LEADER 05305nam 2200637 a 450 001 9910810907303321 005 20200520144314.0 010 $a1-282-36816-8 010 $a9786612368165 010 $a0-470-43223-3 010 $a0-470-43222-5 035 $a(CKB)1000000000724859 035 $a(EBL)469262 035 $a(OCoLC)352837709 035 $a(SSID)ssj0000294902 035 $a(PQKBManifestationID)11229202 035 $a(PQKBTitleCode)TC0000294902 035 $a(PQKBWorkID)10312324 035 $a(PQKB)10610383 035 $a(MiAaPQ)EBC469262 035 $a(Au-PeEL)EBL469262 035 $a(CaPaEBR)ebr10307538 035 $a(CaONFJC)MIL236816 035 $a(PPN)225725282 035 $a(EXLCZ)991000000000724859 100 $a20080703d2009 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aElectron paramagnetic resonance $ea practitioner's toolkit /$fedited by Marina Brustolon, Elio Giamello 205 $a1st ed. 210 $aHoboken, N.J. $cWiley$dc2009 215 $a1 online resource (568 p.) 300 $aDescription based upon print version of record. 311 $a0-470-25882-9 327 $aELECTRON PARAMAGNETIC RESONANCE; CONTENTS; FOREWORD; PREFACE; CONTRIBUTORS; I PRINCIPLES; 1 Introduction to Electron Paramagnetic Resonance; 1.1 Chapter Summary; 1.2 EPR Spectrum: What Is It?; 1.3 The Electron Spin; 1.4 Electron Spin in a Magnetic Field (Zeeman Effect); 1.5 Effect of Electromagnetic Fields; 1.6 Macroscopic Collection of Electron Spins; 1.7 Observation of Magnetic Resonance; 1.8 Electron Spin in Atoms and Molecules; 1.9 Macroscopic Magnetization; 1.10 Spin Relaxation and Bloch Equations; 1.11 Nuclear Spins; 1.12 Anisotropy of the Hyperfine Interaction; 1.13 ENDOR 327 $a1.14 Two Interacting Electron Spins1.15 Quantum Machinery; 1.16 Electron Spin in a Static Magnetic Field; 1.17 Electron Spin Coupled to a Nuclear Spin; 1.18 Electron Spin in a Zeeman Magnetic Field in the Presence of a Microwave Field; 2 Basic Experimental Methods in Continuous Wave Electron Paramagnetic Resonance; 2.1 Instrumental Components of a Continuous Wave Electron Paramagnetic Resonance (CW-EPR) Spectrometer; 2.2 Experimental Techniques; Acknowledgment; References; Bibliography; 3 What Can Be Studied with Electron Paramagnetic Resonance?; 3.1 Introduction; 3.2 Organic Radicals 327 $a3.3 Organic Molecules with More than One Unpaired Electron3.4 Inorganic Radicals, Small Paramagnetic Molecules, and Isolated Atoms; 3.5 Transition Metal Ions; 3.6 Natural Systems and Processes; 3.7 Tailoring and Assembling PS for Magnetic Materials; 3.8 Industrial Applications of EPR; References; Bibliography; 4 Electron Paramagnetic Resonance Spectroscopy in the Liquid Phase; 4.1 General Considerations; 4.2 Generation of Radicals and Radical Ions; 4.3 Basic Interactions and Principles; 4.4 Patterns and Line Shapes of Fluid-Solution EPR Spectra; 4.5 Transition-Metal Ions; 4.6 Biradicals 327 $a4.7 Simulation Software4.8 How Fluid-Solution Spectra are Analyzed; 4.9 Calculation of EPR Parameters; 4.10 Molecular Properties Mirrored by EPR Spectra in Fluid Solution; 4.11 Chemically Induced Dynamic Electron Polarization (CIDEP) and CID Nuclear Polarization (CIDNP): Methods to Study Short-Lived Radicals; Acknowledgments; References; Further Reading; 5 Pulsed Electron Paramagnetic Resonance; 5.1 Introduction; 5.2 Vector Model for Pulsed EPR; 5.3 Pulse Sequences; 5.4 Data Analysis; 5.5 Spectrometer; References; 6 Electron Paramagnetic Resonance Spectra in the Solid State; 6.1 Introduction 327 $a6.2 Anisotropy of the Zeeman Interaction: The g Tensor6.3 The Hyperfine Interaction in the Solid State; 6.4 TMIs; 6.5 EPR Spectra for S > 1/2: ZFS; References; Appendix A.6.1 Simple Matrix Manipulations; Appendix A.6.2 Pauli Matrices; Appendix A.6.3 Transformation of Tensor Coordinates Via Matrices; Appendix A.6.4 Euler Angles; Appendix A.6.5 Matrix Elements of Spin-Orbit Coupling; Appendix A.6.6 Origin of the g and A Values for simple TMIs; Appendix References; 7 The Virtual Electron Paramagnetic Resonance Laboratory: A User Guide to ab initio Modeling; 7.1 Introduction; 7.2 Modeling Tools 327 $a7.3 Tutorial and Case Studies 330 $aEasy-to-follow guide helps you take full advantage of EPR spectroscopy's capabilities Electron Paramagnetic Resonance: A Practitioner's Toolkit serves as a practical guide that enables you to navigate through and make sense of the complex maze of electron paramagnetic resonance (EPR) spectroscopy fundamentals, techniques, and applications. The first half of this book is dedicated to explaining the core principles of EPR spectroscopy, using clear, easy-to-follow explanations and examples while avoiding complex physics and mathematics. The second half of the book focuses on applications 606 $aElectron paramagnetic resonance 615 0$aElectron paramagnetic resonance. 676 $a543/.67 701 $aBrustolon$b Marina$082122 701 $aGiamello$b Giacomo$01680225 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910810907303321 996 $aElectron paramagnetic resonance$94048830 997 $aUNINA