LEADER 04855nam 2200685 a 450 001 9910822310903321 005 20240514074813.0 010 $a3-527-63963-2 010 $a1-283-37057-3 010 $a9786613370570 010 $a3-527-63962-4 010 $a3-527-63964-0 035 $a(CKB)2550000000073826 035 $a(EBL)822731 035 $a(OCoLC)768732536 035 $a(SSID)ssj0000612999 035 $a(PQKBManifestationID)11931508 035 $a(PQKBTitleCode)TC0000612999 035 $a(PQKBWorkID)10583960 035 $a(PQKB)10080418 035 $a(MiAaPQ)EBC822731 035 $a(Au-PeEL)EBL822731 035 $a(CaPaEBR)ebr10518734 035 $a(CaONFJC)MIL337057 035 $a(EXLCZ)992550000000073826 100 $a20120114d2011 uy 0 101 0 $aeng 135 $aurcn||||||||| 181 $ctxt 182 $cc 183 $acr 200 10$aTerpyridine-based materials $efor catalytic, optoelectronic and life science applications /$fUlrich S. Schubert, Andreas Winter, and George R. Newkome 205 $a1st ed. 210 $aWeinheim, Germany $cWiley-VCH$d2011 215 $a1 online resource (544 p.) 300 $aDescription based upon print version of record. 311 $a3-527-33038-0 320 $aIncludes bibliographical references and index. 327 $aTerpyridine-based Materials: For Catalytic, Optoelectronic and Life Science Applications; Contents; Preface; List of Abbreviations; 1: Introduction; 2: Synthesis, Properties, and Applications of Functionalized 2,2 ;-Terpyridines; 2.1: Introduction; 2.2: Basic Synthetic Strategies; 2.2.1: Ring-Assembly Methodologies; 2.2.2: Cross-Coupling Procedures; 2.3: Synthesis and Properties of 2,-Terpyridine Derivatives; 2.3.1: 4x2032;-Substituted 2, Terpyridinoxy Derivatives; 2.3.2: Miscellaneous 4;-Substituted 2,2032;-Terpyridine Derivatives 327 $a3.3.1: Synthesis of RuII and OsII Bis(terpyridine) Complexes 3.3.2: RuII Ions and Terpyridine Ligands - A Happy Marriage?; 3.3.2.1: Photophysical Properties; 3.3.2.2: Mononuclear RuII Bis(terpyridine) Complexes; 3.3.2.3: Oligonuclear Complexes Containing RuII/OsII Bis(terpyridine) Units; 3.3.2.4: Dendritic and Star-Shaped Systems Containing RuII Bis(terpyridine) Units; 3.4: Iridium(III) Complexes with Terpyridine Ligands; 3.5: Platinum(II) Mono(terpyridine) Complexes; 4: Metallo-Supramolecular Architectures Based on Terpyridine Complexes; 4.1: Introduction 327 $a4.2: Terpyridine-Containing Metallo-Macrocycles 4.3: The HETTAP Concept; 4.4: Racks and Grids; 4.5: Helicates; 4.6: Rotaxanes and Catenanes; 4.7: Miscellaneous Structures; 4.7.1: Cyclodextrin Derivatives; 4.7.2: Other Assemblies; 5: CO; -Conjugated Polymers Incorporating Terpyridine Metal Complexes; 5.1: Introduction; 5.2: Metallo-Supramolecular Polymerization; 5.3: Metallopolymers Based on CO; -Conjugated Bis(terpyridine)s; 5.3.1: Polymerization by Transition Metal Ion Coordination; 5.3.2: Self-Assembly of Metallopolymers; 5.3.3: Chiral Metallopolymers; 5.3.4: Non-Classical Metallopolymers 327 $a5.3.5: Polymerization Using the ''Complex First'' Method 5.4: Main-Chain Metallopolymers Based on Terpyridine-Functionalized CO; -Conjugated Polymers; 6: Functional Polymers Incorporating Terpyridine-Metal Complexes; 6.1: Introduction; 6.2: Polymers with Terpyridine Units in the Side-Chain; 6.2.1: Materials Based on Flexible Organic Polymers; 6.2.2: Materials Based on CO; -Conjugated Polymers; 6.3: Polymers with Terpyridines within the Polymer Backbone; 6.3.1: Polymers from Organic Small-Molecule Building Blocks; 6.3.2: Chain-Extended Polymers from Polymeric Building Blocks 327 $a6.3.3: Monotopic Macroligands by End-Group Functionalization 330 $aIn recent years, the utilization of terpyridines both in macromolecular structure assembly and device chemistry has exploded, enabling, for example, supramolecular polymer architectures with switchable chemical and physical properties as well as novel functional materials for optoelectronic applications such as light-emitting diodes and solar cells. Further applications include the usage of terpyridines and their metal complexes as catalysts for asymmetric organic reactions and, in a biological context, as anti-tumor agents or biolabels. This book covers terpyridine-based materials topics 606 $aPyridine 615 0$aPyridine. 676 $a547.593 686 $a540$2sdnb 686 $aVK 7150$2rvk 686 $aVK 7200$2rvk 700 $aSchubert$b U$g(Ulrich)$0864504 701 $aWinter$b Andreas$0941979 701 $aNewkome$b George R$g(George Richard)$0866143 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910822310903321 996 $aTerpyridine-based materials$94103101 997 $aUNINA