LEADER 04051nam 2200637 a 450 001 9910817713003321 005 20240417000402.0 010 $a0-309-17399-X 010 $a1-280-18679-8 010 $a9786610186792 010 $a0-309-56255-4 035 $a(CKB)110986584752270 035 $a(OCoLC)320320524 035 $a(CaPaEBR)ebrary10068367 035 $a(SSID)ssj0000266258 035 $a(PQKBManifestationID)11226968 035 $a(PQKBTitleCode)TC0000266258 035 $a(PQKBWorkID)10301370 035 $a(PQKB)11663024 035 $a(Au-PeEL)EBL3377135 035 $a(CaPaEBR)ebr10068367 035 $a(CaONFJC)MIL18679 035 $a(OCoLC)923268562 035 $a(MiAaPQ)EBC3377135 035 $a(EXLCZ)99110986584752270 100 $a19980430d1998 uy 0 101 0 $aeng 135 $aurcn||||||||| 181 $ctxt 182 $cc 183 $acr 200 10$aUsing supercritical water oxidation to treat hydrolysate from VX neutralization /$fCommittee on Review and Evaluation of the Army Chemical Stockpile Disposal Program, Board on Army Science and Technology, Commission on Engineering and Technical Systems, National Research Council 205 $a1st ed. 210 $aWashington, D.C. $cNational Academy Press$d1998 215 $a1 online resource (82 p.) 225 1 $aThe compass series 300 $aBibliographic Level Mode of Issuance: Monograph 311 $a0-309-06043-5 320 $aIncludes bibliographical references (p. 55-58). 327 $aUsing Supercritical Water Oxidation to Treat Hydrolysate from VX Neutralization -- Copyright -- Preface -- Contents -- Acronyms -- Executive Summary -- BACKGROUND -- FINDINGS -- RECOMMENDATIONS -- 1 Introduction and Background -- SELECTION OF NEUTRALIZATION FOLLOWED BY SUPERCRITICAL WATER OXIDATION FOR STOCKPILE DISPOSAL AT NEWPORT, INDIANA -- VX STORAGE AT NEWPORT, INDIANA -- NEUTRALIZATION OF VX -- 2 Process Description and Scientific Principles -- PROCESS OVERVIEW -- SCIENTIFIC PRINCIPLES -- KINETICS -- PHASE BEHAVIOR -- 3 Technology Status -- PREVIOUS APPLICATIONS OF SUPERCRITICAL WATER OXIDATION TECHNOLOGY -- DEVELOPMENT PROGRAM FOR APPLICATION TO VX HYDROLYSATE -- Laboratory-Scale Tests to Establish Methylphosphonic Acid DREs -- Pilot-Scale Testing with Surrogates and VX Hydrolysate -- Toxicity of the Liquid Effluent -- Summary of Solids Management and System Performance -- STATUS OF EVAPORATOR TECHNOLOGY -- 4 Scale-Up, Stability, and Reliability -- PROCESS SCALE-UP -- SALT MANAGEMENT AND REACTOR DESIGN -- Higher Pressure Systems -- Dissolution in Molten Sodium Hydroxide -- Catalyzed Oxidation -- Transpiring Wall Reactor -- Engineering Control -- Conclusion -- CHOICE OF OXIDANT, MIXING, AND HEAT BALANCE -- CORROSION AND THE MATERIALS OF CONSTRUCTION -- PRESSURE LET-DOWN SYSTEMS -- SUMMARY -- 5 Full-Scale Process Design -- PROCESS DESCRIPTION -- PROCESS START-UP AND SHUTDOWN -- PROCESS MASS AND ENERGY BALANCES -- PROCESS MONITORING AND CONTROL -- MANAGING UPSETS AND MAINTENANCE -- PROCESS SAFETY -- PROCESS EFFLUENT REQUIREMENTS -- TECHNOLOGY IMPLEMENTATION TIMELINE -- ENVIRONMENTAL PERMIT REQUIREMENTS -- 6 Findings and Recommendations -- FINDINGS -- RECOMMENDATIONS -- References -- Appendices -- Appendix A Process Flow Diagrams for the Supercritical Water Oxidation and Evaporation Process Steps. 327 $aAppendix B Mass Balance for the Newport Chemical Agent Disposal Facility (NECDF) Process. 410 0$aCompass series (Washington, D.C.) 606 $aChemical weapons disposal 606 $aChemical weapons disposal$zUnited States 606 $aChemical agents (Munitions) 615 0$aChemical weapons disposal. 615 0$aChemical weapons disposal 615 0$aChemical agents (Munitions) 676 $a623.4/45 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910817713003321 996 $aUsing supercritical water oxidation to treat hydrolysate from VX neutralization$93920868 997 $aUNINA