LEADER 07651nam 2200601Ia 450 001 9910813802403321 005 20200520144314.0 010 $a9780470385821 010 0 $a9780470385814 010 0 $a0470385812 035 $a(MiAaPQ)EBC7103321 035 $a(CKB)24989766800041 035 $a(MiAaPQ)EBC427787 035 $a(Au-PeEL)EBL427787 035 $a(CaPaEBR)ebr10303818 035 $a(CaONFJC)MIL211269 035 $a(OCoLC)476270816 035 $a(JP-MeL)3000111516 035 $a(Au-PeEL)EBL7103321 035 $a(OCoLC)1347024720 035 $a(PPN)151813051 035 $a(EXLCZ)9924989766800041 100 $a20081017d2009 uy 0 101 0 $aeng 135 $aur||||||||||| 181 $ctxt$2rdacontent 182 $cc$2rdamedia 183 $acr$2rdacarrier 200 10$aPrinciples of chemical reactor analysis and design $enew tools for industrial chemical reactor operations /$fUzi Mann 205 $a2nd ed. 210 $aHoboken $cWiley$dc2009 215 $a1 online resource (xviii, 473 p. $cill.) 300 $aIncludes bibliographical references and index 320 $aIncludes bibliographical references and index. 327 $aIntro -- PRINCIPLES OF CHEMICAL REACTOR ANALYSIS AND DESIGN -- CONTENTS -- Preface -- Notation -- 1 Overview of Chemical Reaction Engineering -- 1.1 Classification of Chemical Reactions -- 1.2 Classification of Chemical Reactors -- 1.3 Phenomena and Concepts -- 1.3.1 Stoichiometry -- 1.3.2 Chemical Kinetics -- 1.3.3 Transport Effects -- 1.3.4 Global Rate Expression -- 1.3.5 Species Balance Equation and Reactor Design Equation -- 1.3.6 Energy Balance Equation -- 1.3.7 Momentum Balance Equation -- 1.4 Common Practices -- 1.4.1 Experimental Reactors -- 1.4.2 Selection of Reactor Configuration -- 1.4.3 Selection of Operating Conditions -- 1.4.4 Operational Considerations -- 1.4.5 Scaleup -- 1.4.6 Diagnostic Methods -- 1.5 Industrial Reactors -- 1.6 Summary -- References -- 2 Stoichiometry -- 2.1 Four Contexts of Chemical Reaction -- 2.2 Chemical Formulas and Stoichiometric Coefficients -- 2.3 Extent of a Chemical Reaction -- 2.4 Independent and Dependent Chemical Reactions -- 2.5 Characterization of the Reactor Feed -- 2.5.1 Limiting Reactant -- 2.5.2 Excess Reactant -- 2.6 Characterization of Reactor Performance -- 2.6.1 Reactant Conversion -- 2.6.2 Product Yield and Selectivity -- 2.7 Dimensionless Extents -- 2.8 Independent Species Composition Specifications -- 2.9 Summary -- Problems -- Bibliography -- 3 Chemical Kinetics -- 3.1 Species Formation Rates -- 3.2 Rates of Chemical Reactions -- 3.3 Rate Expressions of Chemical Reactions -- 3.4 Effects of Transport Phenomena -- 3.5 Characteristic Reaction Time -- 3.6 Summary -- Problems -- Bibliography -- 4 Species Balances and Design Equations -- 4.1 Macroscopic Species Balances-General Species-Based Design Equations -- 4.2 Species-Based Design Equations of Ideal Reactors -- 4.2.1 Ideal Batch Reactor -- 4.2.2 Continuous Stirred-Tank Reactor (CSTR) -- 4.2.3 Plug-Flow Reactor (PFR). 327 $a4.3 Reaction-Based Design Equations -- 4.3.1 Ideal Batch Reactor -- 4.3.2 Plug-Flow Reactor -- 4.3.3 Continuous Stirred-Tank Reactor (CSTR) -- 4.3.4 Formulation Procedure -- 4.4 Dimensionless Design Equations and Operating Curves -- 4.5 Summary -- Problems -- Bibliography -- 5 Energy Balances -- 5.1 Review of Thermodynamic Relations -- 5.1.1 Heat of Reaction -- 5.1.2 Effect of Temperature on Reaction Equilibrium Constant -- 5.2 Energy Balances -- 5.2.1 Batch Reactors -- 5.2.2 Flow Reactors -- 5.3 Summary -- Problems -- Bibliography -- 6 Ideal Batch Reactor -- 6.1 Design Equations and Auxiliary Relations -- 6.2 Isothermal Operations with Single Reactions -- 6.2.1 Constant-Volume Reactors -- 6.2.2 Gaseous, Variable-Volume Batch Reactors -- 6.2.3 Determination of the Reaction Rate Expression -- 6.3 Isothermal Operations with Multiple