LEADER 05688nam 2200757Ia 450 001 9910816078203321 005 20240514074809.0 010 $a9783527639519 010 $a3527639519 010 $a9781283869713 010 $a1283869713 010 $a9783527639526 010 $a3527639527 010 $a9783527639502 010 $a3527639500 035 $a(CKB)2670000000177374 035 $a(EBL)822730 035 $a(OCoLC)792684103 035 $a(SSID)ssj0000632004 035 $a(PQKBManifestationID)11374052 035 $a(PQKBTitleCode)TC0000632004 035 $a(PQKBWorkID)10610264 035 $a(PQKB)11252581 035 $a(MiAaPQ)EBC822730 035 $a(Au-PeEL)EBL822730 035 $a(CaPaEBR)ebr10577528 035 $a(CaONFJC)MIL418221 035 $a(PPN)243140800 035 $a(Perlego)1002461 035 $a(EXLCZ)992670000000177374 100 $a20091027d2012 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aAnion coordination chemistry /$fedited by Kristin Bowman-James, Antonio Bianchi, Enrique Garci?a-Espana 205 $a1st ed. 210 $aWeinheim $cWiley-VCH$dc2012 215 $a1 online resource (575 p.) 300 $aDescription based upon print version of record. 311 08$a9783527323708 311 08$a3527323708 320 $aIncludes bibliographical references and index. 327 $aAnion Coordination Chemistry; Contents; Preface; List of Contributors; 1 Aspects of Anion Coordination from Historical Perspectives; 1.1 Introduction; 1.2 Halide and Pseudohalide Anions; 1.3 Oxoanions; 1.4 Phosphate and Polyphosphate Anions; 1.5 Carboxylate Anions and Amino Acids; 1.6 Anionic Complexes: Supercomplex Formation; 1.7 Nucleotides; 1.8 Final Notes; References; 2 Thermodynamic Aspects of Anion Coordination; 2.1 Introduction; 2.2 Parameters Determining the Stability of Anion Complexes; 2.2.1 Type of Binding Group: Noncovalent Forces in Anion Coordination 327 $a2.2.2 Charge of Anions and Receptors2.2.3 Number of Binding Groups; 2.2.3.1 Additivity of Noncovalent Forces; 2.2.4 Preorganization; 2.2.4.1 Macrocyclic Effect; 2.2.5 Solvent Effects; 2.3 Molecular Recognition and Selectivity; 2.4 Enthalpic and Entropic Contributions in Anion Coordination; References; 3 Structural Aspects of Anion Coordination Chemistry; 3.1 Introduction; 3.2 Basic Concepts of Anion Coordination Chemistry; 3.3 Classes of Anion Hosts; 3.4 Acycles; 3.4.1 Bidentate; 3.4.2 Tridentate; 3.4.3 Tetradentate; 3.4.4 Pentadentate; 3.4.5 Hexadentate; 3.5 Monocycles; 3.5.1 Bidentate 327 $a3.5.2 Tridentate3.5.3 Tetradentate; 3.5.4 Pentadentate; 3.5.5 Hexadentate; 3.5.6 Octadentate; 3.5.7 Dodecadentate; 3.6 Cryptands; 3.6.1 Bidentate; 3.6.2 Tridentate; 3.6.3 Tetradentate; 3.6.4 Pentadentate; 3.6.5 Hexadentate; 3.6.6 Septadentate; 3.6.7 Octadentate; 3.6.8 Nonadentate; 3.6.9 Decadentate; 3.6.10 Dodecadentate; 3.7 Transition-Metal-Assisted Ligands; 3.7.1 Bidentate; 3.7.2 Tridentate; 3.7.3 Tetradentate; 3.7.4 Hexadentate; 3.7.5 Septadentate; 3.7.6 Dodecadentate; 3.8 Lewis Acid Ligands; 3.8.1 Transition Metal Cascade Complexes; 3.8.2 Other Lewis Acid Donor Ligands 327 $a3.8.2.1 Boron-Based Ligands3.8.2.2 Tin-Based Ligands; 3.8.2.3 Hg-Based Ligands; 3.9 Conclusion; Acknowledgments; References; 4 Synthetic Strategies; 4.1 Introduction; 4.2 Design and Synthesis of Polyamine-Based Receptors for Anions; 4.2.1 Acyclic Polyamine Receptors; 4.2.2 Tripodal Polyamine Receptors; 4.2.3 Macrocyclic Polyamine Receptors with Aliphatic Skeletons; 4.2.4 Macrocyclic Receptors Incorporating a Single Aromatic Unit; 4.2.5 Macrocyclic Receptors Incorporating Two Aromatic Units; 4.2.6 Anion Receptors Containing Separated Macrocyclic Binding Units; 4.2.7 Cryptands 327 $a4.3 Design and Synthesis of Amide Receptors4.3.1 Acid Halides as Starting Materials; 4.3.1.1 Acyclic Amide Receptors; 4.3.1.2 Macrocyclic Amide Receptors; 4.3.2 Esters as Starting Materials; 4.3.3 Using Coupling Reagents; References; 5 Template Synthesis; 5.1 Introductory Remarks; 5.2 Macrocyclic Systems; 5.3 Bowl-Shaped Systems; 5.4 Capsule, Cage, and Tube-Shaped Systems; 5.5 Circular Helicates and meso-Helicates; 5.6 Mechanically Linked Systems; 5.7 Concluding Remarks; References; 6 Anion-ð Interactions in Molecular Recognition; 6.1 Introduction; 6.2 Physical Nature of the Interaction 327 $a6.3 Energetic and Geometric Features of the Interaction Depending on the Host (Aromatic Moieties) and the Guest (Anions) 330 $aBuilding on the pioneering work in supramolecular chemistry from the last 20 years or so, this monograph addresses new and recentapproaches to anion coordination chemistry. Synthesis of receptors, biological receptors and metallareceptors, the energetics of anion binding, molecular structures of anion complexes, sensing devices are presented and computational studies addressed to aid with the understanding of the different driving forces responsible for anion complexation. The reader is promised an actual picture of the state of the art for this exciting and constantly evolving field of su 606 $aAnions 606 $aSupramolecular chemistry 615 0$aAnions. 615 0$aSupramolecular chemistry. 676 $a541.3722 701 $aBianchi$b Antonio$f1956-$0297266 701 $aBowman-James$b Kristin$f1946-$01720346 701 $aGarci?a-Espan?a$b Enrique$01720347 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910816078203321 996 $aAnion coordination chemistry$94118920 997 $aUNINA