LEADER 05622nam 2200721 450 001 9910827584503321 005 20200520144314.0 010 $a1-118-85883-2 010 $a1-118-85891-3 010 $a1-118-85914-6 035 $a(CKB)2670000000610006 035 $a(EBL)1895673 035 $a(MiAaPQ)EBC1895673 035 $a(DLC) 2014043995 035 $a(Au-PeEL)EBL1895673 035 $a(CaPaEBR)ebr11048210 035 $a(CaONFJC)MIL770213 035 $a(OCoLC)894777802 035 $a(PPN)194585115 035 $a(EXLCZ)992670000000610006 100 $a20150508h20152015 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $2rdacontent 182 $2rdamedia 183 $2rdacarrier 200 10$aPhysical chemistry for the biological sciences /$fGordon G. Hammes, Sharon Hammes-Schiffer 205 $aSecond edition. 210 1$aHoboken, New Jersey :$cWiley,$d2015. 210 4$d©2015 215 $a1 online resource (504 p.) 225 1 $aMethods of Biochemical Analysis ;$vVolume 55 300 $a"Part of Wiley Series in Methods of Biochemical Analysis." 311 $a1-118-85900-6 320 $aIncludes bibliographical references at the end of each chapters and index. 327 $aCover; Title Page; Copyright; Contents; Preface to First Edition; Preface to Second Edition; THERMODYNAMICS; Chapter 1 Heat, Work, and Energy; 1.1 Introduction; 1.2 Temperature; 1.3 Heat; 1.4 Work; 1.5 Definition of Energy; 1.6 Enthalpy; 1.7 Standard States; 1.8 Calorimetry; 1.9 Reaction Enthalpies; 1.10 Temperature Dependence of the Reaction Enthalpy; References; Problems; Chapter 2 Entropy and Gibbs Energy; 2.1 Introduction; 2.2 Statement of the Second Law; 2.3 Calculation of the Entropy; 2.4 Third Law of Thermodynamics; 2.5 Molecular Interpretation of Entropy; 2.6 Gibbs Energy 327 $a2.7 Chemical Equilibria2.8 Pressure and Temperature Dependence of the Gibbs Energy; 2.9 Phase Changes; 2.10 Additions to the Gibbs Energy; Problems; Chapter 3 Applications of Thermodynamics to Biological Systems; 3.1 Biochemical Reactions; 3.2 Metabolic Cycles; 3.3 Direct Synthesis of ATP; 3.4 Establishment of Membrane Ion Gradients by Chemical Reactions; 3.5 Protein Structure; 3.6 Protein Folding; 3.7 Nucleic Acid Structures; 3.8 DNA Melting; 3.9 RNA; References; Problems; Chapter 4 Thermodynamics Revisited; 4.1 Introduction; 4.2 Mathematical Tools; 4.3 Maxwell Relations 327 $a4.4 Chemical Potential4.5 Partial Molar Quantities; 4.6 Osmotic Pressure; 4.7 Chemical Equilibria; 4.8 Ionic Solutions; References; Problems; CHEMICAL KINETICS; Chapter 5 Principles of Chemical Kinetics; 5.1 Introduction; 5.2 Reaction Rates; 5.3 Determination of Rate Laws; 5.4 Radioactive Decay; 5.5 Reaction Mechanisms; 5.6 Temperature Dependence of Rate Constants; 5.7 Relationship Between Thermodynamics and Kinetics; 5.8 Reaction Rates Near Equilibrium; 5.9 Single Molecule Kinetics; References; Problems; Chapter 6 Applications of Kinetics to Biological Systems; 6.1 Introduction 327 $a6.2 Enzyme Catalysis: The Michaelis-Menten Mechanism6.3 ?-Chymotrypsin; 6.4 Protein Tyrosine Phosphatase; 6.5 Ribozymes; 6.6 DNA Melting and Renaturation; References; Problems; QUANTUM MECHANICS; Chapter 7 Fundamentals of Quantum Mechanics; 7.1 Introduction; 7.2 Schrödinger Equation; 7.3 Particle in a Box; 7.4 Vibrational Motions; 7.5 Tunneling; 7.6 Rotational Motions; 7.7 Basics of Spectroscopy; References; Problems; Chapter 8 Electronic Structure of Atoms and Molecules; 8.1 Introduction; 8.2 Hydrogenic Atoms; 8.3 Many-Electron Atoms; 8.4 Born-Oppenheimer Approximation 327 $a8.5 Molecular Orbital Theory8.6 Hartree-Fock Theory and Beyond; 8.7 Density Functional Theory; 8.8 Quantum Chemistry of Biological Systems; References; Problems; SPECTROSCOPY; Chapter 9 X-ray Crystallography; 9.1 Introduction; 9.2 Scattering of X-Rays by a Crystal; 9.3 Structure Determination; 9.4 Neutron Diffraction; 9.5 Nucleic Acid Structure; 9.6 Protein Structure; 9.7 Enzyme Catalysis; References; Problems; Chapter 10 Electronic Spectra; 10.1 Introduction; 10.2 Absorption Spectra; 10.3 Ultraviolet Spectra of Proteins; 10.4 Nucleic Acid Spectra; 10.5 Prosthetic Groups 327 $a10.6 Difference Spectroscopy 330 $a A new edition with complete, up-to-date and expanded material for a working knowledge of physical chemistry for the biological sciencesThe second edition of Physical Chemistry for the Biological Sciences builds on the success of the first edition with important updates and new material to provide a state-of-the-art introduction to physical chemistry for both professionals and students. The topics discussed include thermodynamics, kinetics, quantum mechanics, spectroscopy, statistical mechanics, and hydrodynamics. As in the first edition, most of the subjects can be understood without advanced 410 0$aMethods of biochemical analysis ;$vVolume 55. 606 $aPhysical biochemistry 606 $aThermodynamics 606 $aChemical kinetics 606 $aBiomolecules$xSpectra 606 $aSpectrum analysis 615 0$aPhysical biochemistry. 615 0$aThermodynamics. 615 0$aChemical kinetics. 615 0$aBiomolecules$xSpectra. 615 0$aSpectrum analysis. 676 $a612/.01583 700 $aHammes$b Gordon G.$f1934-$017344 702 $aHammes-Schiffer$b Sharon 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910827584503321 996 $aPhysical chemistry for the biological sciences$9230699 997 $aUNINA