Reactions -- 6.4 Nonisothermal Operations -- 6.5 Summary -- Problems -- Bibliography -- 7 Plug-Flow Reactor -- 7.1 Design Equations and Auxiliary Relations -- 7.2 Isothermal Operations with Single Reactions -- 7.2.1 Design -- 7.2.2 Determination of Reaction Rate Expression -- 7.3 Isothermal Operations with Multiple Reactions -- 7.4 Nonisothermal Operations -- 7.5 Effects of Pressure Drop -- 7.6 Summary -- Problems -- 8 Continuous Stirred-Tank Reactor -- 8.1 Design Equations and Auxiliary Relations -- 8.2 Isothermal Operations with Single Reactions -- 8.2.1 Design of a Single CSTR -- 8.2.2 Determination of the Reaction Rate Expression -- 8.2.3 Cascade of CSTRs Connected in Series -- 8.3 Isothermal Operations with Multiple Reactions -- 8.4 Nonisothermal Operations -- 8.5 Summary -- Problems -- 9 Other Reactor Configurations -- 9.1 Semibatch Reactors -- 9.2 Plug-Flow Reactor with Distributed Feed -- 9.3 Distillation Reactor -- 9.4 Recycle Reactor -- 9.5 Summary -- Problems -- 10 Economic-Based Optimization. 327 $a10.1 Economic-Based Performance Objective Functions -- 10.2 Batch and Semibatch Reactors -- 10.3 Flow Reactors -- 10.4 Summary -- Problems -- Bibliography -- Appendix A Summary of Key Relationships -- Appendix B Microscopic Species Balances-Species Continuity Equations -- Appendix C Summary of Numerical Differentiation and Integration -- Index. 330 $aAn innovative approach that helps students move from the classroom to professional practice This text offers a comprehensive, unified methodology to analyze and design chemical reactors, using a reaction-based design formulation rather than the common species-based design formulation. The book's acclaimed approach addresses the weaknesses of current pedagogy by giving readers the knowledge and tools needed to address the technical challenges they will face in practice. Principles of Chemical Reactor Analysis and Design prepares readers to design and operate real chemical reactors and to troubleshoot any technical problems that may arise. The text's unified methodology is applicable to both single and multiple chemical reactions, to all reactor configurations, and to all forms of rate expression. This text also . . . Describes reactor operations in terms of dimensionless design equations, generating dimensionless operating curves that depict the progress of individual chemical reactions, the composition of species, and the temperature. Combines all parameters that affect heat transfer into a single dimensionless number that can be estimated a priori. Accounts for all variations in the heat capacity of the reacting fluid. Develops a complete framework for economic-based optimization of reactor operations. Problems at the end of each chapter are categorized by their level of difficulty from one to four, giving readers the opportunity to test and develop their skills. Graduate and advanced undergraduate chemical engineering students will find that this text's unified approach better prepares them for professional practice by teaching them the actual skills needed to design and analyze chemical reactors. 606 $aChemical plants$xEquipment and supplies$xDesign and construction 606 $aChemical reactors$xDesign and construction 615 0$aChemical plants$xEquipment and supplies$xDesign and construction. 615 0$aChemical reactors$xDesign and construction. 676 $a660/.2832 686 $a571.1$2njb/09 686 $a660/.2832$2njb/09 700 $aMann$b Uzi$01722790 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910813802403321 996 $aPrinciples of chemical reactor analysis and design$94123470 997 $aUNINA