LEADER 03826nam 22006614a 450 001 9910826684703321 005 20200520144314.0 010 $a1-280-20500-8 010 $a9786610205004 010 $a0-306-46940-5 024 7 $a10.1007/0-306-46940-5 035 $a(CKB)111056486603352 035 $a(EBL)3035683 035 $a(SSID)ssj0000145097 035 $a(PQKBManifestationID)11142423 035 $a(PQKBTitleCode)TC0000145097 035 $a(PQKBWorkID)10156891 035 $a(PQKB)11030762 035 $a(DE-He213)978-0-306-46940-4 035 $a(MiAaPQ)EBC3035683 035 $a(Au-PeEL)EBL3035683 035 $a(CaPaEBR)ebr10052998 035 $a(CaONFJC)MIL20500 035 $a(OCoLC)923696533 035 $a(PPN)237933802 035 $a(EXLCZ)99111056486603352 100 $a19990715d2000 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aElectrolytes at interfaces$b[electronic resource] /$fby S. Durand-Vidal, J.-P. Simonin and P. Turq 205 $a1st ed. 2002. 210 $aDordrecht ;$aBoston $cKluwer Academic Publishers$dc2000 215 $a1 online resource (359 p.) 225 1 $aProgress in theoretical chemistry and physics ;$vv. 1 300 $aDescription based upon print version of record. 311 $a0-7923-5922-4 320 $aIncludes bibliographical references and index. 327 $aBasic Concepts -- Hydrodynamic properties -- Electrostatics -- Van der Waals forces -- Bulk Electrolytes -- The mean spherical approximation (MSA) for the equal size primitive model -- Thermodynamic properties -- Ion association in the MSA -- Thermodynamic excess properties of ionic solutions in the primitive MSA -- Mathematical background -- Specific applications -- Ions at liquid/air and liquid/liquid interfaces -- Solute transfer kinetics at a liquid/liquid interface -- Electrokinetic phenomena -- Description of electrolyte transport using the MSA for simple electrolytes, polyelectrolytes and micelles -- Polyelectrolytes. 330 $aThe aim of this book is to provide the reader with a modern presentation of ionic solutions at interfaces, for physical chemists, chemists and theoretically oriented experimentalists in this field. The discussion is mainly on the structural and thermodynamic properties, in relation to presently available statistical mechanical models. Some dynamic properties are also presented, at a more phenomenological level. The initial chapters are devoted to the presentation of some basic concepts for bulk properties: hydrodynamic interactions, electrostatics, van der Waals forces and thermodynamics of ionic solutions in the framework of a particular model: the mean spherical approximation (MSA). Specific features of interfaces are then discussed: experimental techniques such as in-situ X-ray diffraction, STM and AFM microscopy are described. Ions at liquid/air, liquid/metal and liquid/liquid interfaces are considered from the experimental and theoretical viewpoint. Lastly some dynamic (transport) properties are included, namely the self-diffusion and conductance of small colloids (polyelectrolytes and micelles) and the kinetics of solute transfer at free liquid/liquid interfaces. 410 0$aProgress in theoretical chemistry and physics ;$vv. 1. 606 $aElectrolytes 606 $aInterfaces (Physical sciences) 615 0$aElectrolytes. 615 0$aInterfaces (Physical sciences) 676 $a541.3/72 700 $aDurand-Vidal$b S$01699249 701 $aSimonin$b J.-P$01699250 701 $aTurq$b Pierre$01699251 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910826684703321 996 $aElectrolytes at interfaces$94081362 997 $aUNINA