LEADER 05266nam 2200637Ia 450 001 9910828161103321 005 20200520144314.0 010 $a1-282-54031-9 010 $a9786612540318 010 $a0-08-055050-9 035 $a(CKB)2670000000019540 035 $a(EBL)535154 035 $a(OCoLC)635293526 035 $a(SSID)ssj0000426055 035 $a(PQKBManifestationID)11250166 035 $a(PQKBTitleCode)TC0000426055 035 $a(PQKBWorkID)10372546 035 $a(PQKB)10473191 035 $a(Au-PeEL)EBL535154 035 $a(CaPaEBR)ebr10451127 035 $a(CaONFJC)MIL254031 035 $a(MiAaPQ)EBC535154 035 $a(EXLCZ)992670000000019540 100 $a20070611d2007 uy 0 101 0 $aeng 135 $aurcn||||||||| 181 $ctxt 182 $cc 183 $acr 200 10$aPrinciples of chemical kinetics /$fJames E. House 205 $a2nd ed. 210 $aAmsterdam ;$aBoston $cElsevier/Academic Press$dc2007 215 $a1 online resource (337 p.) 300 $aDescription based upon print version of record. 311 $a0-12-356787-4 320 $aIncludes bibliographical references and index. 327 $aFront Cover; Principles of Chemical Kinetics; Copyright Page; Preface; Contents; Chapter 1: Fundamental Concepts of Kinetics; 1.1 Rates of Reactions; 1.2.1 First-Order; 1.2.3 Zero-Order; 1.2.4 Nth-Order Reactions; 1.3 Cautions on Treating Kinetic Data; 1.5 Some Common Reaction Mechanisms; 1.5.3 Substitution Reactions; References for Further Reading; Problems; Chapter 2: Kinetics of More Complex Systems; 2.1 Second-Order Reaction, First-Order in Two Components; 2.3 Parallel Reactions; 2.7 Autocatalysis; References for Further Reading; Problems; Chapter 3: Techniques and Methods 327 $a3.1 Calculating Rate Constants 3.2 The Method of Half-Lives; 3.4 Using Large Excess of a Reactant (Flooding); 3.5 The Logarithmic Method; 3.6 Effects of Pressure; 3.9 Tracer Methods; References for Further Reading; Problems; Chapter 4: Reactions in the Gas Phase; 4.1 Collision Theory; 4.2 The Potential Energy Surface; 4.3 Transition State Theory; 4.4 Unimolecular Decomposition of Gases; 4.5 Free Radical or Chain Mechanisms; 4.6 Adsorption of Gases on Solids; 4.6.2 B-E-T Isotherm; References for Further Reading; Problems; Chapter 5: Reactions in Solutions; 5.1 The Nature of Liquids 327 $a5.1.1 Intermolecular Forces 5.1.2 The Solubility Parameter; 5.1.3 Solvation of Ions and Molecules; 5.1.4 The Hard-Soft Interaction Principle (HSIP); 5.2 Effects of Solvent Polarity on Rates; 5.3 Ideal Solutions; 5.5 Effects of Solvent Cohesion Energy on Rates; 5.6 Solvation and Its Effects on Rates; 5.7 Effects of Ionic Strength; 5.8 Linear Free Energy Relationships; 5.9 The Compensation Effect; 5.10 Some Correlations of Rates with Solubility Parameter; References for Further Reading; Problems; Chapter 6: Enzyme Catalysis; 6.1 Enzyme Action; 6.2.2 Lineweaver-Burk and Eadie Analyses 327 $a6.3.1 Competitive Inhibition References for Further Reading; Problems; Chapter 7: Kinetics of Reactions in the Solid State; 7.1 Some General Considerations; 7.2 Factors Affecting Reactions in Solids; 7.3 Rate Laws for Reactions in Solids; 7.3.1 The Parabolic Rate Law; 7.3.2 The First-Order Rate Law; 7.3.3 The Contracting Sphere Rate Law; 7.4 The Prout-Tompkins Equation; 7.5 Rate Laws Based on Nucleation; 7.6 Applying Rate Laws; 7.7 Results of Some Kinetic Studies; 7.7.1 The Deaquation-Anation of [Co(NH3)5H2O]Cl3; 7.7.3 The Dehydration of Trans-[Co(NH3)4Cl2]IO3bull 2H2O 327 $a7.7.4 Two Reacting Solids Problems; Chapter 8: Nonisothermal Methods in Kinetics; 8.1 TGA and DSC Methods; 8.3 The Reich and Stivala Method; 8.4 A Method Based on Three (alpha,T) Data Pairs; 8.5 A Method Based on Four (alpha,T) Data Pairs; 8.6 A Differential Method; 8.7 A Comprehensive Nonisothermal Kinetic Method; 8.8 The General Rate Law and a Comprehensive Method; References for Further Reading; Problems; Chapter 9: Additional Applications of Kinetics; 9.1 Radioactive Decay; 9.1.1 Independent Isotopes; 9.1.2 Parent-Daughter Cases; 9.3 A Further Look at Solvent Properties and Rates 327 $aReferences for Further Reading 330 $aJames House's revised Principles of Chemical Kinetics provides a clear and logical description of chemical kinetics in a manner unlike any other book of its kind. Clearly written with detailed derivations, the text allows students to move rapidly from theoretical concepts of rates of reaction to concrete applications. Unlike other texts, House presents a balanced treatment of kinetic reactions in gas, solution, and solid states. The entire text has been revised and includes many new sections and an additional chapter on applications of kinetics. The topics covered include quantitative 606 $aChemical kinetics 606 $aChemistry, Physical and theoretical 615 0$aChemical kinetics. 615 0$aChemistry, Physical and theoretical. 676 $a541/.394 700 $aHouse$b J. E$0897323 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910828161103321 996 $aPrinciples of chemical kinetics$93960482 997 $aUNINA