LEADER 01334nam a2200289 i 4500 001 991003421579707536 005 20020509121836.0 008 980109s1994 us ||| | eng 020 $a1884419011 035 $ab11158955-39ule_inst 035 $aPARLA181542$9ExL 040 $aDip.to Scienze dell'Antichità$bita 100 1 $aGiordano, Paolo A.$0540174 245 10$aJoseph Tusiani :$bpoet translator humanist :$ban international homage /$ceditor Paolo A. Giordano 260 $aWest Lafayette :$bBordighera,$cc1994 300 $a352 p. ;$c22 cm. 500 $aBibliografia: p. 341-352. 650 4$aTusiani, Joseph - Scritti in onore 907 $a.b11158955$b02-04-14$c28-06-02 912 $a991003421579707536 945 $aLE015 Fondo Tusiani 13$g1$i2015000006394$lle007$o-$pE0.00$q-$rl$s- $t0$u0$v0$w0$x0$y.i11302112$z28-06-02 945 $aLE015 Fondo Tusiani 13 bis$g2$i2015000006622$lle007$o-$pE0.00$q-$rl$s- $t0$u0$v0$w0$x0$y.i11302124$z28-06-02 945 $aLE015 Fondo Tusiani 13 ter$g3$i2015000006639$lle007$o-$pE0.00$q-$rl$s- $t0$u0$v0$w0$x0$y.i11302136$z28-06-02 945 $aLE015 Fondo Tusiani 13 quater$g4$i2015000006646$lle007$o-$pE0.00$q-$rl$s- $t0$u0$v0$w0$x0$y.i11302148$z28-06-02 996 $aJoseph Tusiani$9872695 997 $aUNISALENTO 998 $ale007$b01-01-98$cm$da $e-$feng$gus $h0$i4 LEADER 05920nam 22008294a 450 001 9910817898003321 005 20200520144314.0 010 $a9786610270958 010 $a9781280270956 010 $a1280270950 010 $a9780470300138 010 $a0470300132 010 $a9780470858455 010 $a0470858451 010 $a9780470858448 010 $a0470858443 035 $a(CKB)1000000000244151 035 $a(EBL)470188 035 $a(OCoLC)57598338 035 $a(SSID)ssj0000156245 035 $a(PQKBManifestationID)11159996 035 $a(PQKBTitleCode)TC0000156245 035 $a(PQKBWorkID)10123772 035 $a(PQKB)10840000 035 $a(MiAaPQ)EBC470188 035 $a(Au-PeEL)EBL470188 035 $a(CaPaEBR)ebr10114036 035 $a(CaONFJC)MIL27095 035 $a(Perlego)2760267 035 $a(EXLCZ)991000000000244151 100 $a20040217d2004 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aFluxional organometallic and coordination compounds /$fedited by Marcel Gielen, Rudolph Willem, Bernd Wrackmeyer 205 $a1st ed. 210 $aHoboken, NJ $cJ. Wiley$dc2004 215 $a1 online resource (343 p.) 225 1 $aPhysical organometallic chemistry ;$vv. 4 300 $aDescription based upon print version of record. 311 08$a9780470858394 311 08$a0470858397 320 $aIncludes bibliographical references and index. 327 $aFluxional Organometallic and Coordination Compounds; Contents; Contributors; Series Preface; Preface; 1 Polyhedral Dynamics and the Jahn-Teller Effect; 1 Introduction; 2 Polyhedron Topology; 3 Polyhedral Isomerizations: Microscopic Models; 3.1 Diamond-Square-Diamond Processes; 3.2 Gale Diagrams; 3.3 Generation of Metallaborane Structures by Diamond-Square-Diamond Transformations in Deltahedra; 4 Polyhedral Isomerizations: Macroscopic Models; 4.1 Topological Representations of Polyhedral Isomerizations; 4.2 Topological Representations of Jahn-Teller Distortions; 5 Acknowledgement; 6 References 327 $a2 NMR Studies of Intramolecular Dynamics in Allylic Type Triorganoboranes1 Introduction; 2 Discovery Activation Parameters of [1,3]-B Shifts; 3 Fluxional Linear Polyunsaturated Allylboranes; 3.1 2,4-Pentadienyl(di-n-propyl)borane; 3.2 2,4,6-Heptatrienyl(di-n-propyl)borane; 4 Dynamic Behavior of Cyclic Allylboranes; 4.1 Dynamic Equilibria Between 2-(Dialkylboryl)methylenecyclobutanes