LEADER 05423nam 2200661 a 450 001 9910811228803321 005 20230120004108.0 010 $a1-281-05911-0 010 $a9786611059118 010 $a0-08-052843-0 035 $a(CKB)1000000000001166 035 $a(EBL)318294 035 $a(OCoLC)476112805 035 $a(SSID)ssj0000116958 035 $a(PQKBManifestationID)12034272 035 $a(PQKBTitleCode)TC0000116958 035 $a(PQKBWorkID)10043034 035 $a(PQKB)10508253 035 $a(MiAaPQ)EBC318294 035 $a(Au-PeEL)EBL318294 035 $a(CaPaEBR)ebr10041450 035 $a(CaONFJC)MIL105911 035 $a(EXLCZ)991000000000001166 100 $a19980324d1998 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aCALPHAD (calculation of phase diagrams)$b[electronic resource] $ea comprehensive guide /$fby N. Saunders and A.P. Miodownik 210 $aOxford ;$aNew York $cPergamon$dc1998 215 $a1 online resource (497 p.) 225 1 $aPergamon materials series ;$vv. 1 300 $aDescription based upon print version of record. 311 $a0-08-042129-6 320 $aIncludes bibliographical references and indexes. 327 $aFront Cover; CALPHAD Calculation of Phase Diagrams: A Comprehensive Guide; Copyright Page; Contents; Series preface; Preface; Foreword; CHAPTER 1. INTRODUCTION; CHAPTER 2. History of CALPHAD; 2.1. Introduction; 2.2. The Early Years; 2.3. The Intermediate Years; 2.4. The Last Decade; 2.5. The Current Status of CALPHAD; References; CHAPTER 3. BASIC THERMODYNAMICS; 3.1. Introduction; 3.2. The First Law of Thermodynamics; 3.3. The Second Law of Thermodynamics; 3.4. The Third Law of Thermodynamics; 3.5. Thermodynamics and Chemical Equilibrium; 3.6. Solution Phase Thermodynamics 327 $a3.7. Thermodynamics of Phase Equilibria and Some Simple Calculated Phase DiagramsReferences; CHAPTER 4. EXPERIMENTAL DETERMINATION OF THERMODYNAMIC QUANTITIES AND PHASE DIAGRAMS; 4.1. Introduction; 4.2. Experimental Determination of Thermodynamic Quantities; 4.3. Experimental Determination of Phase Diagrams; References; CHAPTER 5. THERMODYNAMIC MODELS FOR SOLUTION AND COMPOUND PHASES; 5.1. Introduction; 5.2. Stoichiometrie Compounds; 5.3. Random Substitutional Models; 5.4. Sublattice Models; 5.5. Ionic Liquid Models; 5.6. Aqueous Solutions; References; CHAPTER 6. PHASE STABILITIES 327 $a6.1. Introduction6.2. Thermochemical Estimations; 6.3. Ab Initio Electron Energy Calculations; 6.4. The Behaviour of Magnetic Elements; 6.5. The Effect of Pressure; 6.6. Determination of Interaction Coefficients for Alloys and Stability of Counter-Phases; 6.7. Summary; References; CHAPTER 7. ORDERING MODELS; 7.1. Introduction; 7.2. General Principles of Ordering Models; 7.3. Features of Various Ordering Models; 7.4. Empirical Routes; 7.5. Role of Lattice Vibrations; 7.6. Integration of Ordering into Phase Diagram Calculations 327 $a7.7. Comments on the use of ordering treatments in CALPHAD calculationsReferences; CHAPTER 8. THE ROLE OF MAGNETIC GIBBS ENERGY; 8.1. Introduction; 8.2. Derivation of the Magnetic Entropy; 8.3. Derivation of Magnetic Enthalpy, Hmag; 8.4. Derivation of Magnetic Gibbs Energy; 8.5. The Effect of Alloying Elements; 8.6. The Estimation of Magnetic Parameters; 8.7. Multiple Magnetic States; 8.8. Changes in Phase Equilibria Directly Attributable to Gmag; 8.9. Interaction with External Magnetic Fields; References; CHAPTER 9. COMPUTATIONAL METHODS; 9.1. Introduction 327 $a9.2. Calculation of Phase Equilibria9.3. Thermodynamic Optimisation of Phase Diagrams; References; CHAPTER 10. THE APPLICATION OF CALPHAD METHODS; 10.1. Introduction; 10.2. Early CALPHAD Applications; 10.3. General Background to Multi-Component Calculations; 10.4. Step-by-Step Examples of Multi-Component Calculations; 10.5. Quantitative Verification of Calculated Equilibria in Multi-Component Alloys; 10.6. Selected Examples; 10.7. Summary; References; CHAPTER 11. COMBINING THERMODYNAMICS AND KINETICS; 11.1. Introduction; 11.2. The Calculation of Metastable Equilibria 327 $a11.3. The Direct Coupling of Thermodynamics and Kinetics 330 $aThis monograph acts as a benchmark to current achievements in the field of Computer Coupling of Phase Diagrams and Thermochemistry, often called CALPHAD which is an acronym for Computer CALculation of PHAse Diagrams. It also acts as a guide to both the basic background of the subject area and the cutting edge of the topic, combining comprehensive discussions of the underlying physical principles of the CALPHAD method with detailed descriptions of their application to real complex multi-component materials. Approaches which combine both thermodynamic and kinetic models to 410 0$aPergamon materials series ;$vv. 1. 606 $aPhase diagrams$xData processing 606 $aThermochemistry$xData processing 615 0$aPhase diagrams$xData processing. 615 0$aThermochemistry$xData processing. 676 $a530.4/74 700 $aSaunders$b N$g(Nigel)$01688087 701 $aMiodownik$b A. P$g(A. Peter)$01688088 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910811228803321 996 $aCALPHAD (calculation of phase diagrams)$94062060 997 $aUNINA