LEADER 04796nam 2200685Ia 450 001 9910820404203321 005 20240516061141.0 010 $a1-118-00539-2 010 $a1-283-09864-4 010 $a9786613098641 010 $a1-118-00537-6 035 $a(CKB)2550000000032875 035 $a(EBL)693209 035 $a(OCoLC)732956391 035 $a(SSID)ssj0000536814 035 $a(PQKBManifestationID)11359158 035 $a(PQKBTitleCode)TC0000536814 035 $a(PQKBWorkID)10550662 035 $a(PQKB)10159419 035 $a(MiAaPQ)EBC693209 035 $a(Au-PeEL)EBL693209 035 $a(CaPaEBR)ebr10466749 035 $a(CaONFJC)MIL309864 035 $a(MiAaPQ)EBC7103409 035 $a(Au-PeEL)EBL7103409 035 $a(EXLCZ)992550000000032875 100 $a20101027d2011 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aFoundations of organic chemistry $eunity and diversity of structures, pathways, and reactions /$fby David R. Dalton 205 $a1st ed. 210 $aHoboken, N.J. $cWiley$dc2011 215 $a1 online resource (1436 p.) 225 1 $aNew York Academy of Sciences 300 $aDescription based upon print version of record. 311 $a0-470-47908-6 320 $aIncludes bibliographical references and index. 327 $aFOUNDATIONS OF ORGANIC CHEMISTRY; CONTENTS; PREFACE; ACKNOWLEDGMENTS; PART I: BACKGROUND; CHAPTER 1: An Introduction to Structure and Bonding; A: THE SOURCES OF CARBON COMPOUNDS; I. How Do We Know a Material Is Pure?; B. MORE ABOUT HYDROCARBONS; I. Combustion-Heats of Reaction; C. ON THE NATURE OF THE CHEMICAL BOND; I. Ionic and Nonpolar Covalent Bonds; II. Polar Covalent Bonds; III. Orbital Hybridization; IV. Allotropes of Carbon; V. Combination of Ionic and Covalent Bonding; NOTICE TO THE STUDENT; ADDITIONAL PROBLEMS; REFERENCE 327 $aCHAPTER 2: An Introduction to Spectroscopy and Selected Spectroscopic Methods in Organic ChemistryA. GENERAL INTRODUCTION; B. X-RAY CRYSTALLOGRAPHY; C. PHOTON SPECTROSCOPY; I. General Introduction; II. UV and VIS Spectroscopy; III. IR Spectroscopy; IV. Raman Spectroscopy; V. Microwave Spectroscopy; VI. Magnetic Resonance Spectroscopy; a. NMR; b. ESR; D. MS; I. Creation of Ions in the Mass Spectrometer: The Ionization Chamber; II. The Separation of Ions by Mass: The Mass Analyzer; III. Detecting the Ions; ADDITIONAL PROBLEMS; REFERENCE 327 $aCHAPTER 3: Structure: The Nomenclature of Hydrocarbons and the Shape of Things to ComeA. INTRODUCTION; B. NOMENCLATURE AND SPECTROSCOPY; I. Alkanes; a. Acyclic Alkanes; b. Cyclic Alkanes; II. Alkenes, Arenes, and Alkynes; a. Alkenes; b. Arenes; c. Alkynes; C. PHYSICAL AND CHEMICAL PROPERTIES; OXIDATION AND REDUCTION OF HYDROCARBONS; I. The Concept of Homology; II. Oxidation and Reduction; a. Oxidation; b. Reduction; ADDITIONAL PROBLEMS; REFERENCES; CHAPTER 4: An Introduction to Dynamics; A. INTRODUCTION; B. REVIEW OF SOME ENERGY CONSIDERATIONS; C. THE BARRIER BETWEEN REACTANTS AND PRODUCTS 327 $aCHAPTER 5: Classes of Organic Compounds-A Survey: An Introduction to Solvents and to Acids and Bases and to Computational ChemistryA. INTRODUCTION; B. GENERAL CHARACTERISTICS OF FUNCTIONAL GROUP PLACEMENT; C. THE FUNCTIONAL GROUPS AND THEIR NAMES; I. Hydrocarbons; a. Alkanes; b. Alkenes; c. Alkynes; d. Arenes; II. Alkyl and Aryl Halides; III. Alcohols and Phenols; IV. Ethers; V. Thiols, Thioethers, Disulfides, and Their Oxides; VI. Amines, Hydrazines, and Other Nitrogenous Materials; VII. Phosphines, Phosphonium Salts, and Other Phosphorus Derivatives 327 $aVIII. An Introduction to Organometallic Compounds 330 $aThis book differs from other organic chemistry textbooks in that it is not focused purely on the needs of students studying premed, but rather for all students studying organic chemistry. It directs the reader to question present assumptions rather than to accept what is told, so the second chapter is largely devoted to spectroscopy (rather than finding it much later on as with most current organic chemistry textbooks). Additionally, after an introduction to spectroscopy, thermodynamics and kinetics, the presentation of structural information of compounds and organic families advances from hyd 410 0$aNew York Academy of Sciences 606 $aChemistry, Organic$vTextbooks 606 $aOrganic compounds 615 0$aChemistry, Organic 615 0$aOrganic compounds. 676 $a547 700 $aDalton$b David R$01714348 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910820404203321 996 $aFoundations of organic chemistry$94108088 997 $aUNINA