LEADER 05600nam 2200769 a 450 001 9910818145703321 005 20240516163739.0 010 $a9786613722683 010 $a9781280881374 010 $a1280881372 010 $a9781118463208 010 $a111846320X 010 $a9781118463215 010 $a1118463218 010 $a9781118463185 010 $a1118463188 035 $a(CKB)2670000000209921 035 $a(EBL)918624 035 $a(OCoLC)798535399 035 $a(SSID)ssj0000678013 035 $a(PQKBManifestationID)11449745 035 $a(PQKBTitleCode)TC0000678013 035 $a(PQKBWorkID)10696991 035 $a(PQKB)10740311 035 $a(MiAaPQ)EBC918624 035 $a(Au-PeEL)EBL918624 035 $a(CaPaEBR)ebr10579521 035 $a(CaONFJC)MIL372268 035 $a(Perlego)1012781 035 $a(EXLCZ)992670000000209921 100 $a20120424d2012 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aIntroduction to industrial polypropylene $eproperties, catalysts, processes /$fDennis B. Malpass and Elliot I. Band 205 $a1st ed. 210 $aSalem, Mass. $cScrivener ;$aHoboken, N.J. $cWiley$dc2012 215 $a1 online resource (356 p.) 300 $aDescription based upon print version of record. 311 08$a9781118062760 311 08$a1118062760 320 $aIncludes bibliographical references and index. 327 $aIntroduction to Industrial Polypropylene: Properties, Catalysts, Processes; Contents; List of Tables; List of Figures; Preface; 1 Introduction to Polymers of Propylene; 1.1 Origins of Crystalline Polypropylene; 1.2 Basic Description of Polypropylene; 1.3 Types and Nomenclature of Polypropylene; 1.4 Molecular Weight of Polypropylene; 1.5 Transition Metal Catalysts for Propylene Polymerization; 1.6 Questions; References; 2 Polymer Characterization; 2.1 Introduction; 2.2 Polymer Tacticity; 2.2.1 Introduction; 2.2.2 Measurement of Polymer Microtacticity by 13C NMR; 2.2.3 Total Isotactic Index 327 $a2.2.4 Total Xylene Insolubles2.3 Molecular Weight and Molecular Weight Distribution; 2.3.1 Introduction; 2.3.2 Gel Permeation Chromatography; 2.3.3 Intrinsic Viscosity; 2.3.4 Melt Flow Rate; 2.4 Polymer Bulk Density; 2.4.1 Introduction; 2.4.2 Measurement Method; 2.5 Particle Size Distribution and Morphology; 2.5.1 Introduction; 2.5.2 Measurement Method; 2.6 Questions; References; 3 Ziegler-Natta Catalysts; 3.1 A Brief History of Ziegler-Natta Catalysts; 3.2 Definitions and Nomenclature; 3.3 Characteristics of Ziegler-Natta Catalysts; 3.4 Early Commercial Ziegler-Natta Catalysts 327 $a3.5 Supported Ziegler-Natta Catalysts3.6 Prepolymerized Ziegler-Natta Catalysts; 3.7 Mechanism of Ziegler-Natta Polymerization; 3.8 Questions and Exercises; References; 4 Propylene Polymerization Catalysts; 4.1 Introduction; 4.2 Zero Generation Ziegler-Natta Catalysts; 4.3 First Generation ZN Catalysts; 4.4 Second Generation ZN Catalysts; 4.5 Third Generation ZN Catalysts; 4.6 Fourth Generation ZN Catalysts; 4.7 Fifth Generation ZN Catalysts; 4.8 ZN Catalysts for Atactic Polypropylene; 4.9 Metallocenes and Other Single Site Catalysts; 4.10 Cocatalysts for ZN Catalysts 327 $a4.11 Kinetics and ZN Catalyst Productivity4.12 Concluding Remarks; 4.13 Questions; References; 5 Aluminum Alkyls in Ziegler-Natta Catalysts; 5.1 Organometallic Compounds; 5.2 Characteristics of Aluminum Alkyls; 5.2.1 Basic Physical and Chemical Properties; 5.2.2 Hydride Content; 5.2.3 Other R3A1 Impurities; 5.2.4 Analysis of Aluminum Alkyls; 5.2.5 Impurities Resulting from Exposure to Minute Concentrations of Water and Oxygen; 5.2.6 Assays of Aluminum Alkyls; 5.2.7 Reactivity with Organic Substrates; 5.2.8 Reactivity with CO2 and CO; 5.2.9 Distillation; 5.2.10 Association of Aluminum Alkyls 327 $a5.2.11 Storage Stability5.2.12 Thermal Stability; 5.3 Production of Aluminum Alkyls; 5.4 Reducing Agent for the Transition Metal; 5.5 Alkylating Agent for Creation of Active Centers; 5.6 Scavenger of Catalyst Poisons; 5.7 Chain Transfer Agent; 5.8 Safety and Handling of Aluminum Alkyls; 5.9 Questions; References; 6 Single Site Catalysts and Cocatalysts; 6.1 Introduction; 6.2 The Structures of Metallocenes and SSCs; 6.3 Non-Metallocene Polymerization Catalysts; 6.4 Cocatalysts for SSCs; 6.4.1 Aluminoxanes; 6.4.2 Organoboron Cocatalysts; 6.4.3 Activated Supports; 6.5 Supports for SSCs 327 $a6.6 Characteristics of mPP 330 $a This introductory text is an important resource for new engineers, chemists, students, and chemical industry personnel to understand the technical aspects of polypropylene which is the 2nd largest synthetics polymer in manufactured output. The book considers the following topics: What are the principal types of polypropylene and how do they differ? What catalysts are used to produce polypropylene and how do they function? What is the role of cocatalysts and how have they evolved over the years? How are industrial polypropylene catalysts tested an 606 $aPolypropylene 606 $aPolymers 606 $aPolymerization 615 0$aPolypropylene. 615 0$aPolymers. 615 0$aPolymerization. 676 $a668.4/234 700 $aMalpass$b Dennis B$01610646 701 $aBand$b Elliot I$01610647 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910818145703321 996 $aIntroduction to industrial polypropylene$93938478 997 $aUNINA