LEADER 06104nam 2200601Ia 450 001 9910825283403321 005 20200520144314.0 010 $a1-280-50065-4 010 $a9786610500659 010 $a1-904602-84-3 035 $a(CKB)1000000000032797 035 $a(OCoLC)191926095 035 $a(CaPaEBR)ebrary10087039 035 $a(SSID)ssj0000280079 035 $a(PQKBManifestationID)11241356 035 $a(PQKBTitleCode)TC0000280079 035 $a(PQKBWorkID)10268352 035 $a(PQKB)10552010 035 $a(PQKBManifestationID)16035136 035 $a(PQKB)22691029 035 $a(MiAaPQ)EBC3007737 035 $a(Au-PeEL)EBL3007737 035 $a(CaPaEBR)ebr10087039 035 $a(CaONFJC)MIL50065 035 $a(OCoLC)923619042 035 $a(EXLCZ)991000000000032797 100 $a19980716d2004 uy 0 101 0 $aeng 135 $aurcn||||||||| 181 $ctxt 182 $cc 183 $acr 200 10$aGrowth kinetics of chemical compound layers /$fV.I. Dybkov 210 $aCambridge $cCambridge International Science$d2004 215 $a1 online resource (201 p.) 300 $aIncludes index. 311 $a1-898326-34-7 327 $aIntro -- INTRODUCTORY REMARKS -- 1. SOLID-STATE GROWTH OF A CHEMICAL COMPOUND LAYER AT THE INTERFACE OF TWO ELEMENTARY SUBSTANCES -- 1.1 Special features of description of the kinetics of solid-state heterogeneous reactions -- 1.2 Reaction diffusion -- 1.3 Growth of the ApBq layer at the expense of diffusion of only component B -- 1.3.1 Critical thickness of the ApBq layer with regard to component B -- 1.3.2 Growth regime of the ApBq layer with regard to component B: Theoretical definition -- 1.3.3. Stationary state or stationary point? -- 1.4. Growth of the ApBq layer at the expense of diffusion of components A and B -- 1.4.1 Critical thickness and the growth regime of the ApBq layer with regard to component A -- 1.4.2 General kinetic equation: a single compound layer -- 1.4.3. Separate determination of the reaction diffusion constants -- 1.5. Linear growth of the Cu6Sn5 layer in the copper-tin reaction couple -- 1.6. Parabolic growth of the AlSb layer in the aluminium-antimony diffusion couple -- 1.7 Linear-parabolic growth of the chemical compound layer -- 1.8. The ratio of diffusion coefficients of a component in growing and nongrowing chemical compound layers -- 1.9 Growth of the layer of a single compound: Brief conclusions -- 2. GROWTH OF THE LAYERS OF TWO CHEMICAL COMPOUNDS BETWEEN ELEMENTARY SUBSTANCES -- 2.1. Chemical reactions at phase interfaces -- 2.2. A system of differential equations describing the formation rate of the layers of two chemical compounds -- 2.3. Initial linear growth of the ApBq and ArBs layers -- 2.4. Minimal thickness of the ArBs layer necessary for the ApBq layer to grow -- 2.5 Non-linear growth of the ApBq and ArBs layers -- 2.6 Effect of the critical thickness of the ApBq layer with regard to component A on the process of growth of the ArBs layer -- 2.7 'Paralinear' stage of growth of two compound layers. 327 $a2.8 Diffusional stage of growth of the ApBq and ArBs layers -- 2.9 Growth of the layers of two compounds: brief conclusions -- 3. GROWTH OF COMPOUND LAYERS IN A MULTIPHASE BINARY SYSTEM -- 3.1 Chemical reactions at the phase interfaces of a multiphase binary system -- 3.2 A system of differential equations describing the growth process of layers of three chemical compounds between elementary substances A and B -- 3.3 Initial linear growth of the layers -- 3.4 Transition from linear to non-linear kinetics -- 3.5 Critical values of the thickness of the layers and their effect on growth kinetics -- 3.6 Diffusional stage of formation of the layers -- 3.7 Sequence of formation of the layers of chemical compounds in the A-B reaction couple of a multiphase binary system -- 3.8 Multiphase growth of compound layers: brief conclusions -- 4. THE EFFECT OF COMPOSITIONS OF INITIAL PHASES ON THE GROWTH RATE OF A CHEMICAL COMPOUND LAYER -- 4.1 Growth of the ArBs layer at the A-B interface -- 4.2 Growth of the ArBs layer at the ApBq-B interface -- 4.2.1 Growth of the ArBs layer between ApBq and B at the expense of diffusion of only component A -- 4.2.2 Growth of the ArBs layer between ApBq and B at the expense of diffusion of both components -- 4.3 Growth of the ArBs layer at the ApBq - AlBn interface -- 4.4 Comparison of the growth rates of the ArBs layer in different reaction couples of the A - B multiphase system -- 4.5 Duplex structure of the ArBs layer -- 4.6 The effect of compositions of initial phases on the growth rate of a chemical compound layer: brief conclusions -- 5. THE EFFECT OF DISSOLUTION (EVAPORATION) ON THE GROWTH RATE OF A CHEMICAL COMPOUND LAYER -- 5.1 Main relationships governing dissolution of a solid in a liquid -- 5.2 Experimental investigation of the process of dissolution of a solid in a liquid. 327 $a5.2.1 Determination of saturation concentration -- 5.2.2 Determination of the dissolution rate constant -- 5.2.3 Determination of diffusion coefficients -- 5.3 Growth kinetics of the layer of a chemical compound under the conditions of its simultaneous dissolution in the liquid phase -- 5.4 Growth kinetics of intermetallic layers at the transition metal- liquid aluminium interface -- 5.5 Special features of kinetic dependences in the solid-gas system -- 5.5.1 Influence of evaporation on the growth of a chemical compound layer -- 5.5.2 Oxidation of chemical compounds -- 5.6 The effect of dissolution (evaporation) on the growth rate of a chemical compound layer: brief conclusions -- FINAL REMARKS -- REFERENCES -- Index. 606 $aChemical kinetics 606 $aChemical engineering 615 0$aChemical kinetics. 615 0$aChemical engineering. 676 $a541.394 700 $aDybkov$b V. I$g(Vasilii Ivanovich)$0996557 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910825283403321 996 $aGrowth kinetics of chemical compound layers$94073230 997 $aUNINA