LEADER 05089nam 2200625 450 001 9910826821803321 005 20200520144314.0 010 $a1-118-70929-2 010 $a1-118-70931-4 010 $a1-118-70933-0 035 $a(CKB)2550000001130089 035 $a(EBL)1469187 035 $a(OCoLC)860923523 035 $a(OCoLC)853618740 035 $a(MiAaPQ)EBC1469187 035 $a(DLC) 2013029041 035 $a(Au-PeEL)EBL1469187 035 $a(CaPaEBR)ebr10777216 035 $a(CaONFJC)MIL530136 035 $a(PPN)224484710 035 $a(EXLCZ)992550000001130089 100 $a20130722d2014 uy| 0 101 0 $aeng 135 $aur|n|---||||| 181 $2rdacontent 182 $2rdamedia 183 $2rdacarrier 200 10$aAlkynes in cycloadditions /$fauthor, Irina A. Maretina ; translated from the Russian by Boris I. Ionin ; consulting editor, John C. Tebby 210 1$aChichester, West Sussex :$cJohn Wiley & Sons, Inc.,$d2014. 215 $a1 online resource (312 p.) 300 $aIncludes index. 311 $a1-118-61532-8 311 $a1-299-98885-7 327 $aAlkynes in Cycloadditions; Contents; Preface; Acknowledgments; Biography; 1 Introduction; 2 Regioselective Syntheses of Polysubstituted Benzenes Catalyzed by Transition Metal Complexes; 2.1 [2+2+2] Cycloaddition Reactions of Acetylenes; 2.1.1 Reactions of Alkynes with Metallocyclopentadiene as an Intermediate; 2.1.2 Intra-intermolecular [2+2+2] Cycloaddition of Alkynes; 2.2 Stereochemical Aspect of Intramolecular and Intermolecular Reactions of Diynes with Monoalkynes; 2.2.1 Strategy of Enantioselective [2+2+2] Cycloaddition; 2.3 Heteroatom Bound to the Triple Bond 327 $a2.3.1 Nitrogen-Containing Substrates2.3.2 [2+2+2] Cycloadditions of Alkynes to Nitriles: Synthesis of Pyridines; 2.4 Heterohelicens. Asymmetric Syntheses; 2.4.1 Oxygen-Containing Helicens; 2.4.2 Nitrogen-Containing Helicens. Helical Dications; 2.5 Aromatic Rings with Boron and Silicon Substituents; 2.6 [2+2+2] Cycloaddition Reactions of 1-Alkynylphosphines and Their Derivatives; 2.7 Intramolecular [2+2+2] Cycloaddition of Diynes to Alkenes; 2.7.1 Allene as an Alkene Component; 2.7.2 Formation of Polycyclic Cyclohexadienes by Ru-catalyzed Cascade Reactions of 1,6-Diynes and Alkenes 327 $a2.7.3 Stereochemical Aspects of the Reaction of Diynes with Alkenes2.7.4 Hetero-[2+2+2] Cycloaddition of Alkynes to Compounds with a Multiple Carbon-Heteroatom Bond; 2.8 Reactions of [4+2] Cycloaddition and Other Approaches to the Synthesis of Polysubstituted Benzenes; 2.8.1 Reactions of Conjugated Enynes; 2.8.2 Acceleration of Pd-catalyzed [4+2]-Benzannulation in the Reaction of Enynes and Diynes in the Presence of Lewis Acids and Bronsted Bases; 2.9 Combined Reactions 327 $a2.9.1 Formal [4+2+2] Cycloaddition of 1,6-Diynes to 1,3-Dienes Catalyzed by Ru: Formation of Cyclooctatrienes and Vinylcyclohexadienes2.9.2 Formation of Eight-Membered Ring Systems by [4+2+2] Annulation; 2.9.3 AuBr3 (AlCl3)- and Cu(OTf)2-Catalyzed [4+2] Cycloaddition of Alkynyl- and Alkenyl-Enynones and Enynals: An Approach to Functionalized Polycyclic Hydrocarbons; 2.10 Construction of Polycyclic Systems; 2.10.1 Strategies for the Synthesis of Steroid Systems by Co-catalyzed [2+2+2] Cycloaddition of Nonconjugated Enyne-Allenes and Enediynes 327 $a2.10.2 Cobalt(I)-Mediated [2+2+2] Cyclization of Allene-Diynes: A Diastereoselective Approach to 11-aryl Steroid Core. 11-Aryl-Substituted Steroid Systems by Co-catalyzed [2+2+2] Cyclization of Allene-Diynes2.10.3 Synthesis of (3S)-hydroxyandrosta-5,7-diene-17-ones via Intramolecular Cobalt-Mediated [2+2+2] Cycloaddition; 2.10.4 Intramolecular Cycloaddition of Nonconjugated Enediynes of a Higher Order as a Route to Functionalized Condensed Polycyclic Systems; 2.10.5 A Strategy for the Synthesis of Aromatic Molecular-Bowl Hydrocarbons 327 $a2.10.6 A Route to Archimedenes: Total Synthesis of C3h-symmetric [7]phenylenes 330 $a Acetylene systems present a new route to cyclic compounds as an alternative to more traditional methods employed in classical organic chemistry. The synthesis of cyclic structures based on acetylene systems has important applications in the formation of nanostructures, naturally occurring compounds and chemosensory materials for the design of nonlinear optics, electronic and photonic devices. Alkynes in Cycloadditions presents a modern review of regioselective synthesis of aromatic and non-aromatic carbocyclic and heterocyclic ring systems based primarily on [2+2+2] and [4+2] c 606 $aAlkynes 606 $aRing formation (Chemistry) 615 0$aAlkynes. 615 0$aRing formation (Chemistry) 676 $a547/.413 700 $aMaretina$b Irina A$01609214 701 $aTebby$b John C.$f1933-$099393 701 $aIonin$b B. I$01609215 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910826821803321 996 $aAlkynes in cycloadditions$93936347 997 $aUNINA