LEADER 03411nam 2200601 a 450 001 9910820073903321 005 20210916150752.0 010 $a1-280-58131-X 010 $a9786613611093 010 $a0-12-415884-6 035 $a(CKB)2670000000147354 035 $a(EBL)872587 035 $a(OCoLC)781260639 035 $a(SSID)ssj0000629765 035 $a(PQKBManifestationID)12266045 035 $a(PQKBTitleCode)TC0000629765 035 $a(PQKBWorkID)10743058 035 $a(PQKB)11604290 035 $a(Au-PeEL)EBL872587 035 $a(CaPaEBR)ebr10537915 035 $a(CaONFJC)MIL361109 035 $a(PPN)182571483 035 $a(FR-PaCSA)88812293 035 $a(MiAaPQ)EBC872587 035 $a(EXLCZ)992670000000147354 100 $a20010606d2011 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aOrganic synthesis /$fMichael B. Smith 205 $a3rd ed. 210 $a[Boston] $cAcademic Press, an imprint of Elsevier$d[2011] 215 $a1 online resource (1536 p.) 300 $aDescription based upon print version of record. 311 $a1-890661-40-6 320 $aIncludes bibliographical references and indexes. 327 $aFront Cover; Organic Synthesis; Copyright Page; About the Author; Table of Contents; Preface to the 3rd edition; Preface to the 1st edition. Why I wrote this book!; Common Abbreviations; Chapter 1: Retrosynthesis, Stereochemistry, and Conformations; 1.1. Introduction; 1.2. The Disconnection Protocol; 1.3. Bond Proximity and Implications for Chemical Reactions; 1.4. Stereochemistry; 1.5. Conformations; 1.6. Conclusion; Homework; Chapter 2: Acids, Bases and Functional Group Exchange Reactions; 2.1. Introduction; 2.2. Brønsted-Lowry Acids and Bases; 2.3. Lewis Acids 327 $a4.6. Borane, Aluminum Hydride, and Derivatives4.7. Stereoselectivity in Reductions; 4.8. Catalytic Hydrogenation; 4.9. Dissolving Metal Reductions; 4.10. Nonmetallic Reducing Agents; 4.11. Conclusion; Homework; Chapter 5 : Hydroboration; 5.1. Introduction; 5.2. Preparation of Alkyl and Alkenyl Boranes; 5.3. Synthetic Transformations; 5.4. Formation of Oxygen-Containing Functional Groups; 5.5. Amines and Sulfides via Hydroboration; 5.6. Conclusion; Homework; Chapter 6 : Stereocontrol and Ring Formation; 6.1. Introduction; 6.2. Stereocontrol in AcyclIc Systems 327 $a8.5. OrganoLithium Reagents (C-Li) 330 $aA reactions oriented course is a staple of most graduate organic programs, and synthesis is taught either as a part of that course or as a special topic. Ideally, the incoming student is an organic major, who has a good working knowledge of basic reactions, stereochemistry and conformational principles. In fact, however, many (often most) of the students in a first year graduate level organic course have deficiencies in their undergraduate work, are not organic majors and are not synthetically inclined. To save students much time catching up this text provides a reliable and readily 606 $aOrganic compounds$xSynthesis 615 0$aOrganic compounds$xSynthesis. 676 $a547/.2 700 $aSmith$b Michael$f1946 October 17-$066607 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910820073903321 996 $aOrganic synthesis$985244 997 $aUNINA