruthenium Complex-Catalyzed Reactions; 1.5.6 Other Metal Complex-Catalyzed Reactions; 1.6 KULINKOVICH REACTIONS 327 $a1.6.1 Introduction1.6.2 The Kulinkovich Reaction to Esters, Ketones, and Amides; 1.6.3 Kulinkovich Reaction to Nitriles; 1.6.4 Other Ti-Mediated Cyclopropanation Reactions; 1.7 MISCELLANEOUS [2+1]-TYPE OF CYCLOPROPANATION REACTIONS; REFERENCES; 2 N1 Unit Transfer Reaction To C-C Double Bonds; 2.1 INTRODUCTION; 2.2 AZIRIDINATION WITH AZIDES; 2.3 AZIRIDINATION WITH IMINOIODINANES; 2.4 AZIRIDINATION WITH N-HALOAMINE SALTS; 2.5 AZIRIDINATION WITH OTHER N1 UNIT; 2.6 CONCLUSIONS; REFERENCES; Part II: [2+2] Cycloaddition; 3 Lewis Base Catalyzed Asymmetric Formal [2+2] Cycloadditions 327 $a3.1 INTRODUCTION3.2 ?-LACTAMS: FORMAL [2+2] CYCLOADDITIONS INVOLVING IMINES; 3.3 ?-LACTONES I: FORMAL [2+2] CYCLOADDITIONS INVOLVING ALDEHYDES/KETONES; 3.4 ?-LACTONES II: FORMAL [2+2] CYCLOADDITION OF KETENES LEADING TO KETENE DIMERS; 3.4.1 Introduction or or; 3.4.2 Homodimerization; 3.4.3 Heterodimerization; 3.5 MISCELLANEOUS FORMAL [2+2] ASYMMETRIC CYCLOADDITION PROCESSES; 3.5.1 Other Heterocyclic Classes-Introduction; 3.5.2 Asymmetric Formal [2+2] Cycloadditions; 3.6 CONCLUSIONS; REFERENCES; Part III: [2+2] and [4+2]/[2+2] Cycloaddition; 4 Catalytic [2+2] Cycloaddition of Silyl Enol Ethers 327 $a4.1 INTRODUCTION4.2 CATALYTIC [2+2] CYCLOADDITION REACTIONS OF SILYL ENOL ETHERS BY LEWIS ACID CATALYST; 4.2.1 Introduction; 4.2.2 Intramolecular [2+2] Cycloaddition Reactions; 4.2.3 Intermolecular [2+2] Cycloaddition Reactions; 4.2.4 Asymmetric Catalytic [2+2] Cycloaddition Reaction with Silyl Enol Ethers; 4.3 CATALYTIC [2+2] CYCLOADDITION REACTIONS OF SILYL ENOL ETHERS BY BRØNSTED ACID; 4.3.1 Catalytic [2+2] Cycloaddition Reactions of Silyl Enol Ethers by Trifluoromethanesulfonimide; 4.3.2 Multigram Syntheses of Cyclobutanes and Cyclobutenes by [2+2] Cycloaddition Reactions 327 $a4.3.3 Analysis of the Mechanism for [2+2] Cycloaddition Reactions by Trifluoromethanesulfonimide 330 $aAlthough these reactions have been studied for a long time, cycloaddition chemistry makes frequent and considerable advances that requires chemists to keep constantly up-to-date with the practices and state-of-the-art. Bringing together the contributions from leading worldwide researchers, Methods and Applications of Cycloaddition Reactions in Organic Syntheses provides a valuable guidebook for synthetic organic chemists involved in chemical research, pharmaceuticals, and materials science to keep organic chemists updated and current in the practices of cycloadditions, a leading class o 606 $aOrganic compounds$xSynthesis 606 $aRing formation (Chemistry) 615 0$aOrganic compounds$xSynthesis. 615 0$aRing formation (Chemistry) 676 $a547/.27 701 $aNishiwaki$b Nagatoshi$f1963-$01294155 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910828347603321 996 $aMethods and applications of cycloaddition reactions in organic syntheses$94017860 997 $aUNINA