LEADER 05449nam 2200697Ia 450 001 9910819438103321 005 20240516163059.0 010 $a3-527-65259-0 010 $a1-280-66334-0 010 $a9786613640277 010 $a3-527-65257-4 010 $a3-527-65260-4 035 $a(CKB)2550000000099614 035 $a(EBL)915632 035 $a(OCoLC)798929495 035 $a(SSID)ssj0000655007 035 $a(PQKBManifestationID)11389757 035 $a(PQKBTitleCode)TC0000655007 035 $a(PQKBWorkID)10595685 035 $a(PQKB)10851518 035 $a(MiAaPQ)EBC915632 035 $a(Au-PeEL)EBL915632 035 $a(CaPaEBR)ebr10560610 035 $a(CaONFJC)MIL364027 035 $a(EXLCZ)992550000000099614 100 $a20120528d2012 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aComplex-shaped metal nanoparticles$b[electronic resource] $ebottom-up syntheses and applications /$fedited by Tapan K. Sau and Andrey L. Rogachi 205 $a1st ed. 210 $aManheim, Germany $cWiley$dc2012 215 $a1 online resource (584 p.) 300 $aDescription based upon print version of record. 311 $a3-527-33077-1 320 $aIncludes bibliographical references and index. 327 $aComplex-shaped Metal Nanoparticles: Bottom-Up Syntheses and Applications; Foreword; Contents; Preface; List of Contributors; Metal Nanoparticles of Complex Morphologies: A General Introduction; References; 1 Colloidal Synthesis of Noble Metal Nanoparticles of Complex Morphologies; 1.1 Introduction; 1.2 Classification of Noble Metal Nanoparticles; 1.3 Synthesis Methodologies; 1.3.1 Chemical Reduction Method; 1.3.1.1 Spatially Confined Medium/Template Approach; 1.3.1.2 Preformed Seed-Mediated Synthesis; 1.3.1.3 High-Temperature Reduction Method; 1.3.2 Chemical Transformation Method 327 $a1.3.2.1 Galvanic Displacement Method1.3.2.2 Etching Method; 1.3.3 Electrochemical Synthesis; 1.3.4 Photochemical Method; 1.3.5 Biosynthesis; 1.3.6 Postpreparation Separation; 1.4 Characterization; 1.5 Thermodynamic-Kinetic Factors and Particle Morphology; 1.5.1 Nucleation and Growth; 1.5.1.1 Homogeneous and Heterogeneous Nucleations; 1.5.1.2 Defects in Seed Crystal; 1.5.1.3 Growth of Seed Crystal; 1.5.2 Reaction Parameters; 1.5.2.1 Reactants and Their Concentrations; 1.5.2.2 Additives/Impurities; 1.5.2.3 Solvent, pH, and Temperature; 1.6 Mechanisms of Morphology Evolution 327 $a1.6.1 One-Dimensional Nanoparticle Formation1.6.1.1 Nanorod Formation; 1.6.1.2 Nanobipyramid Formation; 1.6.2 Two-Dimensional Nanoparticle Formation; 1.6.3 Three-Dimensional Polyhedral Shape Evolution; 1.6.4 Epitaxial/Core-Shell/Heterodimer/Overgrowth Mechanism; 1.6.5 Branched Nanoparticle Formation; 1.6.6 Hollow/Porous Nanoparticle Formation; 1.7 Conclusions and Outlook; References; 2 Controlling Morphology in Noble Metal Nanoparticles via Templating Approach; 2.1 Introduction; 2.2 Galvanic Replacement Method; 2.2.1 Synthesis of Quasi-Zero-Dimensional Nanoparticles 327 $a2.2.2 Synthesis of One-Dimensional Nanostructures2.3 Hard Template-Directed Method; 2.3.1 Porous Membrane Template-Directed Method; 2.3.2 Pattern Template-Directed Method; 2.4 Soft Template-Directed Method; 2.4.1 Micelle Template-Directed Synthesis; 2.4.2 Selective Adsorption-Directed Synthesis; 2.5 Conclusions and Outlook; References; 3 Shape-Controlled Synthesis of Metal Nanoparticles of High Surface Energy and Their Applications in Electrocatalysis; 3.1 Introduction; 3.2 Fundamentals and Background; 3.2.1 Thermodynamics of Crystallization: Principles and Rules 327 $a3.2.1.1 Equilibrium Shape of a Crystal3.2.1.2 Nucleation; 3.2.1.3 Three-Dimensional Growth of a Crystal on Substrate; 3.2.1.4 Two-Dimensional Nuclei Theory; 3.2.2 Correlation of the Shape of Crystal and Its Surface Structure; 3.3 Progress in Shape-Controlled Synthesis of Metal Nanoparticles of High Surface Energy and Their Applications; 3.3.1 Electrochemistry Route; 3.3.1.1 Pt and Pd Nanoparticles; 3.3.1.2 Fe Nanoparticles; 3.3.2 Wet Chemistry Route; 3.3.2.1 Au Nanoparticles; 3.3.2.2 Pd and Pd-Au Nanoparticles; 3.3.2.3 Pt Nanoparticles 327 $a3.4 Theoretical Simulations of Structural Transformation and Stability of Metal Nanoparticles with High Surface Energy 330 $aThe past few years have witnessed the development of non-spherical metal nanoparticles with complex morphologies, which offer tremendous potential in materials science, chemistry, physics and medicine.Covering all important aspects and techniques of preparation and characterization of metal nanoparticles with controlled morphology and architecture, this book provides a sound overview - from the basics right up to recent developments. Renowned research scientists from all over the world present the existing knowledge in the field, covering theory and modeling, synthesis and prope 606 $aMetal clusters 606 $aNanoparticles 615 0$aMetal clusters. 615 0$aNanoparticles. 676 $a620.1 676 $a620.1/699 676 $a620.5 701 $aSau$b Tapan K$01647255 701 $aRogachi$b Andrey L$01647256 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910819438103321 996 $aComplex-shaped metal nanoparticles$93994720 997 $aUNINA