LEADER 05390nam 2200697 450 001 9910814187003321 005 20200520144314.0 010 $a1-118-87762-4 010 $a1-118-87774-8 010 $a1-118-87775-6 035 $a(CKB)3710000000218269 035 $a(EBL)1765093 035 $a(SSID)ssj0001288900 035 $a(PQKBManifestationID)12497021 035 $a(PQKBTitleCode)TC0001288900 035 $a(PQKBWorkID)11296919 035 $a(PQKB)11165595 035 $a(OCoLC)879119507 035 $a(MiAaPQ)EBC1765093 035 $a(DLC) 2014017613 035 $a(Au-PeEL)EBL1765093 035 $a(CaPaEBR)ebr10907556 035 $a(CaONFJC)MIL637325 035 $a(OCoLC)887507318 035 $a(PPN)190616172 035 $a(EXLCZ)993710000000218269 100 $a20140826h20142014 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aGas treating $eabsorption theory and practice /$fDag A. Eimer 210 1$aChichester, [England] :$cWiley,$d2014. 210 4$d©2014 215 $a1 online resource (441 p.) 300 $aIncludes index. 311 $a1-118-87773-X 320 $aIncludes bibliographical references and index at the end of each chapters. 327 $aCover; Title Page; Copyright; Contents; Preface; List of Abbreviations; Nomenclature List; Chapter 1 Introduction; 1.1 Definitions; 1.2 Gas Markets, Gas Applications and Feedstock; 1.3 Sizes; 1.4 Units; 1.5 Ambient Conditions; 1.6 Objective of This Book; 1.7 Example Problems; 1.7.1 Synthesis Gas Plant; 1.7.2 Natural Gas Treatment; 1.7.3 Natural Gas Treatment for LNG; 1.7.4 Flue Gas CO2 Capture from a CCGT Power Plant; 1.7.5 Flue Gas CO2 Capture from a Coal Based Power Plant; 1.7.6 CO2 Removal from Biogas; 1.7.7 CO2 Removal from Landfill Gas; 1.7.8 Summarising Plant Sizes Just Considered 327 $aReferencesChapter 2 Gas Treating in General; 2.1 Introduction; 2.2 Process Categories; 2.2.1 Absorption; 2.2.2 Adsorption; 2.2.3 Cryogenics; 2.2.4 LNG Trains; 2.2.5 Membranes; 2.3 Sulfur Removal; 2.3.1 Scavengers; 2.3.2 Adsorption; 2.3.3 Direct Oxidation-Liquid Redox Processes; 2.3.4 Claus Plants; 2.3.5 Novelties; 2.4 Absorption Process; References; Chapter 3 Rate of Mass Transfer; 3.1 Introduction; 3.2 The Rate Equation; 3.3 Co-absorption and/or Simultaneous Desorption; 3.4 Convection and Diffusion; 3.5 Heat Balance; 3.6 Axially along the Column; 3.7 Flowsheet Simulators 327 $a3.8 Rate versus Equilibrium ApproachesFurther Reading; Chapter 4 Chemistry in Acid Gas Treating; 4.1 Introduction; 4.2 ''Chemistry''; 4.3 Acid Character of CO2 and H2S; 4.4 The H2S Chemistry with any Alkanolamine; 4.5 Chemistry of CO2 with Primary and Secondary Alkanolamines; 4.5.1 Zwitterion Mechanism; 4.5.2 Termolecular Mechanism of Crooks and Donnellan; 4.5.3 Australian Approach; 4.5.4 Older Representations; 4.6 The Chemistry of Tertiary Amines; 4.7 Chemistry of the Minor Sulfur Containing Gases; 4.7.1 The COS Chemistry; 4.7.2 Chemistry of CS2; 4.7.3 Chemistry of Mercaptans (RSH) 327 $a4.8 Sterically Hindered Amines4.9 Hot Carbonate Absorbent Systems; 4.10 Simultaneous Absorption of H2S and CO2; 4.11 Reaction Mechanisms and Activators-Final Words; 4.12 Review Questions, Problems and Challenges; References; Chapter 5 Physical Chemistry Topics; 5.1 Introduction; 5.2 Discussion of Solvents; 5.3 Acid-Base Considerations; 5.3.1 Arrhenius, Brønsted and Lewis; 5.3.2 Weak and Strong Acids and Bases; 5.3.3 pH; 5.3.4 Strength of Acids and Bases; 5.3.5 Titration; 5.3.6 Buffer Action in the NaOH or KOH Based CO2 Absorbents; 5.4 The Amine-CO2 Buffer System 327 $a5.5 Gas Solubilities, Henry''s and Raoult''s Laws5.5.1 Henry''s Law; 5.5.2 Gas Solubilities; 5.5.3 Raoult''s Law; 5.6 Solubilities of Solids; 5.7 N2O Analogy; 5.8 Partial Molar Properties and Representation; 5.9 Hydration and Hydrolysis; 5.10 Solvation; References; Chapter 6 Diffusion; 6.1 Dilute Mixtures; 6.2 Concentrated Mixtures; 6.3 Values of Diffusion Coefficients; 6.3.1 Gas Phase Values; 6.3.2 Liquid Phase Values; 6.4 Interacting Species; 6.5 Interaction with Surfaces; 6.6 Multicomponent Situations; 6.7 Examples; 6.7.1 Gaseous CO2-CH4; 6.7.2 Gaseous H2O-CH4 327 $a6.7.3 Liquid Phase Diffusion of H2O in TEG 330 $a Gas Treating: Absorption Theory and Practice provides an introduction to the treatment of natural gas, synthesis gas and flue gas, addressing why it is necessary and the challenges involved. The book concentrates in particular on the absorption-desorption process and mass transfer coupled with chemical reaction. Following a general introduction to gas treatment, the chemistry of CO2, H2S and amine systems is described, and selected topics from physical chemistry with relevance to gas treating are presented. Thereafter the absorption process is discussed in detail, column hardware is explain 606 $aGases$xAbsorption and adsorption 606 $aGases$xPurification 606 $aGases 615 0$aGases$xAbsorption and adsorption. 615 0$aGases$xPurification. 615 0$aGases. 676 $a536/.412 700 $aEimer$b D$g(Dag),$01642475 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910814187003321 996 $aGas treating$93987200 997 $aUNINA