LEADER 05537nam 2200721Ia 450 001 9910818229403321 005 20240418150008.0 010 $a1-282-01326-2 010 $a9786612013263 010 $a1-4443-0001-6 010 $a1-4443-0000-8 035 $a(CKB)1000000000715995 035 $a(EBL)416477 035 $a(OCoLC)437097834 035 $a(SSID)ssj0000221202 035 $a(PQKBManifestationID)11190869 035 $a(PQKBTitleCode)TC0000221202 035 $a(PQKBWorkID)10161145 035 $a(PQKB)10661611 035 $a(MiAaPQ)EBC416477 035 $a(Au-PeEL)EBL416477 035 $a(CaPaEBR)ebr10300787 035 $a(CaONFJC)MIL201326 035 $a(PPN)140475850 035 $a(EXLCZ)991000000000715995 100 $a20081020d2009 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aPhotochemistry of organic compounds$b[electronic resource] $efrom concepts to practice /$fPetr Kla?n, Jakob Wirz 205 $a1st ed. 210 $aChichester, U.K. $cWiley$d2009 215 $a1 online resource (583 p.) 225 1 $aPostgraduate chemistry series 300 $aDescription based upon print version of record. 311 $a1-4051-9088-4 311 $a1-4051-6173-6 320 $aIncludes bibliographical references (p. [471]-548) and index. 327 $aPhotochemistry Of Organic Compounds: From Concepts To Practice; Contents; Special Topics; Case Studies; Foreword; Preface; 1 Introduction; 1.1 Who's Afraid of Photochemistry?; 1.2 Electromagnetic Radiation; 1.3 Perception of Colour; 1.4 Electronic States: Elements of Molecular Quantum Mechanics; 1.5 Problems; 2 A Crash Course in Photophysics and a Classification of Primary Photoreactions; 2.1 Photophysical Processes; 2.1.1 State Diagrams; 2.1.2 Beer-Lambert Law; 2.1.3 Calculation of Fluorescence Rate Constants from Absorption Spectra; 2.1.4 Dipole and Transition Moments, Selection Rules 327 $a2.1.5 Rate Constants of Internal Conversion the Energy Gap Law; 2.1.6 Rate Constants of Intersystem Crossing, El Sayed Rules; 2.1.7 Quantum Yield: Definition; 2.1.8 Kasha and Vavilov Rules; 2.1.9 Franck-Condon Principle; 2.2 Energy Transfer, Quenching and Sensitization; 2.2.1 Diffusion-Controlled Reactions in Solution, Spin Statistics; 2.2.2 Energy Transfer; 2.2.3 Excimers and Exciplexes; 2.2.4 Delayed Fluorescence; 2.2.5 Dioxygen; 2.3 A Classification of Photochemical Reaction Pathways; 2.4 Problems; 3 Techniques and Methods; 3.1 Light Sources, Filters and Detectors 327 $a3.2 Preparative Irradiation3.3 Absorption Spectra; 3.4 Steady-State Emission Spectra and their Correction; 3.5 Time-Resolved Luminescence; 3.6 Absorption and Emission Spectroscopy with Polarized Light; 3.7 Flash Photolysis; 3.7.1 Kinetic Flash Photolysis; 3.7.2 Spectrographic Detection Systems; 3.7.3 Pump-Probe Spectroscopy; 3.7.4 Analysis of Kinetic Data; 3.7.5 Global Analysis of Transient Optical Spectra; 3.8 Time-Resolved IR and Raman Spectroscopy; 3.9 Quantum Yields; 3.9.1 Differential Quantum Yield; 3.9.2 Actinometry; 3.9.3 Spectrophotometric Determination of the Reaction Progress 327 $a3.9.4 Reversible Photoreactions3.9.5 Luminescence Quantum Yields; 3.9.6 Polychromatic Actinometry and Heterogeneous Systems; 3.9.7 Relating Quantum Yields to Rate Constants; 3.9.8 Stern-Volmer Analysis; 3.9.9 Quantum Yields of Triplet Formation; 3.9.10 Experimental Arrangements for Quantum Yield Measurements; 3.10 Low-Temperature Studies; Matrix Isolation; 3.11 Photoacoustic Calorimetry; 3.12 Two-Photon Absorption Spectroscopy; 3.13 Single-Molecule Spectroscopy; 3.14 Problems; 4 Quantum Mechanical Models of Electronic Excitation and Photochemical Reactivity 327 $a4.1 Boiling Down the Schro?dinger Equation4.2 Hu?ckel Molecular Orbital Theory; 4.3 HMO Perturbation Theory; 4.4 Symmetry Considerations; 4.5 Simple Quantum Chemical Models of Electronic Excitation; 4.6 Pairing Theorems and Dewar's PMO Theory; 4.7 The Need for Improvement; SCF, CI and DFT Calculations; 4.8 Spin-Orbit Coupling; 4.9 Theoretical Models of Photoreactivity, Correlation Diagrams; 4.10 Problems; 4.11 Appendix; 4.11.1 First-Order Perturbation; 4.11.2 Second-Order Perturbation; 5 Photochemical Reaction Mechanisms and Reaction Intermediates; 5.1 What is a Reaction Mechanism? 327 $a5.2 Electron Transfer 330 $aPhotochemistry of Organic Compounds: From Concepts to Practice provides a hands-on guide demonstrating the underlying principles of photochemistry and, by reference to a range of organic reaction types, its effective use in the synthesis of new organic compounds and in various applications. The book presents a complete and methodical approach to the topic,Working from basic principles, discussing key techniques and studies of reactive intermediates, and illustrating synthetic photochemical procedures.Incorporating special topics and case studies covering various applicatio 410 0$aPostgraduate chemistry series. 606 $aOrganic compounds$xSynthesis 606 $aOrganic photochemistry 615 0$aOrganic compounds$xSynthesis. 615 0$aOrganic photochemistry. 676 $a541.35 676 $a572.435 700 $aKla?n$b Petr$0472474 701 $aWirz$b Jakob$0731284 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910818229403321 996 $aPhotochemistry of organic compounds$91440617 997 $aUNINA