and 1-(Dialkylboryl)cyclobutenes; 4.2 Dynamic Properties of Cyclopentadienyl and Pentamethylcyclopentadienyl Derivatives of Boron; 4.3 Synthesis and Dynamic Properties of 1-Indenyl(diethyl)borane 327 $a4.4 Dynamic Behavior of Cycloheptadienyl(di-n-propyl)borane4.5 Synthesis and Dynamic Properties of Cycloheptatrienyl(di-n-propyl)borane. Equilibrium with 7-(Di-n-propylboryl)norcaradiene; 4.6 Three Independent Dynamic Processes in the Irontricarbonyl Complex of Cycloheptatrienyl(di-n-propyl)borane; 4.7 Cyclooctatetraenyl(di-n-propyl)borane; 4.8 Sigmatropic Migrations and Thermal Rearrangements in Cyclononatetraenyl(di-n-propyl)borane. Comparison with the Dynamic Properties of Cyclononatetraenyl(trimethyl)tin; 4.9 Borotropic Migrations in Phenalenyl(di-n-propyl)borane 24 327 $a5 Diverse Chemoselectivity of Cyclic Polyunsaturated Organoboranes5.1 Chemical Behavior of Borane 23; 5.2 Diverse Chemoselectivity of 9-Cyclopentyl-9-borabarbaralane 54e; 6 Conclusion; 7 References; 3 Dynamic Behavior of Group 5 and 6 Transition Metal Complexes with NMR; 1 Introduction; 2 Rotational Isomerism in Amido and Ketimido Complexes; 2.1 Rotational Isomerism in Oxofluoramido Complexes of Tungsten(VI); 2.2 Restricted M-NR(2) Rotation in the Dinuclear Complexes with M(2)(6+) Core (M = W, Mo) 327 $a2.3 Features of Dynamic Behavior of Amido Cyclopentadienyl Complexes of Group 5 Transition Metals2.4 Internal Hindered Rotation of Ketimido Ligands; 3 Dynamic Behavior of d(0) Transition Metal Complexes with n-Donor Two-Center Ligands; 3.1 Isomerization of Fluorocomplexes of Group 5-6 with O, N-Two-Center Ligands; 3.2 Isomerism of Transition Metal Complexes with N, N-Two-center Ligands; 3.3 Nature of Bonding of n-Donor Two-center Ligands in d(0) Transition Metal Complexes; 3.4 Mechanism of Internal Hindered Rotation of h(2)-Bound Ligands; 4 Conclusion; 5 References 327 $a4 Conformational Mobility in Chelated Square-planar Rh, Ir, Pd, and Pt Complexes 330 $aThis series offers leading contributions by well-known chemists reviewing the state of the art of this wide research area. Physical organometallic chemistry aims to develop new insights and to promote novel interest and investigations applicable to organometallic chemistry. This volume focuses on several important topics on fluxionality in organometallic and coordination chemistry, reviewed by experts in each of the respective fields. It is intended to provide both authoritative concepts and stimulating ideas in order to tackle dynamics from different angles, aiming at an interdisciplinary a 410 0$aPhysical organometallic chemistry ;$vv. 4. 606 $aCoordination compounds 606 $aOrganometallic chemistry 606 $aMolecular dynamics 606 $aNuclear magnetic resonance spectroscopy 615 0$aCoordination compounds. 615 0$aOrganometallic chemistry. 615 0$aMolecular dynamics. 615 0$aNuclear magnetic resonance spectroscopy. 676 $a541/.2242 701 $aGielen$b M$g(Marcel),$f1938-$01608337 701 $aWillem$b R$g(Rudolf)$01618741 701 $aWrackmeyer$b Bernd$f1947-$01618742 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910817898003321 996 $aFluxional organometallic and coordination compounds$93950638 997 $aUNINA