LEADER 05733nam 2200793 a 450 001 9910817240503321 005 20240516092138.0 010 $a9786613619327 010 $a9781280589492 010 $a1280589493 010 $a9781118309483 010 $a1118309480 010 $a9781118309513 010 $a1118309510 010 $a9781118309476 010 $a1118309472 035 $a(CKB)2670000000175359 035 $a(EBL)827160 035 $a(OCoLC)787842608 035 $a(SSID)ssj0000668006 035 $a(PQKBManifestationID)11391355 035 $a(PQKBTitleCode)TC0000668006 035 $a(PQKBWorkID)10685743 035 $a(PQKB)10693764 035 $a(MiAaPQ)EBC827160 035 $a(Au-PeEL)EBL827160 035 $a(CaPaEBR)ebr10558103 035 $a(CaONFJC)MIL361932 035 $a(Perlego)1014204 035 $a(EXLCZ)992670000000175359 100 $a20120524d2012 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aKinetics and thermodynamics of multistep nucleation and self-assembly in nanoscale materials /$fedited by Gregoire Nicolis and Dominique Maes 205 $a1st ed. 210 $aHoboken, N.J. $cJohn Wiley & Sons$d2012 215 $a1 online resource (353 p.) 225 1 $aAdvances in chemical physics ;$vv. 151 300 $aDescription based upon print version of record. 311 08$a9781118167830 311 08$a111816783X 320 $aIncludes bibliographical references and indexes. 327 $aKinetics and Thermodynamics of Multistep Nucleation and Self-Assembly in Nanoscale Materials: Advances in Chemical Physics Volume 151; CONTRIBUTORS; PREFACE; PREFACE TO THE SERIES; CONTENTS; KINETICS AND THERMODYNAMICS OF FLUCTUATION-INDUCED TRANSITIONS IN MULTISTABLE SYSTEMS; I. INTRODUCTION; II. FORMULATION; A. Stationary Distribution; B. Exit from an Attraction Basin; III. CLOSED SYSTEMS AND DETAILED BALANCE; IV. GENERIC POTENTIALS AND THEIR UNFOLDINGS; A. Transitions from 1 to 3 Occur Necessarily Through State 2; B. Transitions from 1 to 3 Need Not Occur Through State 2 327 $aV. KINETICS OF TRANSITIONS BETWEEN STATES: MAPPING INTO A DISCRETE MARKOV PROCESSA. Three Simultaneously Stable States (Seven-Steady-State Region); B. Two Simultaneously Stable States (Five-Steady-State Region); C. Two Simultaneously Stable States (Three-Steady-State Region); VI. IRREVERSIBLE THERMODYNAMICS OF FLUCTUATION-INDUCED TRANSITIONS; VII. CONCLUSIONS; ACKNOWLEDGMENTS; REFERENCES; DYNAMICAL RARE EVENT SIMULATION TECHNIQUES FOR EQUILIBRIUM AND NONEQUILIBRIUM SYSTEMS; I. INTRODUCTION; II. REACTIVE FLUX METHOD; III. TRANSITION PATH SAMPLING; IV. TRANSITION INTERFACE SAMPLING 327 $aV. PARTIAL PATH SAMPLINGVI. FORWARD FLUX SAMPLING; VII. REPLICA EXCHANGE TIS; VIII. NUMERICAL EXAMPLE; IX. CONCLUSIONS; ACKNOWLEDGMENTS; REFERENCES; CONFOCAL DEPOLARIZED DYNAMIC LIGHT SCATTERING; I. INTRODUCTION; II. FUNDAMENTALS OF DEPOLARIZED SCATTERING: THE STATE OF THE ART; III. THE TRADITIONAL APPROACH; IV. THE NOVEL APPROACH; V. THE OPTICAL LAYOUT; VI. DATA REDUCTION SCHEME; VII. RESULTS; VIII. CONCLUSIONS; ACKNOWLEDGMENT; REFERENCES; THE TWO-STEP MECHANISM AND THE SOLUTION-CRYSTAL SPINODAL FOR NUCLEATION OF CRYSTALS IN SOLUTION; I. INTRODUCTION; II. THE CLASSICAL NUCLEATION THEORY 327 $aA. The Crystallization Driving ForceB. The Thermodynamic Theory of J.W. Gibbs; C. The Rate of Crystal Nucleation; III. THE TWO-STEP MECHANISM AND THE SOLUTION-CRYSTAL SPINODAL; A. Experimental Data on the Rate of Nucleation of Crystals; B. The Nucleus Size and Solution-to-Crystal Spinodal; C. The Classical Theory Overestimates the Crystal Nucleation Rate by 10 Orders of Magnitude; D. The Two-Step Mechanism of Nucleation of Crystal in Solution; E. Dense Liquid Clusters; F. The Rate Law for the Two-Step Mechanism of Crystal Nucleation 327 $aG. The Rate-determining Step in the Two-Step Nucleation MechanismH. The Role of Heterogeneous Nucleation Substrates; I. The Broad Applicability of the Two-Step Nucleation Mechanism; IV. SUMMARY AND CONCLUSIONS; ACKNOWLEDGMENTS; REFERENCES; EXPERIMENTAL STUDIES OF TWO-STEP NUCLEATION DURING TWO-DIMENSIONAL CRYSTALLIZATION OF COLLOIDAL PARTICLES WITH SHORT-RANGE ATTRACTION; I. INTRODUCTION; II. EXPERIMENTAL METHODS: SAMPLE PREPARATION AND IMAGING; III. ANALYSIS OF IMAGES: PARTICLE COORDINATES, AREA FRACTION, CLUSTER SIZES, AND CRYSTALLINE ORDER; IV. RESULTS 327 $aA. Single-Step and Two-Step Nucleation of Crystallites 330 $a The Advances in Chemical Physics series-the cutting edge of research in chemical physics The Advances in Chemical Physics series provides the chemical physics and physical chemistry fields with a forum for critical, authoritative evaluations of advances in every area of the discipline. Filled with cutting-edge research reported in a cohesive manner not found elsewhere in the literature, each volume of the Advances in Chemical Physics series presents contributions from internationally renowned chemists and serves as the perfect supplement to any advanced graduate class de 410 0$aAdvances in chemical physics ;$vv. 151. 606 $aNucleation 606 $aDynamics 606 $aThermodynamics 615 0$aNucleation. 615 0$aDynamics. 615 0$aThermodynamics. 676 $a541 701 $aNicolis$b Gregoire$016618 701 $aMaes$b Dominique$01629098 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910817240503321 996 $aKinetics and thermodynamics of multistep nucleation and self-assembly in nanoscale materials$93966613 997 $aUNINA