LEADER 05107nam 2200625 450 001 9910816076303321 005 20230807221447.0 010 $a1-119-17850-9 010 $a1-119-17849-5 010 $a1-119-17848-7 035 $a(CKB)3710000000459387 035 $a(EBL)2057223 035 $a(MiAaPQ)EBC2057223 035 $a(Au-PeEL)EBL2057223 035 $a(CaPaEBR)ebr11086793 035 $a(CaONFJC)MIL820177 035 $a(OCoLC)939554533 035 $a(EXLCZ)993710000000459387 100 $a20150824h20152015 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $2rdacontent 182 $2rdamedia 183 $2rdacarrier 200 10$aModeling of liquid phases$hVolume 2 /$fMichel Soustelle 210 1$aLondon, England ;$aHoboken, New Jersey :$cISTE :$cWiley,$d2015. 210 4$dİ2015 215 $a1 online resource (261 p.) 225 1 $aChemical Engineering Series 300 $aDescription based upon print version of record. 311 $a1-84821-865-6 320 $aIncludes bibliographical references and index. 327 $aCover; Title Page; Copyright ; Contents; Preface; Notations and Symbols; 1: Pure Liquids; 1.1. Macroscopic modeling of liquids; 1.2. Distribution of molecules in a liquid; 1.2.1. Molecular structure of a non-associated liquid; 1.2.2. The radial distribution function; 1.2.3 The curve representative of the radial distribution function; 1.2.4. Calculation of the macroscopic thermodynamic values; 1.3. Models extrapolated from gases or solids; 1.3.1. Guggenheim's smoothed potential model; 1.3.2. Mie's harmonic oscillator model 327 $a1.3.3. Determination of the free volume on the basis of the dilation and the compressibility1.4. Lennard-Jones and Devonshire cellular model; 1.5. Cellular and vacancies model; 1.6. Eyring's semi-microscopic formulation of the vacancy model; 1.7. Comparison between the different microscopic models and experimental results; 2: Macroscopic Modeling of Liquid Molecular Solutions; 2.1. Macroscopic modeling of the Margules expansion; 2.2. General representation of a solution with several components; 2.3. Macroscopic modeling of the Wagner expansions 327 $a2.3.1. Definition of the Wagner interaction coefficients2.3.2. Example of a ternary solution: experimental determination of Wagner's interaction coefficients; 2.4. Dilute ideal solutions; 2.4.1. Thermodynamic definition of a dilute ideal solution; 2.4.2. Activity coefficients of a component with a pure-substance reference; 2.4.3. Excess Gibbs energy of an ideal dilute solution; 2.4.4. Enthalpy of mixing for an ideal dilute solution; 2.4.5. Excess entropy of a dilute ideal solution; 2.4.6. Molar heat capacity of an ideal dilute solution at constant pressure; 2.5. Associated solutions 327 $a2.5.1. Example of the study of an associated solution2.5.2. Relations between the chemical potentials of the associated solution; 2.5.3. Calculating the extent of the equilibrium in an associated solution; 2.5.4. Calculating the activity coefficients in an associated solution; 2.5.5. Definition of a regular solution; 2.5.6. Strictly-regular solutions; 2.5.7. Macroscopic modeling of strictly-regular binary solutions; 2.5.8. Extension of the model of a strictly-regular solution to solutions with more than two components; 2.6. Athermic solutions 327 $a2.6.1. Thermodynamic definition of an athermic solution2.6.2. Variation of the activity coefficients with temperature in an athermic solution; 2.6.3. Molar entropy and Gibbs energy of mixing for an athermic solution; 2.6.4. Molar heat capacity of an athermic solution; 3: Microscopic Modeling of Liquid Molecular Solutions; 3.1. Models of binary solutions with molecules of similar dimensions; 3.1.1. The microscopic model of a perfect solution; 3.1.2. Microscopic description of strictly-regular solutions; 3.1.3. Microscopic modeling of an ideal dilute solution 327 $a3.2. The concept of local composition 330 $a This book is part of a set of books which offers advanced students successive characterization tool phases, the study of all types of phase (liquid, gas and solid, pure or multi-component), process engineering, chemical and electrochemical equilibria, and the properties of surfaces and phases of small sizes. Macroscopic and microscopic models are in turn covered with a constant correlation between the two scales. Particular attention has been given to the rigor of mathematical developments. This second volume in the set is devoted to the study of liquid phases. 410 0$aChemical engineering series (ISTE Ltd.) 606 $aThermochemistry 606 $aSolution (Chemistry) 606 $aKinetic theory of liquids 615 0$aThermochemistry. 615 0$aSolution (Chemistry) 615 0$aKinetic theory of liquids. 676 $a541.36 700 $aSoustelle$b Michel$01628148 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910816076303321 996 $aModeling of liquid phases$94118902 997 $aUNINA