LEADER 05435nam 2200709 450 001 9910811958803321 005 20200520144314.0 010 $a3-527-65480-1 010 $a3-527-65478-X 010 $a3-527-65481-X 035 $a(CKB)2550000001171788 035 $a(EBL)1580788 035 $a(SSID)ssj0001168981 035 $a(PQKBManifestationID)11620458 035 $a(PQKBTitleCode)TC0001168981 035 $a(PQKBWorkID)11152019 035 $a(PQKB)10970068 035 $a(OCoLC)868925491 035 $a(MiAaPQ)EBC1580788 035 $a(MiAaPQ)EBC4044374 035 $a(Au-PeEL)EBL1580788 035 $a(CaPaEBR)ebr10822353 035 $a(CaONFJC)MIL553188 035 $a(OCoLC)866442912 035 $a(PPN)219878323 035 $a(EXLCZ)992550000001171788 100 $a20111102h20142014 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aSupported ionic liquids $efundamentals and applications /$fedited by Rasmus Fehrmann, Anders Riisager, and Marco Haumann 210 1$aWeinheim :$cWiley-VCH Verlag GmbH,$d[2014] 210 4$dİ2014 215 $a1 online resource (497 p.) 300 $aDescription based upon print version of record. 311 $a3-527-32429-1 311 $a1-306-21937-X 320 $aIncludes bibliographical references and index. 327 $aSupported Ionic Liquids; Contents; Preface; List of Contributors; Chapter 1 Introduction; 1.1 A Century of Supported Liquids; 1.2 Supported Ionic Liquids; 1.3 Applications in Catalysis; 1.4 Applications in Separation; 1.5 Coating of Heterogeneous Catalysts; 1.6 Monolayers of IL on Surfaces; 1.7 Conclusion; References; Part I Concept and Building Blocks; Chapter 2 Introducing Ionic Liquids; 2.1 Introduction; 2.2 Preparation; 2.3 Liquid Range; 2.4 Structures; 2.4.1 The Liquid/Solid Interface; 2.4.2 The Liquid/Gas Interface; 2.5 Physical Properties; 2.5.1 The Liquid/Solid Interface 327 $a2.5.2 The Liquid/Gas Interface2.5.3 Polarity; 2.5.4 Chromatographic Measurements and the Abraham Model of Polarity; 2.5.5 Infinite Dilution Activity Coefficients; 2.6 Effects of Ionic Liquids on Chemical Reactions; 2.7 Ionic Liquids as Process Solvents in Industry; 2.8 Summary; References; Chapter 3 Porous Inorganic Materials as Potential Supports for Ionic Liquids; 3.1 Introduction; 3.2 Porous Materials - an Overview; 3.2.1 History; 3.2.2 Pore Size; 3.2.3 Structural Aspects; 3.2.4 Chemistry; 3.2.5 Synthesis; 3.3 Silica-Based Materials - Amorphous; 3.3.1 Silica Gels 327 $a3.3.2 Precipitated Silicas3.3.3 Porous Glass; 3.4 Layered Materials; 3.5 Microporous Materials; 3.5.1 Zeolites; 3.5.2 AlPOs/SAPOs; 3.5.3 Hierarchical Porosity in Zeolite Crystals; 3.6 Ordered Mesoporous Materials; 3.6.1 Silica-Based Classical Compounds; 3.6.2 PMOs; 3.6.3 Mesoporous Carbons; 3.6.4 Other Mesoporous Oxides; 3.6.5 Anodic Oxidized Materials; 3.7 Structured Supports and Monolithic Materials; 3.7.1 Monoliths with Hierarchical Porosity; 3.7.2 Hierarchically Structured Reactors; 3.8 Conclusions; References; Chapter 4 Synthetic Methodologies for Supported Ionic Liquid Materials 327 $a4.1 Introduction4.2 Support Materials; 4.3 Preparation Methods for Supported Ionic Liquids; 4.3.1 Incipient Wetness Impregnation; 4.3.2 Freeze-Drying; 4.3.3 Spray Coating; 4.3.4 Chemically Bound Ionic Liquids; 4.3.5 IL-Silica Hybrid Materials; 4.4 Summary; References; Part II Synthesis and Properties; Chapter 5 Pore Volume and Surface Area of Supported Ionic Liquids Systems; 5.1 Example I: [EMIM][NTf2] on Porous Silica; 5.2 Example II: SCILL Catalyst (Commercial Ni catalyst) Coated with [BMIM][OcSO4]; Acknowledgments; Symbols; Abbreviations; References 327 $aChapter 6 Transport Phenomena, Evaporation, and Thermal Stability of Supported Ionic Liquids6.1 Introduction; 6.2 Diffusion of Gases and Liquids in ILs and Diffusivity of ILs in Gases; 6.2.1 Diffusivity of Gases and Liquids in ILs; 6.2.2 Diffusion Coefficient of Evaporated ILs in Gases; 6.3 Thermal Stability and Vapor Pressure of Pure ILs; 6.3.1 Drawbacks and Opportunities Regarding Stability and Vapor Pressure Measurements of ILs; 6.3.2 Experimental Methods to Determine the Stability and Vapor Pressure of ILs; 6.3.3 Data Evaluation and Modeling Methodology 327 $a6.3.3.1 Evaluation of Vapor Pressure and Decomposition of ILs by Ambient Pressure TG at Constant Heating Rate 330 $a This unique book gives a timely overview about the fundamentals and applications of supported ionic liquids in modern organic synthesis. It introduces the concept and synthesis of SILP materials and presents important applications in the field of catalysis (e.g. hydroformylation, hydrogenation, coupling reactions, fine chemical synthesis) as well as energy technology and gas separation. Written by pioneers in the field, this book is an invaluable reference book for organic chemists in academia or industry. 606 $aIonic solutions 606 $aCatalysis 615 0$aIonic solutions. 615 0$aCatalysis. 676 $a541.395 701 $aFehrmann$b Rasmus$01697104 701 $aRiisager$b Anders$01697105 701 $aHaumann$b Marco$01697106 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910811958803321 996 $aSupported ionic liquids$94077559 997 $aUNINA