LEADER 05438nam 2200685 450 001 9910827804803321 005 20221102144014.0 010 $a3-527-69055-7 010 $a3-527-69054-9 035 $a(CKB)2670000000613248 035 $a(EBL)2030315 035 $a(SSID)ssj0001538363 035 $a(PQKBManifestationID)11922120 035 $a(PQKBTitleCode)TC0001538363 035 $a(PQKBWorkID)11536345 035 $a(PQKB)11278164 035 $a(MiAaPQ)EBC2030315 035 $a(Au-PeEL)EBL2030315 035 $a(CaPaEBR)ebr11048238 035 $a(CaONFJC)MIL776678 035 $a(OCoLC)907924106 035 $a(PPN)25947570X 035 $a(EXLCZ)992670000000613248 100 $a20150509h20152015 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aIntroduction to molecular magnetism $efrom transition metals to lanthanides /$fCristiano Benelli and Dante Gatteschi 210 1$aWeinheim, Germany :$cWiley-VCH,$d2015. 210 4$dİ2015 215 $a1 online resource (465 p.) 300 $aDescription based upon print version of record. 311 $a3-527-69056-5 311 $a3-527-33540-4 320 $aIncludes bibliographical references at the end of each chapters and index. 327 $aCover; Title Page; Copyright; Contents; Preface; Chapter 1 Introduction; 1.1 A Nano History of Molecular Magnetism; 1.2 Molecules, Conductors, and Magnets; 1.3 Origin of Molecular Magnetism; 1.4 Playing with the Periodic Table; 1.5 p Magnetic Orbitals; 1.6 d Magnetic Orbitals; 1.7 f Magnetic Orbitals; 1.8 The Goals of Molecular Magnetism; 1.9 Why a Book; 1.10 Outlook; 1.11 The Applications of Ln; 1.12 Finally SI versus emu; References; Chapter 2 Electronic Structures of Free Ions; 2.1 The Naked Ions; 2.2 Spin-Orbit Coupling; 2.3 Applying a Magnetic Field; References 327 $aChapter 3 Electronic Structure of Coordinated Ions3.1 Dressing Ions; 3.2 The Crystal Field; 3.3 The aquo Ions; 3.4 The Angular Overlap Model; 3.5 The Lantanum(III) with Phthalocyanine (Pc) and PolyOxoMetalates (POM); 3.6 Introducing Magnetic Anisotropy; References; Chapter 4 Coordination Chemistry and Molecular Magnetism; 4.1 Introduction; 4.2 Pyrazolylborates; 4.3 Phthalocyanines; 4.4 Cyclopentadiene and Cyclooctatetraene; 4.5 Polyoxometalates (POMs); 4.6 Diketonates; 4.7 Nitronyl-nitroxides (NITs); 4.8 Carboxylates; 4.9 Schiff Bases; References; Chapter 5 Magnetism of Ions 327 $a5.1 The Curie Law5.2 The Van Vleck Equation; 5.3 Anisotropy Steps in; References; Chapter 6 Molecular Orbital of Isolated Magnetic Centers; 6.1 Moving to MO; 6.2 Correlation Effects; 6.3 DFT; 6.4 The Complexity of Simple; 6.5 DFT and Single Ions; 6.6 DOTA Complexes, Not Only Contrast; References; Chapter 7 Toward the Molecular Ferromagnet; 7.1 Introduction; 7.2 A Road to Infinite; 7.3 Magnetic Interactions; 7.4 Introducing Interactions: Dipolar; 7.5 Spin Hamiltonians; 7.6 The Giant Spin; 7.7 Single Building Block; 7.8 Multicenter Interactions; 7.9 Noncollinearity 327 $a7.10 Introducing Orbital DegeneracyReferences; Chapter 8 Molecular Orbital of Coupled Systems; 8.1 Exchange and Superexchange; 8.2 Structure and Magnetic Correlations: d Orbitals; 8.3 Quantum Chemical Calculations of SH Parameters; 8.4 Copper Acetate!; 8.5 Mixed Pairs: Degenerate-Nondegenerate; 8.6 f Orbitals and Orbital Degeneracy; References; Chapter 9 Structure and Properties of p Magnetic Orbitals Systems; 9.1 Magnetic Coupling in Organics; 9.2 Magnetism in Nitroxides; 9.3 Thioradicals; 9.4 Metallorganic Magnets; 9.5 Semiquinone Radicals; 9.6 NITR Radicals with Metals 327 $a9.7 Long Distance Interactions in NitroxidesReferences; Chapter 10 Structure and Properties of Coupled Systems: d, f; 10.1 d Orbitals; 10.2 3d; 10.3 4d and 5d; 10.4 Introducing Chirality; 10.5 f-d Interactions; 10.6 A Model DFT Calculation; 10.7 Magneto-Structural Correlations in Gd-Cu; 10.8 f Orbital Systems and Orbital Degeneracy; References; Chapter 11 Dynamic Properties; 11.1 Introductory Remarks; 11.2 Spin-Lattice Relaxation and T1; 11.3 Phonons and Direct Mechanism; 11.4 Two Is Better than One; 11.5 Playing with Fields; 11.6 Something Real; 11.7 Spin-Spin Relaxation and T2; References 327 $aChapter 12 SMM Past and Present 330 $aThis first introduction to the rapidly growing field of molecular magnetism is written with Masters and PhD students in mind, while postdocs and other newcomers will also find it an extremely useful guide. Adopting a clear didactic approach, the authors cover the fundamental concepts, providing many examples and give an overview of the most important techniques and key applications. Although the focus is one lanthanide ions, thus reflecting the current research in the field, the principles and the methods equally apply to other systems. 606 $aMagnetochemistry 606 $aMolecular crystals$xMagnetic properties 606 $aRare earth metals 615 0$aMagnetochemistry. 615 0$aMolecular crystals$xMagnetic properties. 615 0$aRare earth metals. 676 $a541.378 700 $aBenelli$b Cristiano$01645324 702 $aGatteschi$b D$g(Dante), 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910827804803321 996 $aIntroduction to molecular magnetism$93991711 997 $aUNINA